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Abbreviations | |
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Preface to the fourth edition | |
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The theory of nuclear magnetization | |
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The properties of the nucleus of an atom | |
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The nucleus in a magnetic field | |
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The source of the NMR signal | |
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A basic NMR spectrometer | |
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Questions | |
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The magnetic field at the nucleus: nuclear screening and the chemical shift | |
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Effects due to the molecule | |
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Isotope effects | |
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Effects due to unpaired electrons | |
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The chemical shift | |
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Notes on sample preparation, standardization and solvent and temperature effects | |
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Questions | |
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Internuclear spin-spin coupling | |
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The mutual effects of nuclear magnets on resonance positions | |
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The appearance of multiplets arising from spin-spin coupling | |
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Spin-spin coupling satellites | |
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The description of spin systems | |
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Second-order effects | |
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Questions | |
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Nuclear magnetic relaxation | |
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Relaxation processes in assemblies of nuclear spins | |
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Dipole-dipole relaxation | |
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Quadrupolar relaxation | |
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Spin rotation relaxation: detailed molecular motion | |
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Chemical shift anisotropy relaxation | |
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Scalar relaxation | |
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Examples of [superscript 13]C relaxation times | |
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Questions | |
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The spectrometer | |
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The magnet and field homogeneity | |
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The probe | |
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Field-frequency lock | |
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The transmitter | |
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The detection system | |
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Production of the spectrum | |
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Rapid multiple pulsing | |
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Manipulation of collected data | |
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Questions | |
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Making the spins dance | |
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Decoupling | |
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Composite pulses | |
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Refocusing pulse | |
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Questions | |
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NMR spectra of exchanging and reacting systems | |
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Systems at equilibrium | |
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Reaction monitoring of systems not at equilibrium | |
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Questions | |
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Multiple resonance and one-dimensional pulse sequences | |
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Decoupling difference spectroscopy | |
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The nuclear Overhauser effect | |
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One-dimensional multipulse sequences | |
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Exercises in spectral interpretation | |
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Two-dimensional NMR spectroscopy | |
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J-resolved two-dimensional NMR spectroscopy | |
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Homonuclear COSY NMR spectroscopy | |
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Heteronuclear COSY NMR spectroscopy | |
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HOHAHA or TOCSY | |
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Two-dimensional Inadequate | |
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Overhauser and magnetization transfer based two-dimensional NMR spectroscopy | |
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Inverse detection | |
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Three-dimensional NMR spectroscopy | |
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Questions | |
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Magnetic resonance imaging and biomedical NMR | |
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Producing an image | |
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Whole body imaging | |
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Diffusion and flow | |
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Chemical shift imaging | |
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Biological uses of imaging - imaging microscopy | |
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Industrial uses of imaging techniques | |
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Biomedical NMR | |
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High-resolution solid-state NMR | |
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Magic angle spinning | |
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Spin-1/2 nuclei with low magnetogyric ratios | |
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I = 1/2 nuclei with high magnetogyric ratios | |
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MAS of quadrupolar nuclei | |
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Some applications | |
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Deuterium, an integral-spin nucleus | |
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Questions | |
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Bibliography | |
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Answers to Questions | |
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Index | |