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Organometallic Chemistry of the Transition Metals

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ISBN-10: 0471662569

ISBN-13: 9780471662563

Edition: 4th 2005 (Revised)

Authors: Robert H. Crabtree

List price: $120.00
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Description:

Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
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Book details

List price: $120.00
Edition: 4th
Copyright year: 2005
Publisher: John Wiley & Sons, Incorporated
Publication date: 5/5/2005
Binding: Hardcover
Pages: 560
Size: 6.50" wide x 9.50" long x 1.00" tall
Weight: 1.892
Language: English

Preface
List of Abbreviations
Introduction
Werner Complexes
The Trans Effect
Soft Versus Hard Ligands
The Crystal Field
The Ligand Field
Back Bonding
Electroneutrality
Types of Ligand
General Properties of Organometallic Complexes
The 18-Electron Rule
Limitations of the 18-Electron Rule
Electron Counting in Reactions
Oxidation State
Coordination Number and Geometry
Effects of Complexation
Differences between Metals
Outer-Sphere Coordination
Metal Alkyls, Aryls, and Hydrides and Related ?-Bonded Ligands
Transition Metal Alkyls and Aryls
Related ?-Bonded Ligands
Metal Hydride Complexes
Complexes
Bond Strengths for Classical ?-Bonding Ligands
Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions
Metal Complexes of CO, RNC, CS, and NO
Phosphines and Related Ligands
Dissociative Substitution
Associative Mechanism
Redox Effects, the I Mechanism, and Rearrangements in Substitution
Photochemical Substitution
Steric and Solvent Effects in Substitution
Complexes of A-Bound Ligands
Alkene and Alkyne Complexes
Allyl Complexes
Diene Complexes
Cyclopentadienyl Complexes
Arenes and Other Alicyclic Ligands
Metalacycles and Isoelectronic and Isolobal Replacement
Stability of Polyene and Polyenyl Complexes
Oxidative Addition and Reductive Elimination
Concerted Additions
SN2 Reactions
Radical Mechanisms
Ionic Mechanisms
Reductive Elimination
?-Bond Metathesis
Oxidative Coupling and Reductive Cleavage
Insertion and Elimination
Reactions Involving CO
Insertions Involving Alkenes
Other Insertions
?, ?, ?, and ' Elimination
Nucleophilic and Electrophilic Addition and Abstraction
Nucleophilic Addition to CO
Nucleophilic Addition to Polyene and Polyenyl Ligands
Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls
Electrophilic Addition
Electrophilic Abstraction of Alkyl Groups
Single-Electron Transfer Pathways
Reactions of Organic Free Radicals with Metal Complexes
Homogeneous Catalysis
Alkene Isomerization
Alkene Hydrogenation
Alkene Hydroformylation
Hydrocyanation of Butadiene
Alkene Hydrosilation and Hydroboration
Coupling Reactions
Surface and Supported Organometallic Catalysis
Physical Methods in Organometallic Chemistry
Isolation
1H NMR Spectroscopy
13C NMR Spectroscopy
31P NMR Spectroscopy
Dynamic NMR
Spin Saturation Transfer
T1 and the Nuclear Overhauser Effect
Isotopic Perturbation of Resonance
IR Spectroscopy
Crystallography
Other Methods
Metal-Ligand Multiple Bonds
Carbenes
Carbynes
Bridging Carbenes and Carbynes
N-Heterocyclic Carbenes
Multiple Bonds to Heteroatoms
Applications of Organometallic Chemistry
Alkene Metathesis
Dimerization, Oligomerization, and Polymerization of Alkenes
Activation of CO and CO2
CH Activation
Organometallic Materials and Polymers