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| Preface | |
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| Preface to the First Edition | |
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| Contributors | |
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| Contributors to the First Edition | |
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| Fundamentals of Impedance Spectroscopy | |
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| Background, Basic Definitions, and History | |
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| The Importance of Interfaces | |
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| The Basic Impedance Spectroscopy Experiment | |
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| Response to a Small-Signal Stimulus in the Frequency Domain | |
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| Impedance-Related Functions | |
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| Early History | |
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| Advantages and Limitations | |
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| Differences Between Solid State and Aqueous Electrochemistry | |
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| Elementary Analysis of Impedance Spectra | |
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| Physical Models for Equivalent Circuit Elements | |
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| Simple RC Circuits | |
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| Analysis of Single Impedance Arcs | |
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| Selected Applications of IS | |
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| Theory | |
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| The Electrical Analogs of Physical and Chemical Processes | |
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| Introduction | |
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| The Electrical Properties of Bulk Homogeneous Phases | |
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| Introduction | |
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| Dielectric Relaxation in Materials with a Single Time Constant | |
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| Distributions of Relaxation Times | |
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| Conductivity and Diffusion in Electrolytes | |
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| Conductivity and Diffusion-a Statistical Description | |
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| Migration in the Absence of Concentration Gradients | |
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| Transport in Disordered Media | |
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| Mass and Charge Transport in the Presence of Concentration Gradients | |
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| Diffusion | |
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| Mixed Electronic-Ionic Conductors | |
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| Concentration Polarization | |
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| Interfaces and Boundary Conditions | |
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| Reversible and Irreversible Interfaces | |
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| Polarizable Electrodes | |
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| Adsorption at the Electrode-Electrolyte Interface | |
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| Charge Transfer at the Electrode-Electrolyte Interface | |
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| Grain Boundary Effects | |
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| Current Distribution, Porous and Rough Electrodes- the Effect of Geometry | |
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| Current Distribution Problems | |
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| Rough and Porous Electrodes | |
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| Physical and Electrochemical Models | |
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| The Modeling of Electrochemical Systems | |
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| Equivalent Circuits | |
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| Unification of Immitance Responses | |
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| Distributed Circuit Elements | |
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| Ambiguous Circuits | |
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| Modeling Results | |
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| Introduction | |
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| Supported Situations | |
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| Unsupported Situations: Theoretical Models | |
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| Unsupported Situations: Equivalent Network Models | |
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| Unsupported Situations: Empirical and Semiempirical Models | |
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| Measuring Techniques and Data Analysis | |
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| Impedance Measurement Techniques | |
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| Introduction | |
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| Frequency Domain Methods | |
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| Audio Frequency Bridges | |
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| Transformer Ratio Arm Bridges | |
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| Berberian-Cole Bridge | |
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| Considerations of Potentiostatic Control | |
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| Oscilloscopic Methods for Direct Measurement | |
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| Phase-Sensitive Detection for Direct Measurement | |
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| Automated Frequency Response Analysis | |
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| Automated Impedance Analyzers | |
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| The Use of Kramers-Kronig Transforms | |
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| Spectrum Analyzers | |
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| Time Domain Methods | |
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| Introduction | |
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| Analog-to-Digital (A/D) Conversion | |
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| Computer Interfacing | |
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| Digital Signal Processing | |
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| Conclusions | |
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| Commercially Available Impedance Measurement Systems (Brian Sayers) | |
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| Electrochemical Impedance Measurement Systems | |
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| System Configuration | |
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| Why Use a Potentiostat? | |
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| Measurements Using 2, 3 or 4-Terminal Techniques | |
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| Measurement Resolution an | |