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Impedance Spectroscopy Theory, Experiment, and Applications

ISBN-10: 0471647497

ISBN-13: 9780471647492

Edition: 2nd 2005 (Revised)

Authors: Evgenij Barsoukov, J. Ross Macdonald, J. Ross Macdonald, J. Ross Macdonald

List price: $202.00
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Description:

Impedance spectroscopy has established itself as one of the most informative & irreplaceable investigative methods in physical chemistry, electrochemistry & physics. This text provides an overview & detailed guidance to the application of this methodology in various areas.
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Book details

List price: $202.00
Edition: 2nd
Copyright year: 2005
Publisher: John Wiley & Sons, Incorporated
Publication date: 3/17/2005
Binding: Hardcover
Pages: 616
Size: 6.75" wide x 9.75" long x 1.25" tall
Weight: 2.090
Language: English

EVGENIJ BARSOUKOV, PhD, is a Senior Application Engineer at Texas Instruments, Inc. His current research focuses on the application of impedance spectroscopy-based modeling to improve battery monitoring technology.J. ROSS MACDONALD, DSc, is the William Rand Kenan, Jr., Professor Emeritus of Physics at The University of North Carolina. He has published more than 200 papers in the fields of physics, chemistry, applied mathematics, and electrical engineering, and he was the editor of the First Edition of Impedance Spectroscopy (Wiley). His current research uses impedance spectroscopy to help analyze the electrical response of high-resistivity ionically conducting solid materials.

Preface
Preface to the First Edition
Contributors
Contributors to the First Edition
Fundamentals of Impedance Spectroscopy
Background, Basic Definitions, and History
The Importance of Interfaces
The Basic Impedance Spectroscopy Experiment
Response to a Small-Signal Stimulus in the Frequency Domain
Impedance-Related Functions
Early History
Advantages and Limitations
Differences Between Solid State and Aqueous Electrochemistry
Elementary Analysis of Impedance Spectra
Physical Models for Equivalent Circuit Elements
Simple RC Circuits
Analysis of Single Impedance Arcs
Selected Applications of IS
Theory
The Electrical Analogs of Physical and Chemical Processes
Introduction
The Electrical Properties of Bulk Homogeneous Phases
Introduction
Dielectric Relaxation in Materials with a Single Time Constant
Distributions of Relaxation Times
Conductivity and Diffusion in Electrolytes
Conductivity and Diffusion-a Statistical Description
Migration in the Absence of Concentration Gradients
Transport in Disordered Media
Mass and Charge Transport in the Presence of Concentration Gradients
Diffusion
Mixed Electronic-Ionic Conductors
Concentration Polarization
Interfaces and Boundary Conditions
Reversible and Irreversible Interfaces
Polarizable Electrodes
Adsorption at the Electrode-Electrolyte Interface
Charge Transfer at the Electrode-Electrolyte Interface
Grain Boundary Effects
Current Distribution, Porous and Rough Electrodes- the Effect of Geometry
Current Distribution Problems
Rough and Porous Electrodes
Physical and Electrochemical Models
The Modeling of Electrochemical Systems
Equivalent Circuits
Unification of Immitance Responses
Distributed Circuit Elements
Ambiguous Circuits
Modeling Results
Introduction
Supported Situations
Unsupported Situations: Theoretical Models
Unsupported Situations: Equivalent Network Models
Unsupported Situations: Empirical and Semiempirical Models
Measuring Techniques and Data Analysis
Impedance Measurement Techniques
Introduction
Frequency Domain Methods
Audio Frequency Bridges
Transformer Ratio Arm Bridges
Berberian-Cole Bridge
Considerations of Potentiostatic Control
Oscilloscopic Methods for Direct Measurement
Phase-Sensitive Detection for Direct Measurement
Automated Frequency Response Analysis
Automated Impedance Analyzers
The Use of Kramers-Kronig Transforms
Spectrum Analyzers
Time Domain Methods
Introduction
Analog-to-Digital (A/D) Conversion
Computer Interfacing
Digital Signal Processing
Conclusions
Commercially Available Impedance Measurement Systems (Brian Sayers)
Electrochemical Impedance Measurement Systems
System Configuration
Why Use a Potentiostat?
Measurements Using 2, 3 or 4-Terminal Techniques
Measurement Resolution an