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| Preface to the Third Edition | |
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| Preface to the Second Edition | |
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| Preface to the First Edition | |
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| Introduction | |
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| Definitions | |
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| Thermodynamics and Potential | |
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| Kinetics and Rates of Reaction | |
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| Transport | |
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| Concentration Overpotential and the Diffusion Potential | |
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| Overall Cell Potential | |
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| Problems | |
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| Notation | |
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| THermodynamics of Electrochemical Cells | |
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| Thermodynamics in Terms of Electrochemical Potentials | |
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| Phase Equilibrium | |
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| Chemical Potential and Electrochemical Potential | |
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| Definition of Some Thermodynamic Functions | |
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| Cell with Solution of Uniform Concentration | |
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| Transport Processes in Junction Regions | |
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| Cell with a Single Electrolyte of Varying Concentration | |
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| Cell with Two Electrolytes, One of Nearly Uniform Concentration | |
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| Cell with Two Electrolytes, Both of Varying Concentration | |
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| Standard Cell Potential and Activity Coefficients | |
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| Pressure Dependence of Activity Coefficients | |
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| Temperature Dependence of Cell Potentials | |
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| Problems | |
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| Notation | |
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| References | |
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| The Electric Potential | |
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| The Electrostatic Potential | |
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| Intermolecular Forces | |
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| Outer and Inner Potentials | |
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| Potentials of Reference Electrodes | |
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| The Electric Potential in Thermodynamics | |
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| Notation | |
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| References | |
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| Activity Coefficients | |
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| Ionic Distributions in Dilute Solutions | |
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| Electrical Contribution to the Free Energy | |
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| Shortcomings of the Debye-Hu�ckel Model | |
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| Binary Solutions | |
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| Multicomponent Solutions | |
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| Measurement of Activity Coefficients | |
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| Weak Electrolytes.Problems | |
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| Notation | |
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| References | |
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| Reference Electrodes | |
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| Criteria for Reference Electrodes | |
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| Experimental Factors Affecting The Selection of Reference Electrodes | |
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| The Hydrogen Electrode | |
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| The Calomel Electrode and Other Mercury-Mercurous Salt Electrodes | |
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| The Mercury-Mercuric Oxide Electrode | |
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| Silver-Silver Halide Electrodes | |
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| Potentials Relative to a Given Reference Electrode | |
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| Notation | |
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| References | |
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| Potentials of Cells with Junctions | |
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| Nernst Equation | |
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| Types of Liquid Junctions | |
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| Formulas for Liquid-Junction Potentials | |
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| Determination of Concentration Profiles | |
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| Numerical Results | |
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| Cells with Liquid Junction | |
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| Error in the Nernst Equation | |
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| Potentials Across Membranes | |
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| Problems | |
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| Notation | |
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| References | |
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| Electrode Kinetics and Other Interfacial Phenomena | |
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| Structure of the Electric Double Layer | |
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| Qualitative Description of Double Layers | |
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| Gibbs Adsorption Isotherm | |
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| The Lippmann Equation | |
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| The Diffuse Part of the Double Layer | |
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| Capacity of the Double Layer in the Absence of Specific Adsorption | |
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| Specific Adsorption at an Electrode-Solution Interface | |
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| Problems | |
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| Notation | |
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| References | |
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| Electrode Kinetics | |
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| Heterogeneous Electrode Reactions | |
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| Dependence of Current Density on Surface Overpotential | |
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| Models for Electrode Kinetics | |
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| Effect of Double-Layer Structure | |
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| The Oxygen Electrode | |
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| Methods of Measurement | |
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| Simultaneous Reactions | |
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| Problems | |
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| Notation | |
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| References | |
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| Electrokinetic Phenomena | |
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| Discontinuous Velocity at an Interface | |
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| Electro-Osmosis and the Streaming Potential | |
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| Electrophoresis | |
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| Sedimentation Potential | |
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| Problems | |
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| Notation | |
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| References | |
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| Electrocapillary Phenomena | |
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| Dynamics of Interfaces | |
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| Electrocapillary Motion of Mercury Drops | |
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| Sedimentation Potentials for Falling Mercury Drops | |
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| Notation | |
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| References | |
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| Transport Processes in Electrolytic Solutions | |
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| Infinitely Dilute Solutions | |
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| Transport Laws | |
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| Conductivity, Diffusion Potentials, and Transference Numbers | |
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| Conservation of Charge | |
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| The Binary Electrolyte | |
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| Supporting Electrolyte | |
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| Multicomponent Diffusion by Elimination of the Electric Field | |
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| Mobilities and Diffusion Coefficients | |
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| Electroneutrality and Laplace''s Equation | |
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| Moderately Dilute Solutions | |
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| Problems | |
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| Notation | |
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| References | |
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| Concentrated Solutions | |
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| Transport Laws | |
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| The Binary Electrolyte | |
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| Reference Velocities | |
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| The Potential | |
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| Connection with Dilute-Solution Theory | |
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| Multicomponent Transport | |
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| Liquid-Junction Potentials | |
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| Problems | |
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| No | |