| |
| |
| |
Introduction | |
| |
| |
The Study of Minerals as Part of Earth Science | |
| |
| |
Mineral Science | |
| |
| |
Definition of Mineral | |
| |
| |
History of Mineralogy | |
| |
| |
Economic Importance of Minerals | |
| |
| |
Naming of Minerals | |
| |
| |
References and Literature of Mineralogy | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Physical Properties of Minerals in Hand Specimen | |
| |
| |
Crystal Form and Crystal Habit | |
| |
| |
Intergrowths, Twins, and Striations | |
| |
| |
State of Aggregation | |
| |
| |
Luster, Color, and Streak | |
| |
| |
Luster | |
| |
| |
Color | |
| |
| |
Streak | |
| |
| |
Other Properties Depending on Light | |
| |
| |
Play of Colors | |
| |
| |
Chatoyancy and Asterism | |
| |
| |
Luminescence | |
| |
| |
Fluorescence and Phosphorescence | |
| |
| |
Cleavage, Parting, and Fracture | |
| |
| |
Cleavage | |
| |
| |
Parting | |
| |
| |
Fracture | |
| |
| |
Hardness | |
| |
| |
Tenacity | |
| |
| |
Specific Gravity | |
| |
| |
Average Specific Gravity | |
| |
| |
Determination of Specific Gravity | |
| |
| |
Magnetism | |
| |
| |
Radioactivity | |
| |
| |
Solubility in HCI | |
| |
| |
Piezoelectricity | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Elements of Crystal Chemistry | |
| |
| |
Chemical Composition of the Earth's Crust | |
| |
| |
The Atom | |
| |
| |
Chemical Elements and the Periodic Table | |
| |
| |
The Bohr Model of the Atom | |
| |
| |
The Schrodinger Model of the Atom | |
| |
| |
Electron Configuration and the Periodic Table | |
| |
| |
The Ion | |
| |
| |
Bonding Forces in Crystals | |
| |
| |
Ionic Bond | |
| |
| |
Covalent Bond | |
| |
| |
Estimation of the Character of the Bonding Mechanism | |
| |
| |
Metallic Bond | |
| |
| |
Van der Waals Bond | |
| |
| |
Hydrogren Bond | |
| |
| |
Crystals with More than One Bond Type | |
| |
| |
Atomic and Ionic Radii | |
| |
| |
Coordination of Ions | |
| |
| |
Radius Ratio | |
| |
| |
Pauling's Rules | |
| |
| |
Crystal Structure | |
| |
| |
Illustration of Crystal Structures | |
| |
| |
Isostructuralism | |
| |
| |
Examples of Common Structure Types | |
| |
| |
NaCl Structure | |
| |
| |
CsCl Structure | |
| |
| |
Sphalerite (ZnS) Structure | |
| |
| |
CaF[subscript 2] Structure | |
| |
| |
Rutile (TiO[subscript 2]) Structure | |
| |
| |
Perovskite (ABO[subscript 3]) Structure | |
| |
| |
Spinel (AB[subscript 2]O[subscript 4]) Structure | |
| |
| |
Silicate Structures | |
| |
| |
Compositional Variation in Minerals | |
| |
| |
Substitutional Solid Solution | |
| |
| |
Interstitial Solid Solution | |
| |
| |
Omission Solid Solution | |
| |
| |
Recalculation of Chemical Analyses | |
| |
| |
Graphic Representation of Mineral Composition | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Mineral Reactions, Stability, and Behavior | |
| |
| |
Crystallization | |
| |
| |
Crystal Growth | |
| |
| |
Intergrowth of Crystals | |
| |
| |
Mineral Reactions | |
| |
| |
Reactions in an Igneous Regime | |
| |
| |
Reactions Under Metamorphic Conditions | |
| |
| |
Reactions in a Weathering Environment | |
| |
| |
Ultrahigh-Pressure Reactions | |
| |
| |
Mineral Stability | |
| |
| |
Phase Diagrams | |
| |
| |
Stability, Activation Energy, and Equilibrium | |
| |
| |
Components | |
| |
| |
Introductory Thermodynamics | |
| |
| |
Examples of Mineral Stability (Phase) Diagrams | |
| |
| |
One-Component Diagrams | |
| |
| |
Two-Component Diagrams | |
| |
| |
Three-or More-Component Diagrams | |
| |
| |
Diagrams for Mineral Reactions Involving H[subscript 2]O or CO[subscript 2] | |
| |
| |
Eh-pH Diagrams | |
| |
| |
Polymorphic Reactions | |
| |
| |
Reconstructive Polymorphism | |
| |
| |
Displacive Polymorphism | |
| |
| |
Otder-Disorder Polymorphism | |
| |
| |
Polytypism | |
| |
| |
Exsolution Processes | |
| |
| |
Metamict Minerals | |
| |
| |
Mineraloids (Noncrystalline Minerals) | |
| |
| |
Pseudomorphism | |
| |
| |
Structural Complexities and Defects | |
| |
| |
Twinning | |
| |
| |
Origin of Twinning | |
| |
| |
Origin of Color | |
| |
| |
Crystal Field Transitions | |
| |
| |
Molecular Orbital Transitions | |
| |
| |
Color Centers | |
| |
| |
Other Causes of Color | |
| |
| |
Origin of Magnetic Properties | |
| |
| |
Origin of Radioactivity | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Overview of Crystallographic Concepts | |
| |
| |
From Symmetry Operations to Space Groups | |
| |
| |
Minerals as Crystalline Solids | |
| |
| |
Internal Order | |
| |
| |
Symmetry | |
| |
| |
Crystals and Specific Symmetry Elements | |
| |
| |
Symmetry Elements (Without Translation) | |
| |
| |
Combinations of Rotations | |
| |
| |
Combinations of Rotation Axes and Mirrors | |
| |
| |
Resume of Symmetry Operations Without Translation | |
| |
| |
Crystal Morphology | |
| |
| |
Crystal Symmetry | |
| |
| |
Crystallographic Axes | |
| |
| |
Crystallographic Notation for Planes | |
| |
| |
Crystal Habit | |
| |
| |
Form | |
| |
| |
Some Common Twins | |
| |
| |
Types of Twins | |
| |
| |
Common Twin Laws | |
| |
| |
The Internal Order and Symmetry of Minerals | |
| |
| |
Translations Directions and Distances | |
| |
| |
One-Dimensional Order (Rows) | |
| |
| |
Two-Dimensional Order (Plane Lattices) | |
| |
| |
Symmetry Content of Planar Motifs | |
| |
| |
Symmetry Content of Plane Lattices | |
| |
| |
Two-Dimensional Plane Groups | |
| |
| |
Three-Dimensional Order | |
| |
| |
Space Groups | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Bilateral Symmetry in Humans and Architecture | |
| |
| |
| |
Patterns in Our Environment | |
| |
| |
| |
Selected Point Groups and Space Groups | |
| |
| |
Measurement of Crystal Angles | |
| |
| |
Crystal Projections | |
| |
| |
Spherical Projection | |
| |
| |
Stereographic Projection | |
| |
| |
Nineteen of the Thirty-Two Point Groups | |
| |
| |
Triclinic System | |
| |
| |
Monoclinic System | |
| |
| |
Orthorhombic System | |
| |
| |
Tetragonal System | |
| |
| |
Hexagonal System | |
| |
| |
Isometric System | |
| |
| |
Representation of Some Space Groups | |
| |
| |
Illustration of Space Groups | |
| |
| |
Space Groups as an Expression of Morphology and Structure | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Analytical Methods in Mineral Science | |
| |
| |
Scanning Electron Microscopy (SEM) | |
| |
| |
Optical Microscopy | |
| |
| |
Nature of Light | |
| |
| |
Isotropic and Anisotropic Crystals | |
| |
| |
The Polarizing Microscope | |
| |
| |
Uniaxial Crystals | |
| |
| |
Biaxial Crystals | |
| |
| |
Optical Properties of Opaque Minerals | |
| |
| |
X-Ray Diffraction Techniques (XRD) | |
| |
| |
X-Ray Spectra | |
| |
| |
Diffraction Effects and the Bragg Equation | |
| |
| |
Single-Crystal X-Ray Diffraction and Structure Analysis | |
| |
| |
X-Ray Powder Diffraction and Mineral Identification | |
| |
| |
Transmission Electron Microcopy (TEM) | |
| |
| |
Chemical Analytical Techniques | |
| |
| |
Flame Atomic Absorption Spectroscopy (FAA) | |
| |
| |
X-Ray Fluorescence Analysis (XRF) | |
| |
| |
Electron Microprobe Analysis (EMPA) | |
| |
| |
Secondary Ion Mass Spectrometry (SIMS) | |
| |
| |
Atomic Force Microscopy (AFM) | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Crystal Chemistry and Systematic Descriptions of Native Elements, Sulfides, and Sulfosalts | |
| |
| |
Mineral Classification | |
| |
| |
Crystal Chemistry of Native Elements, Sulfides, and Sulfosalts | |
| |
| |
Native Elements | |
| |
| |
Sulfides | |
| |
| |
Sulfosalts | |
| |
| |
Systematic Descriptions | |
| |
| |
Native Metals | |
| |
| |
Native Nonmetals | |
| |
| |
Sulfides, Sulfarsenides, and Arsenides | |
| |
| |
Sulfosalts | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Diamond Synthesis | |
| |
| |
| |
Veins and Vein Mineralization | |
| |
| |
| |
Sulfide Minerals as Ores and as Mining-Related Contaminants | |
| |
| |
| |
Crystal Chemistry and Systematic Descriptions of Oxides, Hydroxides, and Halides | |
| |
| |
Crystal Chemistry of Oxides | |
| |
| |
Crystal Chemistry of Hydroxides | |
| |
| |
Crystal Chemistry of Halides | |
| |
| |
Systematic Descriptions | |
| |
| |
Oxides | |
| |
| |
Hydroxides | |
| |
| |
Halides | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Ore Minerals for the Steel Industry | |
| |
| |
| |
Evaporite Minerals | |
| |
| |
| |
Crystal Chemistry and Systematic Descriptions of Carbonates, Nitrates, Borates, Sulfates, Chromates, Tungstates, Molyboates, Phosphates, Arsenates and Vanadates | |
| |
| |
Crystal Chemistry of Carbonates | |
| |
| |
Calcite Group | |
| |
| |
Aragonite Group | |
| |
| |
Dolomite Group | |
| |
| |
Crystal Chemistry of Nitrates | |
| |
| |
Crystal Chemistry of Borates | |
| |
| |
Crystal Chemistry of Sulfates | |
| |
| |
Crystal Chemistry of Tungstates and Molybdates | |
| |
| |
Crystal Chemistry of Phosphates, Arsenates, and Vanadates | |
| |
| |
Systematic Descriptions | |
| |
| |
Carbonates | |
| |
| |
Nitrates | |
| |
| |
Borates | |
| |
| |
Sulfates and Chromates | |
| |
| |
Tungstates and Molybdates | |
| |
| |
Phosphates, Arsenates and Vanadates | |
| |
| |
References and Selected Reading | |
| |
| |
| |
The Source of Chemicals in Fertilizers | |
| |
| |
| |
Crystal Chemistry of Rock-Forming Silicates | |
| |
| |
Nesosilicates | |
| |
| |
Sorosilicates | |
| |
| |
Cyclosilicates | |
| |
| |
Inosilicates | |
| |
| |
Pyroxene Group | |
| |
| |
Pyroxenoid Group | |
| |
| |
Amphibole Group | |
| |
| |
Phyllosilicates | |
| |
| |
Tectosilicates | |
| |
| |
SiO[subscript 2] Group | |
| |
| |
Feldspar Group | |
| |
| |
Feldspathoid Group | |
| |
| |
Zeolite Group | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Systematic Descriptions of Rock-Forming Silicates | |
| |
| |
Nesosilicates | |
| |
| |
Phenacite Group | |
| |
| |
Olivine Group | |
| |
| |
Garnet Group | |
| |
| |
Al[subscript 2]SiO[subscript 5] Group | |
| |
| |
Humite Group | |
| |
| |
Sorosilicates | |
| |
| |
Epidote Group | |
| |
| |
Cyclosilicates | |
| |
| |
Inosilicates | |
| |
| |
Pyroxene Group | |
| |
| |
Pyroxenoid Group | |
| |
| |
Amphibole Group | |
| |
| |
Phyllosilicates | |
| |
| |
Serpentine Group | |
| |
| |
Clay Mineral Group | |
| |
| |
Mica Group | |
| |
| |
Chlorite Group | |
| |
| |
Related Species | |
| |
| |
Tectosilicates | |
| |
| |
SiO[subscript 2] Group | |
| |
| |
Feldspar Group | |
| |
| |
Feldspathoid Group | |
| |
| |
Scapolite Series | |
| |
| |
Zeolite Group | |
| |
| |
References and Selected Reading | |
| |
| |
| |
The Two Most Common Rock Types: Basalt and Granite | |
| |
| |
| |
Clay Minerals and some of Their Applications | |
| |
| |
| |
Mineral Dust in the Environment | |
| |
| |
| |
Minerals in Pegmatites | |
| |
| |
| |
Zeolites and their Many Unique Properties | |
| |
| |
| |
Gem Minerals | |
| |
| |
Gem Minerals | |
| |
| |
Gem Qualifications | |
| |
| |
Types of Gem Cuts | |
| |
| |
The Early Uses of Gems | |
| |
| |
Important Gems--Yesterday and Today | |
| |
| |
Diamond | |
| |
| |
Beryl | |
| |
| |
Ruby and Sappire | |
| |
| |
Opal | |
| |
| |
Jade | |
| |
| |
Chrysoberyl | |
| |
| |
Topaz | |
| |
| |
Tourmaline | |
| |
| |
Quartz | |
| |
| |
Turquoise | |
| |
| |
Garnet | |
| |
| |
Zircon | |
| |
| |
Olivine | |
| |
| |
Gem Properties and Instruments for Their Determination | |
| |
| |
Physical Properties | |
| |
| |
Instruments for Studying Gems | |
| |
| |
Synthesis of Gem Materials | |
| |
| |
Verneuil Process | |
| |
| |
Czochralski Process | |
| |
| |
Flux Growth | |
| |
| |
Hydrothermal Growth | |
| |
| |
Treatment of Gemstones | |
| |
| |
Dyeing | |
| |
| |
Heat Treatment | |
| |
| |
Irradiation | |
| |
| |
Synthetic and Treated Gems | |
| |
| |
Beryl | |
| |
| |
Chrysoberyl | |
| |
| |
Corundum (Ruby and Sapphire) | |
| |
| |
Diamond | |
| |
| |
Jade | |
| |
| |
Opal | |
| |
| |
Quartz | |
| |
| |
Rutile | |
| |
| |
Spinel | |
| |
| |
Turquoise | |
| |
| |
Manufactured Gem Materials Without Natural Counterparts | |
| |
| |
Garnet | |
| |
| |
Strontium Titanate, SrTiO[subscript 3] | |
| |
| |
Cubic Zirconia | |
| |
| |
References and Selected Reading | |
| |
| |
| |
Determinative Tables | |
| |
| |
General Classification of the Tables | |
| |
| |
Luster--Metallic or Submetallic | |
| |
| |
Luster--Nonmetallic | |
| |
| |
| |
Minerals Arranged by Several Physical Properties | |
| |
| |
| |
Minerals Arranged According to Increasing Specific Gravity | |
| |
| |
| |
Nonopaque Minerals and Some Synthetic Compounds Arranged According to Increasing Refractive Index | |
| |
| |
Mineral Index | |
| |
| |
Subject Index | |