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| Preface to the Second Edition | |
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| Preface to the First Edition | |
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| Structure of Atoms and Molecules | |
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| Light, Electrons, and Nuclei | |
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| Some Early Experiments in Atomic Physics | |
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| The Nature of Light | |
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| The Bohr Model | |
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| Particle-Wave Duality | |
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| Electronic Properties of Atoms | |
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| Nuclear Binding Energy | |
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| Nuclear Stability | |
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| Types of Nuclear Decay | |
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| Predicting Decay Modes | |
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| Basic Quantum Mechanics and Atomic Structure | |
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| The Postulates | |
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| The Hydrogen Atom | |
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| The Helium Atom | |
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| Slater Wave Functions | |
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| Electron Configurations | |
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| Spectroscopic States | |
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| Covalent Bonding in Diatomic Molecules | |
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| The Basic Ideas of Molecular Orbital Methods | |
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| The H<sub>2</sub><sup>+</sup> and H<sub>2</sub> Molecules | |
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| Diatomic Molecules of Second-Row Elements | |
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| Photoelectron Spectroscopy | |
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| Heteronuclear Diatomic Molecules | |
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| Electronegativity | |
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| Spectroscopic States for Molecules | |
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| A Survey of Inorganic Structures and Bonding | |
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| Structures of Molecules Having Single Bonds | |
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| Resonance and Formal Charge | |
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| Complex Structures: A Preview of Coming Attractions | |
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| Electron-Deficient Molecules | |
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| Structures Having Unsaturated Rings | |
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| Bond Energies | |
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| Symmetry and Molecular Orbitals | |
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| Symmetry Elements | |
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| Orbital Symmetry | |
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| A Brief Look at Group Theory | |
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| Construction of Molecular Orbitals | |
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| Orbitals and Angles | |
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| Simple Calculations Using the H�ckel Method | |
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| Condensed Phases | |
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| Dipole Moments and Intermolecular Interactions | |
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| Dipole Moments | |
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| Dipole-Dipole Forces | |
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| Dipole-Induced Dipole Forces | |
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| London (Dispersion) Forces | |
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| The van der Waals Equation | |
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| Hydrogen Bonding | |
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| Cohesion Energy and Solubility Parameters | |
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| Solvatochromism | |
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| Ionic Bonding and Structures of Solids | |
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| Energetics of Crystal Formation | |
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| Madelung Constants | |
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| The Kapustinskii Equation | |
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| Ionic Sizes and Crystal Environments | |
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| Crystal Structures | |
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| Solubility of Ionic Compounds | |
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| Proton and Electron Affinities | |
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| Structures of Metals | |
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| Defects in Crystals | |
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| Phase Transitions in Solids | |
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| Heat Capacity | |
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| Hardness of Solids | |
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| Dynamic Processes in Inorganic Solids | |
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| Characteristics of Solid-State Reactions | |
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| Kinetic Models for Reactions in Solids | |
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| Thermal Methods of Analysis | |
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| Effects of Pressure | |
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| Reactions in Some Solid Inorganic Compounds | |
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| Phase Transitions | |
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| Reactions at Interfaces | |
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| Diffusion in Solids | |
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| Sintering | |
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| Drift and Conductivity | |
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| Acids, Bases, and Solvents | |
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| Acid-Base Chemistry | |
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| Arrhenius Theory | |
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| Br�nsted-Lowry Theory | |
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| Factors Affecting the Strength of Acids and Bases | |
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| Acid-Base Character of Oxides | |
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| Proton Affinities | |
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| Lewis Theory | |
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| Catalytic Behavior of Acids and Bases | |
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| The Hard-Soft Interaction Principle (HSIP) | |
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| Electronic Polarizabilities | |
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| The Drago Four-Parameter Equation | |
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| Chemistry in Nonaqueous Solvents | |
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| Some Common Nonaqueous Solvents | |
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| The Solvent Concept | |
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| Amphoteric Behavior | |
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| The Coordination Model | |
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| Chemistry in Liquid Ammonia | |
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| Liquid Hydrogen Fluoride | |
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| Liquid Sulfur Dioxide | |
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| Superacids | |
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| Chemistry of the Elements | |
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| Chemistry of Metallic Elements | |
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| The Metallic Elements | |
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| Band Theory | |
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| Groups IA and IIA Metals | |
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| Zintl Phases | |
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| Aluminum and Beryllium | |
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| The First-Row Transition Metals | |
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| Second- and Third-Row Transition Metals | |
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| Alloys | |
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| Chemistry of Transition Metals | |
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| The Lanthanides | |
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| Organometallic Compounds of the Main Group Elements | |
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| Preparation of Organometallic Compounds | |
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| Organometallic Compounds of Group IA Metals | |
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| Organometallic Compounds of Group IIA Metals | |
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| Organometallic Compounds of Group IIIA Metals | |
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| Organometallic Compounds of Group IVA Metals | |
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| Organometallic Compounds of Group VA Elements | |
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| Organometallic Compounds of Zn, Cd, and Hg | |
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| Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen, and Carbon | |
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| Hydrogen | |
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| Boron | |
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| Oxygen | |
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| Carbon | |
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| Chemistry of Nonmetallic Elements II Groups IVA and VA | |
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| The Group IVA Elements | |
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| Nitrogen | |
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| Phosphorus, Arsenic, Antimony, and Bismuth | |
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| Chemistry of Nonmetallic Elements EL Groups VIA-VTIIA | |
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| Sulfur, Selenium, and Tellurium | |
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| The Halogens | |
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| The Noble Gases | |
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| Chemistry of Coordination Compounds | |
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| Introduction to Coordination Chemistry | |
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| Structures of Coordination Compounds | |
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| Metal-Ligand Bonds | |
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| Naming Coordination Compounds | |
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| Isomerism | |
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| A Simple Valence Bond Description of Coordinate Bonds | |
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| Magnetism | |
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| A Survey of Complexes of First-Row Metals | |
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| Complexes of Second- and Third-Row Metals | |
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| The 18-Electron Rule | |
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| Back Donation | |
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| Complexes of Dinitrogen, Dioxygen, and Dihydrogen | |
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| Ligand Fields and Molecular Orbitals | |
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| Splitting of d Orbital Energies in Octahedral Fields | |
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| Splitting of d Orbital Energies in Fields of Other Symmetry | |
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| Factors Affecting � | |
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| Consequences of Crystal Field Splitting | |
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| Jahn-Teller Distortion | |
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| Spectral Bands | |
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| Molecular Orbitals in Complexes | |
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| Interpretation of Spectra | |
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| Splitting of Spectroscopic States | |
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| Orgel Diagrams | |
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| Racah Parameters and Quantitative Methods | |
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| The Nephelauxetic Effect | |
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| Tanabe-Sugano Diagrams | |
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| The Lever Method | |
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| J�rgensen's Method | |
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| Charge Transfer Absorption | |
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| Solvatochromism | |
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| Composition and Stability of Complexes | |
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| Composition of Complexes in Solution | |
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| Job's Method of Continuous Variations | |
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| Equilibria Involving Complexes | |
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| Distribution Diagrams | |
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| Factors Affecting the Stability of Complexes | |
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| Synthesis and Reactions of Coordination Compounds | |
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| Synthesis of Coordination Compounds | |
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| Substitution Reactions in Octahedral Complexes | |
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| Ligand Field Effects | |
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| Acid-Catalyzed Reactions of Complexes | |
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| Base-Catalyzed Reactions of Complexes | |
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| The Compensation Effect | |
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| Linkage Isomerization | |
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| Substitution in Square Planar Complexes | |
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| The Trans Effect | |
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| Electron Transfer Reactions | |
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| Reactions in Solid Coordination Compounds | |
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| Complexes Containing Metal-Carbon and Metal-Metal Bonds | |
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| Binary Metal Carbonyls | |
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| Structures of Metal Carbonyls | |
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| Bonding of Carbon Monoxide to Metals | |
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| Preparation of Metal Carbonyls | |
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| Reactions of Metal Carbonyls | |
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| Structure and Bonding in Metal-Alkene Complexes | |
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| Preparation of Metal-Alkene Complexes | |
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| Chemistry of Cyclopentadienyl and Related Complexes | |
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| Bonding in Ferrocene | |
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| Reactions of Ferrocene and other Metallocenes | |
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| Complexes of Benzene and Related Aromatics | |
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| Compounds Containing Metal-Metal Bonds | |
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| Coordination Compounds in Catalysis | |
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| Elementary Steps in Catalytic Processes | |
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| Homogeneous Catalysis | |
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| Bioinorganic Chemistry | |
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| What Metals Do in Some Living Systems | |
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| Cytotoxicity of Some Metal Compounds | |
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| Antimalarial Metallodrugs | |
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| Ionization Energies | |
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| Character Tables for Selected Point Groups | |
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| Index | |