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Contributors | |
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Introduction | |
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Electronics at the Atomic-Scale | |
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Stm Manipulation of Single Atoms and Molecules on Insulating Films | |
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Introduction | |
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Ultrathin Insulating Films | |
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Interface State in NaCl/Cu(111) | |
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Manipulation of Metal Atoms | |
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Controlling the Charge State | |
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Vertical Transfer and Build-up of Nanostructures | |
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Imaging Molecular Orbitals | |
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Manipulation of Molecules: Molecular/Orbital Engineering | |
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Manipulation of a Small Molecule: Water Dissociation on MgO Films | |
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Organometallic Synthesis: Au-Pentacene | |
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Metai-Ligand Complex Formation | |
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Molecular Switching Based on a Tautomerization Reaction | |
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Conclusion | |
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References | |
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Electron Transfer Phenomena at the Molecular Scale: Organic Charge Transfer Complexes on Metal Surfaces | |
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Introduction | |
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Tcnq on Au(111): The Neutral Adsorption of an Electron Acceptor Molecule | |
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TTF on Au(111): Formation of a Wigner Molecular Lattice | |
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TTF Nucleation: Long-Range Repulsive Versus Short-Range Attractive Interactions | |
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TTF-Tcnq on Au(111): Molecular Magnetism Induced by CT | |
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Conclusions and Remarks | |
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References | |
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Chemistry at the Atomic-Scale | |
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Imprinting Atomic and Molecular Patterns | |
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Single-Molecule Imprinting on Semiconductors | |
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Localized Atomic Reaction | |
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Single Dissociative Attachment 1: Diatomic Molecules at Si(100)-2 x 1 | |
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Single Dissociative Attachment 2: Dissociative Attachment of Polyatomics | |
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Discussion of Single Dissociative Attachment | |
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Multiple Dissociative Attachment | |
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Single-Molecule Imprinting on Metals | |
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Lar on Metals | |
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Self-Assembly Followed by Pattern Imprinting | |
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Imprinting Circles | |
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Forming Lines | |
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Imprinting Lines | |
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Modes of Reaction | |
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Direct and Indirect Reaction | |
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Cooperative Reaction | |
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Chain Reaction | |
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Recoil Reaction | |
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Conclusion | |
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Acknowledgements | |
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References | |
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Tunnel-Current Induced STM Atomic Manipulation | |
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Introduction | |
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Experirnental Methods | |
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Frame-by-Frame Scanning | |
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Single-Point Current Injection | |
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Desorption | |
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Diet and Dimet | |
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Si(100)-2x1:H | |
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Chlorobenzene/Si(11.l)-7x7 | |
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Intramolecular Bond Dissociation | |
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Cypt(ll) | |
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Chlorobenzene/Si(111)-7x7 | |
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Fluoropentane/Si(100) | |
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Nonlocal Manipulation | |
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CH3SSCH3/Au(111) | |
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Chlorobenzene/Si(111)-7x7 | |
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References | |
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Index | |