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Preface | |
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Preface to the First Edition | |
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Symbols and Abbreviations | |
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Short Introduction to Basic Principles and Methods | |
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Chemical shift | |
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Spin-spin coupling and coupling constants | |
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Signal multiplicity (multiplets) | |
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Spectra of first and higher order | |
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Chemical and magnetic equivalence | |
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Fourier transform (FT) NMR spectra | |
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Spin decoupling | |
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Nuclear Overhauser effect | |
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Relaxation, relaxation times | |
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Recognition of Structural Fragments by NMR | |
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Functional groups | |
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[superscript 1]H Chemical Shifts | |
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Deuterium exchange | |
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[superscript 13]C Chemical shifts | |
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[superscript 15]N Chemical shifts | |
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Skeletal structure (atom connectivities) | |
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HH Multiplicities | |
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CH Multiplicities | |
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HH Coupling constants | |
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CH Coupling constants | |
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NH Coupling constants | |
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HH COSY (geminal, vicinal, w-relationships of protons) | |
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CC INADEQUATE (CC bonds) | |
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Two-dimensional carbon-proton shift correlation via one-bond CH coupling | |
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Two-dimensional carbon-proton shift correlation via long-range CH coupling | |
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Relative configuration and conformation | |
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HH Coupling constants | |
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CH Coupling constants | |
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NH Coupling constants | |
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[superscript 13]C Chemical shifts | |
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NOE Difference spectra | |
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HH NOESY and ROESY | |
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Absolute configuration | |
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Diastereotopism | |
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Chiral shift reagents (ee determination) | |
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Intra- and intermolecular interactions | |
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Anisotropic effects | |
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Ring current of aromatic compounds | |
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Intra- and intermolecular hydrogen bonding | |
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Protonation effects | |
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Molecular dynamics (fluxionality) | |
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[superscript 13]C Spin-lattice relaxation times | |
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Summary | |
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Problems | |
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Application of one-dimensional [superscript 1]H NMR | |
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Temperature dependent [superscript 1]H and [superscript 13]C NMR spectra | |
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Application of one-dimensional [superscript 13]C NMR spectra | |
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CC INADEQUATE experiments | |
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Application of one-dimensional [superscript 1]H and [superscript 13]C NMR spectra | |
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Application of one-dimensional [superscript 1]H, [superscript 13]C and [superscript 15]N NMR spectra | |
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Combined application of one and two-dimensional [superscript 1]H and [superscript 13]C NMR experiments | |
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Identification and structural elucidation of of natural products by one and two-dimensional [superscript 1]H and [superscript 13]C NMR | |
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Solutions to Problems | |
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Dimethyl cis-cyclopropane-1,2-dicarboxylate | |
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Ethylacrylate | |
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cis-1-Methoxybut-1-en-3-yne | |
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trans-3-(N-Methylpyrrol-2-yl)propenal | |
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1,9-Bis(pyrrol-2-yl)pyrromethene | |
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3-Acetylpyridine | |
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Anthracene-1,8-dialdehyde | |
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trans-Stilbene-4-aldehyde | |
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6,4'-Dimethoxyisoflavone | |
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Catechol (3,5,7,3',4'-pentahydroxyflavane) | |
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Methyloxirane and monordene | |
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2-Methyl-6-(N,N-dimethylamino)-trans-4-nitro-trans-5-phenylcyclohexene | |
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(E)-3-(N,N-Dimethylamino)acrolein | |
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cis-1,2-Dimethylcyclohexane | |
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5-Ethynyl-2-methylpyridine | |
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5-Hydroxy-3-methyl-1H-pyrazole | |
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o-Hydroxyacetophenone | |
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Potassium 1-acetonyl-2,4,6-trinitrocyclohexa-2,5-dienate | |
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trans-3-[4-(N,N-Dimethylamino)phenyl]-2-ethylpropenal | |
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N-Butylsalicylaldimine | |
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Benzo[b]furan | |
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3-Hydroxypropyl 2-ethylcyclohexa-1,3-diene-5-carboxylate | |
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Hex-3-yn-1-ol | |
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N,N-Diethylamino)ethyl 4-aminobenzoate hydrochloride (procaine hydrochloride) | |
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5,5'-Bis-(hydroxymethyl)-2,2'-bifuran | |
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N-Methyl-6,7-methylenedioxy-1-oxo-1,2,3,4-tetrahydroisoquinoline | |
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Ethoxycarbonyl-4-(3-hydroxypropyl)-1-methylpyrrole | |
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p-Tolylsulphonyl-5-propylpyridine | |
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6-Methoxytetralin-1-one | |
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Triazolo[1,5-a]pyrimidine | |
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6-n-Butyltetrazolo[1,5-a]pyrimidine and 2-azido-5-n-butylpyrimidine | |
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Hydroxyphthalide | |
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Dicyclopentadiene | |
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trans-1-Cyclopropyl-2-methylbuta-1,3-diene | |
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cis-6-Hydroxy-1-methyl-4-isopropylcyclohexene (carveol) | |
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trans-2-Methylcyclopentanol | |
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trans-2-(2-Pyridyl)methylcyclohexanol | |
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Nona-2-trans-6-cis-dienal | |
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2,3-Diaza-7,8,12,13,17,18-hexaethylporphyrin | |
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2-Hydroxy-3,4,3',4'-tetramethoxydeoxybenzoin | |
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3',4',7,8-Tetramethoxyisoflavone | |
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3',4',6,7-Tetramethoxy-3-phenylcoumarin | |
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Aflatoxin B[subscript 1] | |
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1,5-Dimethylcyclohexa-1,3-dien-5-ol-6-one, dimer | |
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Asperuloside | |
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Lacto-N-tetrose | |
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9[beta]-Hydroxycostic acid | |
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14-(Umbelliferon-7-O-yl)driman-3,8-diol | |
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3,4,5-Trimethyl-5,6-dihydronaphtho[2,3-b]furan | |
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Sendarwine | |
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Panaxatriol | |
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trans-N-Methyl-4-methoxyproline | |
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Cocaine hydrochloride | |
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Viridifloric acid 7-retronecine ester (heliospathulin) | |
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Actinomycin-D | |
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References | |
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Formula index of solutions to problems | |
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Subject index | |