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Structure Elucidation by NMR in Organic Chemistry A Practical Guide

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ISBN-10: 0471933813

ISBN-13: 9780471933816

Edition: 1st 1993

Authors: Eberhard Breitmaier

List price: $68.50
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Book details

List price: $68.50
Edition: 1st
Copyright year: 1993
Publisher: John Wiley & Sons, Incorporated
Publication date: 4/27/1993
Binding: Paperback
Pages: 278
Size: 7.34" wide x 9.65" long x 0.73" tall
Weight: 1.320
Language: English

Eberhard Breitmaier received his PhD at the University of T8bingen, Germany, as a member of the research group of Ernst Bayer. After a postdoctoral stay followed by a position as assistant professor at the University of Houston, Texas, he returned to T8bingen to gain his lecturing qualification in 1971. He was Professor for Organic and Analytical Chemistry at the University of Bonn from 1975 until 2004. His research focuses on 3-alkoxyacroleine as a reagent for chemical syntheses, porphyrinoid annulenes and natural products. Professor Breitmaier has authored many scientific publications and several textbooks on NMR-spectroscopy, organic chemistry and natural products.

Preface
Preface to the First Edition
Symbols and Abbreviations
Short Introduction to Basic Principles and Methods
Chemical shift
Spin-spin coupling and coupling constants
Signal multiplicity (multiplets)
Spectra of first and higher order
Chemical and magnetic equivalence
Fourier transform (FT) NMR spectra
Spin decoupling
Nuclear Overhauser effect
Relaxation, relaxation times
Recognition of Structural Fragments by NMR
Functional groups
[superscript 1]H Chemical Shifts
Deuterium exchange
[superscript 13]C Chemical shifts
[superscript 15]N Chemical shifts
Skeletal structure (atom connectivities)
HH Multiplicities
CH Multiplicities
HH Coupling constants
CH Coupling constants
NH Coupling constants
HH COSY (geminal, vicinal, w-relationships of protons)
CC INADEQUATE (CC bonds)
Two-dimensional carbon-proton shift correlation via one-bond CH coupling
Two-dimensional carbon-proton shift correlation via long-range CH coupling
Relative configuration and conformation
HH Coupling constants
CH Coupling constants
NH Coupling constants
[superscript 13]C Chemical shifts
NOE Difference spectra
HH NOESY and ROESY
Absolute configuration
Diastereotopism
Chiral shift reagents (ee determination)
Intra- and intermolecular interactions
Anisotropic effects
Ring current of aromatic compounds
Intra- and intermolecular hydrogen bonding
Protonation effects
Molecular dynamics (fluxionality)
[superscript 13]C Spin-lattice relaxation times
Summary
Problems
Application of one-dimensional [superscript 1]H NMR
Temperature dependent [superscript 1]H and [superscript 13]C NMR spectra
Application of one-dimensional [superscript 13]C NMR spectra
CC INADEQUATE experiments
Application of one-dimensional [superscript 1]H and [superscript 13]C NMR spectra
Application of one-dimensional [superscript 1]H, [superscript 13]C and [superscript 15]N NMR spectra
Combined application of one and two-dimensional [superscript 1]H and [superscript 13]C NMR experiments
Identification and structural elucidation of of natural products by one and two-dimensional [superscript 1]H and [superscript 13]C NMR
Solutions to Problems
Dimethyl cis-cyclopropane-1,2-dicarboxylate
Ethylacrylate
cis-1-Methoxybut-1-en-3-yne
trans-3-(N-Methylpyrrol-2-yl)propenal
1,9-Bis(pyrrol-2-yl)pyrromethene
3-Acetylpyridine
Anthracene-1,8-dialdehyde
trans-Stilbene-4-aldehyde
6,4'-Dimethoxyisoflavone
Catechol (3,5,7,3',4'-pentahydroxyflavane)
Methyloxirane and monordene
2-Methyl-6-(N,N-dimethylamino)-trans-4-nitro-trans-5-phenylcyclohexene
(E)-3-(N,N-Dimethylamino)acrolein
cis-1,2-Dimethylcyclohexane
5-Ethynyl-2-methylpyridine
5-Hydroxy-3-methyl-1H-pyrazole
o-Hydroxyacetophenone
Potassium 1-acetonyl-2,4,6-trinitrocyclohexa-2,5-dienate
trans-3-[4-(N,N-Dimethylamino)phenyl]-2-ethylpropenal
N-Butylsalicylaldimine
Benzo[b]furan
3-Hydroxypropyl 2-ethylcyclohexa-1,3-diene-5-carboxylate
Hex-3-yn-1-ol
N,N-Diethylamino)ethyl 4-aminobenzoate hydrochloride (procaine hydrochloride)
5,5'-Bis-(hydroxymethyl)-2,2'-bifuran
N-Methyl-6,7-methylenedioxy-1-oxo-1,2,3,4-tetrahydroisoquinoline
Ethoxycarbonyl-4-(3-hydroxypropyl)-1-methylpyrrole
p-Tolylsulphonyl-5-propylpyridine
6-Methoxytetralin-1-one
Triazolo[1,5-a]pyrimidine
6-n-Butyltetrazolo[1,5-a]pyrimidine and 2-azido-5-n-butylpyrimidine
Hydroxyphthalide
Dicyclopentadiene
trans-1-Cyclopropyl-2-methylbuta-1,3-diene
cis-6-Hydroxy-1-methyl-4-isopropylcyclohexene (carveol)
trans-2-Methylcyclopentanol
trans-2-(2-Pyridyl)methylcyclohexanol
Nona-2-trans-6-cis-dienal
2,3-Diaza-7,8,12,13,17,18-hexaethylporphyrin
2-Hydroxy-3,4,3',4'-tetramethoxydeoxybenzoin
3',4',7,8-Tetramethoxyisoflavone
3',4',6,7-Tetramethoxy-3-phenylcoumarin
Aflatoxin B[subscript 1]
1,5-Dimethylcyclohexa-1,3-dien-5-ol-6-one, dimer
Asperuloside
Lacto-N-tetrose
9[beta]-Hydroxycostic acid
14-(Umbelliferon-7-O-yl)driman-3,8-diol
3,4,5-Trimethyl-5,6-dihydronaphtho[2,3-b]furan
Sendarwine
Panaxatriol
trans-N-Methyl-4-methoxyproline
Cocaine hydrochloride
Viridifloric acid 7-retronecine ester (heliospathulin)
Actinomycin-D
References
Formula index of solutions to problems
Subject index