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| Elements of Reaction Kinetics | |
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| Definitions of Chemical Rates | |
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| Rate Equations | |
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| Coupled Reactions | |
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| Reducing the Size of Kinetic Models | |
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| Bio-Kinetics | |
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| Complex Reactions | |
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| Modeling the Rate Coefficient | |
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| Kinetics of Heterogeneous Catalytic Reactions | |
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| Introduction | |
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| Adsorption on Solid Catalysts | |
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| Rate Equations | |
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| Complex Catalytic Reactions | |
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| Experimental Reactors | |
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| Model Discrimination and Parameter Estimation | |
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| Sequential Design of Experiments | |
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| Expert Systems in Kinetics Studies | |
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| Transport Processes with Reactions Catalyzed by Solids | |
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| Interfacial Gradient Effects | |
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| Reaction of a component of a fluid at the surface of a solid | |
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| Mass and heat transfer resistances | |
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| Concentration or partial pressure and temperature differences | |
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| Intraparticle Gradient Effects | |
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| Molecular-, Knudsen-, and surface diffusion in pores | |
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| Diffusion in a catalyst particle | |
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| Diffusion and reaction in a catalyst particle. A continuum model | |
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| Falsification of rate coefficient and activation energy by diffusion limitations | |
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| Influence of diffusion limitations on the selectivities of coupled reactions | |
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| Criteria for the importance of intraparticle diffusion limitations | |
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| Multiplicity of steady states in catalyst particles | |
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| Combination of external and internal diffusion limitations | |
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| Diagnostic experimental criteria for the absence of internal and external mass transfer limitations | |
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| Nonisothermal particles | |
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| Noncatalytic Gas-Solid Reactions | |
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| A Qualitative Discussion of Gas-Solid Reactions | |
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| General Model with Interfacial and Intraparticle Gradients | |
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| Heterogeneous Model with Shrinking Unreacted Core | |
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| Models Accounting Explicitly for the Structure of the Solid | |
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| On the Use of More Complex Kinetic Equations | |
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| Catalyst Deactivation | |
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| Types of Catalyst Deactivation | |
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| Kinetics of Catalyst Poisoning | |
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| Kinetics of Catalyst Deactivation by Coke Formation | |
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| Gas-Liquid Reactions | |
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| Introduction | |
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| Models for Transfer at a Gas-Liquid Interface | |
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| Two-Film Theory | |
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| Surface Renewal Theory | |
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| Experimental Determination of the Kinetics of Gas-Liquid Reactions | |
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| The Modeling of Chemical Reactors | |
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| Approach | |
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| Aspects of Mass-, Heat- and Momentum Balances | |
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| The Fundamental Model Equations | |
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| The Batch and Semibatch Reactors | |
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| Introduction | |
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| The Isothermal Batch Reactor | |
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| The Nonisothermal Batch Reactor | |
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| Semibatch Reactor Modeling | |
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| Optimal Operation Policies and Control Strategies | |
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| The Plug Flow Reactor | |
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| The Continuity, Energy, and Momentum Equations | |
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| Kinetic Studies Using a Tubular Reactor with Plug Flow | |
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| Design and Simulation of Tubular Reactors with Plug Flow | |
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| The Perfectly Mixed Flow Reactor | |
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| Introduction | |
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| Mass and Energy Balances | |
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| Design for Optimum Selectivity in Simultaneous Reactions | |
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| Stability of Operation and Transient Behavior | |
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| Fixed Bed Catalytic Reactors | |
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| Introduction | |
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| The Importance and Scale of Fixed Bed Catalytic Processes | |
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| Factors of Progress: Technological Innovations and Increased Fundamental Insight | |
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| Factors Involved in the Preliminary Design of Fixed Bed Reactors | |
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| Modeling of Fixed Bed Reactors | |
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| Pseudohomogeneous Models | |
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| The Basic One-Dimensional Model | |
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| One-Dimensional Model with Axial Mixing | |
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| Two-Dimensional Pseudohomogeneous Models | |
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| Heteorgeneous Models | |
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| One-Dimensional Model Accounting for Interfacial Gradients | |
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| One-Dimensional Model Accounting for Interfacial and Intraparticle Gradients | |
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| Two-Dimensional Heterogeneous Models | |
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| Complex Flow Patterns | |
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| Introduction | |
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| Macro- and Micro-Mixing in Reactors | |
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| Models Explicitly Accounting for Mixing | |
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| Micro- Probability Density Function Methods | |
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| Micro-PDF Moment Methods: Computational Fluid Dynamics | |
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| Macro-PDF / Residence Time Distribution Methods | |
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| Semi-Empirical Models for Reactors with Complex Flow Patterns | |
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| Fluidized Bed and Transport Reactors | |
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| Introduction | |
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| Technological Aspects of Fluidized Bed and Riser Reactors | |
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| Some Features of the Fluidization and Transport of Solids | |
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| Heat Transfert in Fluidized Beds | |
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| Modeling of Fluidized Bed Reactors | |
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| Modeling of a Transport of Riser Reactor | |
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| Fluidized Bed Reactor Models Considering Detailed Flow Patterns | |
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| Catalytic Cracking of Vacuum Gas Oil | |
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| Multiphase Flow Reactors | |
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| Types of Multiphase Flow Reactors | |
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| Design Models for Multiphase Flow Reactors | |
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| Specific Design Aspects | |