| |
| |
| |
Introduction | |
| |
| |
| |
What Is a Polymer | |
| |
| |
| |
How Polymers Are Depicted | |
| |
| |
| |
Reasons for Interest in Organic Polymers | |
| |
| |
| |
Types of Inorganic Polymers | |
| |
| |
| |
Special Characteristics of Polymers | |
| |
| |
| |
Characterization of Inorganic Polymers | |
| |
| |
| |
Molecular Weights | |
| |
| |
| |
Molecular Weight Distribution | |
| |
| |
| |
Other Structural Features | |
| |
| |
| |
Chain Statistics | |
| |
| |
| |
Solubility Considerations | |
| |
| |
| |
Crystallinity | |
| |
| |
| |
Transitions | |
| |
| |
| |
Spectroscopy | |
| |
| |
| |
Mechanical Properties | |
| |
| |
| |
Polyphosphazenes | |
| |
| |
| |
Introduction | |
| |
| |
| |
History | |
| |
| |
| |
Alternative Synthesis Routes to Linear Polymers | |
| |
| |
| |
Surface Reactions of Polyphosphazenes | |
| |
| |
| |
Hybrid Systems through Block, Comb, or Ring-Linked Copolymers | |
| |
| |
| |
Hybrid Systems through Composites | |
| |
| |
| |
Organometallic Polyphosphazenes | |
| |
| |
| |
Small-Molecule Models | |
| |
| |
| |
Molecular Structure of Linear Polyphosphazenes | |
| |
| |
| |
Structure-Property Relationships | |
| |
| |
| |
Applications of Polyphosphazenes | |
| |
| |
| |
Optical and Photonic Polymers | |
| |
| |
| |
Polymers Related to Polyphosphazenes | |
| |
| |
| |
Conclusions | |
| |
| |
| |
Polysiloxanes and Related Polymers | |
| |
| |
| |
Introduction | |
| |
| |
| |
History | |
| |
| |
| |
Nomenclature | |
| |
| |
| |
Preparation and Analysis | |
| |
| |
| |
General Properties | |
| |
| |
| |
Reactive Homopolymers | |
| |
| |
| |
Elastomeric Networks | |
| |
| |
| |
Some New Characterization Techniques Useful for Polysiloxanes | |
| |
| |
| |
Copolymers and Interpenetrating Networks | |
| |
| |
| |
Applications | |
| |
| |
| |
Polysilanes and Related Polymers | |
| |
| |
| |
Introduction | |
| |
| |
| |
History | |
| |
| |
| |
Synthesis | |
| |
| |
| |
Chemical Modification of Polysilanes | |
| |
| |
| |
Physical Properties of Polysilanes | |
| |
| |
| |
Electronic Properties of Polysilanes | |
| |
| |
| |
Chromotropsism of Polysilanes | |
| |
| |
| |
Electrical Conductivity and Photoconductivity | |
| |
| |
| |
Luminescence of Polysilanes | |
| |
| |
| |
Photodegradation of Polysilanes | |
| |
| |
| |
Cross-Linking | |
| |
| |
| |
Structural Arrangements in Polysilanes | |
| |
| |
| |
Technology of Polysilanes | |
| |
| |
| |
Additional Readings | |
| |
| |
| |
Ferrocene-Based Polymers, and Additional Phosphorus- and Boron-Containing Polymers | |
| |
| |
| |
Ferrocene-Based Polymers | |
| |
| |
| |
Other Phosphorus-Containing Polymers | |
| |
| |
| |
Boron-Containing Polymers | |
| |
| |
| |
Miscellaneous Inorganic Polymers | |
| |
| |
| |
Introduction | |
| |
| |
| |
Other Silicon-Containing Polymers | |
| |
| |
| |
Polygermanes | |
| |
| |
| |
Polymeric Sulfur and Selenium | |
| |
| |
| |
Other Sulfer-Containing Polymers | |
| |
| |
| |
Aluminum-Containing Polymers | |
| |
| |
| |
Tin-Containing Polymers | |
| |
| |
| |
Arsenic-Containing Polymers | |
| |
| |
| |
Metal Organometallic Polymers | |
| |
| |
| |
Other Organometallic Species for Sol-Gel Processes | |
| |
| |
| |
Inorganic-Organic Hybrid Composites | |
| |
| |
| |
Sol-Gel Ceramics | |
| |
| |
| |
Fillers in Elastomers | |
| |
| |
| |
Polymer-Modified Ceramics | |
| |
| |
| |
Preceramic Inorganic Polymers | |
| |
| |
| |
Overview of Ceramic Aspects | |
| |
| |
| |
The Sol-Gel Process to Oxide Ceramics | |
| |
| |
| |
Carbon Filter | |
| |
| |
| |
Silicon Carbide | |
| |
| |
| |
Silicon Nitride | |
| |
| |
| |
Boron Nitride | |
| |
| |
| |
Boron Carbide | |
| |
| |
| |
Aluminum Nitride | |
| |
| |
| |
Phosphorus Nitride | |
| |
| |
| |
Poly(ferrocenylsilanes) as Ceramic Precursors | |