| |
| |
Preface to Fourth Edition | |
| |
| |
Acknowledgments | |
| |
| |
Authors | |
| |
| |
Introduction | |
| |
| |
| |
Pollutants and Their Fate in Ecosystems | |
| |
| |
| |
Major Classes of Pollutants | |
| |
| |
| |
Inorganic Ions | |
| |
| |
| |
Metals | |
| |
| |
| |
Anions | |
| |
| |
| |
Organic Pollutants | |
| |
| |
| |
Hydrocarbons | |
| |
| |
| |
Polychlorinated Biphenyls (PCBs) | |
| |
| |
| |
Polychlorinated Benzodioxins (PCDDs) | |
| |
| |
| |
Polychlorinated Dibenzofurans (PCDFs) | |
| |
| |
| |
Polybrominated Biphenyls (PBBs) | |
| |
| |
| |
Organochlorine Insecticides | |
| |
| |
| |
Organophosphorous Insecticides (OPs) | |
| |
| |
| |
Carbamate Insecticides | |
| |
| |
| |
Pyrethroid Insecticides | |
| |
| |
| |
Neonicotinoids | |
| |
| |
| |
Phenoxy Herbicides (Plant Growth Regulators) | |
| |
| |
| |
Anticoagulant Rodenticides | |
| |
| |
| |
Detergents | |
| |
| |
| |
Chlorophenols | |
| |
| |
| |
Ethinylestradiol (EE2) | |
| |
| |
| |
Pharmaceuticals | |
| |
| |
| |
Organometallic Compounds | |
| |
| |
| |
Radioactive Isotopes | |
| |
| |
| |
Introduction | |
| |
| |
| |
Natures and Intensities of Radioactive Decay Products | |
| |
| |
| |
Half-Lives | |
| |
| |
| |
Biochemistry | |
| |
| |
| |
Gaseous Pollutants | |
| |
| |
| |
Nanoparticles | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Routes by which Pollutants Enter Ecosystems | |
| |
| |
| |
Entry into Surface Waters | |
| |
| |
| |
Contamination of Land | |
| |
| |
| |
Discharge into Atmosphere | |
| |
| |
| |
Quantification of Release of Pollutants | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Long-Range Movements and Global Transport of Pollutants | |
| |
| |
| |
Factors Determining Movements and Distributions of Pollutants | |
| |
| |
| |
Polarity and Water Solubility | |
| |
| |
| |
Partition Coefficients | |
| |
| |
| |
Vapor Pressure | |
| |
| |
| |
Partition between Environmental Compartments | |
| |
| |
| |
Molecular Stability and Recalcitrant Molecules | |
| |
| |
| |
Transport in Water | |
| |
| |
| |
Transport in Air | |
| |
| |
| |
Models for Environmental Distribution of Chemicals | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
The Fate of Metals and Radioactive Isotopes in Contaminated Ecosystems | |
| |
| |
| |
Introduction | |
| |
| |
| |
Localization | |
| |
| |
| |
Persistence | |
| |
| |
| |
Bioconcentration and Bioaccumulation Factors | |
| |
| |
| |
Bioavailability | |
| |
| |
| |
Cocktails of Inorganic Pollutants | |
| |
| |
| |
Terrestrial Ecosystems | |
| |
| |
| |
Introduction | |
| |
| |
| |
Metals | |
| |
| |
| |
Radioactivity | |
| |
| |
| |
Aquatic Systems | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Fates of Organic Pollutants in Individuals and in Ecosystems | |
| |
| |
| |
Fate within Individual Organisms | |
| |
| |
| |
General Model | |
| |
| |
| |
Processes of Uptake | |
| |
| |
| |
Processes of Distribution | |
| |
| |
| |
Storage | |
| |
| |
| |
Metabolism | |
| |
| |
| |
Sites of Excretion | |
| |
| |
| |
Toxicokinetic Models | |
| |
| |
| |
Toxicokinetic Models for Bioconcentration and Bioaccumulation | |
| |
| |
| |
Organic Pollutants in Terrestrial Ecosystems | |
| |
| |
| |
Fate in Soils | |
| |
| |
| |
Transfer along Terrestrial Food Chains | |
| |
| |
| |
Organic Pollutants in Aquatic Ecosystems | |
| |
| |
| |
Pollutants in Sediments | |
| |
| |
| |
Transfer along Aquatic Food Chains | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Effects of Pollutants on Individual Organisms | |
| |
| |
| |
Testing for Ecotoxicity | |
| |
| |
| |
General Principles | |
| |
| |
| |
Determination of Toxicities of Mixtures | |
| |
| |
| |
Toxicity Testing with Terrestrial Organisms | |
| |
| |
| |
Introduction | |
| |
| |
| |
Invertebrate Testing | |
| |
| |
| |
Testing with Earthworms | |
| |
| |
| |
Tests with Springtails | |
| |
| |
| |
Tests with Beneficial Arthropods | |
| |
| |
| |
Automated Videotracking | |
| |
| |
| |
Vertebrates | |
| |
| |
| |
Plants | |
| |
| |
| |
Toxicity Testing with Aquatic Organisms | |
| |
| |
| |
Tests for Direct Absorption from Water | |
| |
| |
| |
Sediment Toxicity Tests | |
| |
| |
| |
Risk Assessment | |
| |
| |
| |
Field Testing for Toxicity | |
| |
| |
| |
Alternative Methods in Ecotoxicity Testing | |
| |
| |
| |
Alternative Methods for Estimating Toxicity to Vertebrates | |
| |
| |
| |
Toxicity Testing on Live Vertebrates | |
| |
| |
| |
Toxicity Testing on Nonvertebrates | |
| |
| |
| |
Toxicity Testing on Cellular Systems | |
| |
| |
| |
Predictive Models | |
| |
| |
| |
Alternative Approaches toward More Ecological End Points | |
| |
| |
| |
Field Studies | |
| |
| |
| |
Microcosms and Msocosms | |
| |
| |
| |
Theoretical Models | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Biochemical Effects of Pollutants | |
| |
| |
| |
Introduction | |
| |
| |
| |
Protective Biochemical Responses | |
| |
| |
| |
Molecular Mechanisms of Toxicity | |
| |
| |
| |
Examples of Molecular Mechanisms of Toxicity | |
| |
| |
| |
Genotoxic Compounds | |
| |
| |
| |
Neurotoxic Compounds | |
| |
| |
| |
Mitochondrial Poisons | |
| |
| |
| |
Vitamin K Antagonists | |
| |
| |
| |
Thyroxine Antagonists | |
| |
| |
| |
Inhibition of ATPases | |
| |
| |
| |
Environmental Estrogens and Androgens | |
| |
| |
| |
Reactions with Protein Sulfhydryl (SH) Groups | |
| |
| |
| |
Photosystems of Plants | |
| |
| |
| |
Plant Growth Regulator Herbicides | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Physiological Effects of Pollutants | |
| |
| |
| |
Introduction | |
| |
| |
| |
Effects of Pollutants at Cellular Level | |
| |
| |
| |
Effects at Organ Level in Animals | |
| |
| |
| |
Effects at Whole Organism Level | |
| |
| |
| |
Neurophysiological Effects | |
| |
| |
| |
Effects on Behavior | |
| |
| |
| |
Reproductive Effects | |
| |
| |
| |
Effects on Plants | |
| |
| |
| |
Energy Costs of Physiological Change | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Interactive Effects of Pollutants | |
| |
| |
| |
Introduction | |
| |
| |
| |
Additive Effects | |
| |
| |
| |
Potentiation of Toxicity | |
| |
| |
| |
Potentiation Due to Inhibition of Detoxification | |
| |
| |
| |
Potentiation from Increased Activation | |
| |
| |
| |
Field Detection of Potentiation | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Biomarkers | |
| |
| |
| |
Classification of Biomarkers | |
| |
| |
| |
Specificity of Biomarkers | |
| |
| |
| |
Relationship of Biomarkers to Adverse Effects | |
| |
| |
| |
Specific Biomarkers | |
| |
| |
| |
Inhibition of Esterases | |
| |
| |
| |
The Induction of Monooxygenases | |
| |
| |
| |
Studies of Genetic Materials | |
| |
| |
| |
Porphyrins and Heme Synthesis | |
| |
| |
| |
Induction of Vitellogenin | |
| |
| |
| |
Behavioral Biomarkers | |
| |
| |
| |
Biomarkers in Plants | |
| |
| |
| |
Role of Biomarkers in Environmental Risk Assessment | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
In Situ Biological Monitoring | |
| |
| |
| |
Introduction | |
| |
| |
| |
Community Effects (Type 1 Biomonitoring) | |
| |
| |
| |
Terrestrial Ecosystems | |
| |
| |
| |
Freshwater Ecosystems | |
| |
| |
| |
Marine Ecosystems | |
| |
| |
| |
Bioconcentration of Pollutants (Type 2 Biomonitoring) | |
| |
| |
| |
Terrestrial Ecosystems | |
| |
| |
| |
Freshwater Ecosystems | |
| |
| |
| |
Marine Ecosystems | |
| |
| |
| |
Effects of Pollutants (Type 3 Biomonitoring) | |
| |
| |
| |
Terrestrial Ecosystems | |
| |
| |
| |
Freshwater Ecosystems | |
| |
| |
| |
Marine Ecosystems | |
| |
| |
| |
Genetically Based Resistance to Pollution (Type 4 Biomonitoring) | |
| |
| |
| |
Conclusions | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Effects of Pollutants on Populations and Communities | |
| |
| |
| |
Changes in Numbers: Population Dynamics | |
| |
| |
| |
Population Abundance | |
| |
| |
| |
Population Growth Rate | |
| |
| |
| |
Population Growth Rate Depends on the Properties of Individual Organisms | |
| |
| |
| |
The Life History and Population Growth Rate of the Coastal Copepod Eurytemora affinis | |
| |
| |
| |
Density Dependence | |
| |
| |
| |
Identifying Which Factors Are Density Dependent: k-Value Analysis | |
| |
| |
| |
Interactions between Species | |
| |
| |
| |
Field Studies: Three Case Studies | |
| |
| |
| |
The Decline of the Partridges | |
| |
| |
| |
Population Studies of Pesticides and Birds of Prey in the UK | |
| |
| |
| |
The Boxworth Project (Experimental Analysis of the Effects of Pesticides on Farmland) | |
| |
| |
| |
Modeling the Effects of Insecticides on Skylarks for Risk Assessment Purposes | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Evolution of Resistance to Pollution | |
| |
| |
| |
Chronic Pollution Is Environmental Change | |
| |
| |
| |
Evolutionary Processes in Constant Environments | |
| |
| |
| |
The Evolution of Resistance When There Is a Mortality-Production Trade-Off | |
| |
| |
| |
Evolutionary Responses to Environmental Changes | |
| |
| |
| |
Monogenic Resistance | |
| |
| |
| |
Case Studies | |
| |
| |
| |
Evolution of Pesticide Resistance | |
| |
| |
| |
Evolution of Metal Tolerance in Plants | |
| |
| |
| |
Evolution of Industrial Melanism | |
| |
| |
| |
Evolutionary Response of Dog Whelks, Nucella lapillus, to TBT Contamination | |
| |
| |
| |
Evolution of Resistance to Pollution in Estuaries | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Changes in Communities and Ecosystems | |
| |
| |
| |
Introduction | |
| |
| |
| |
Changes in Soil Processes: The Functional Approach | |
| |
| |
| |
Changes in Compositions of Communities: The Structural Approach | |
| |
| |
| |
Changes in Soil Ecosystems | |
| |
| |
| |
Acidification of Lakes and Rivers | |
| |
| |
| |
Mesocosms | |
| |
| |
| |
Global Processes | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Extrapolating from Molecular Interactions to Consequent Effects at Population Level | |
| |
| |
| |
Introduction | |
| |
| |
| |
Translation of Toxic Effects across Organizational Boundaries | |
| |
| |
| |
From Effects at Site of Action to Localized Cellular Disturbances | |
| |
| |
| |
Example A: Action of Organophosphates on Acetylcholinesterase of Nervous System | |
| |
| |
| |
Example B: Action of p,p'-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes | |
| |
| |
| |
Example C: Action of p,p'-DDE on Transport of Calcium into Eggshell Glands of Birds | |
| |
| |
| |
Example D: Action of 17A-Ethinylestradiol (EE2) on Estrogenic Receptors of Fish | |
| |
| |
| |
From Cellular Disturbances to Effects at Whole Organism Level | |
| |
| |
| |
Example A: Action of Organophosphates on Acetylcholinesterase of Nervous System | |
| |
| |
| |
Example B: Action of p,p'-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes | |
| |
| |
| |
Example C: Action of p,p'-DDE on Transport of Calcium into Eggshell Glands of Birds | |
| |
| |
| |
Example D: Action of 17A-Ethinylestradiol on Estrogenic Receptors of Fish | |
| |
| |
| |
From Effects on Whole Organism to Population Effects | |
| |
| |
| |
Example A: Action of Organophosphates on Acetylcholinesterase of Nervous System | |
| |
| |
| |
Example B: Action of p,p'-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes | |
| |
| |
| |
Example C: Action of p,p'-DDE on Transport of Calcium into Eggshell Glands | |
| |
| |
| |
Example D: Action of 17A-Ethinylestradiol on Estrogenic Receptors in Fish | |
| |
| |
| |
Complete Causal Chain | |
| |
| |
| |
Biomarker Strategies | |
| |
| |
| |
Establishing Causality Where Pollution Already Exists | |
| |
| |
| |
Biomarker Strategies in the Field | |
| |
| |
| |
Control Problems | |
| |
| |
| |
Selection of Biomarkers for Field Studies | |
| |
| |
| |
Biomarkers and Environmental Risk Assessment | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Biomarkers in Population Studies | |
| |
| |
| |
DDE-Induced Eggshell Thinning in Raptorial and Fish-Eating Birds | |
| |
| |
| |
Reproductive Failure of Fish-Eating Birds on Great Lakes of North America | |
| |
| |
| |
Reproductive Failures of Mollusks Caused by Tributyl Tin | |
| |
| |
| |
Forest Spraying in Eastern Canada to Control Spruce Budworm | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
| |
Ecotoxicology: Looking to the Future | |
| |
| |
| |
Changing Patterns of Chemical Pollution | |
| |
| |
| |
Environmental Risk Assessment | |
| |
| |
| |
The Use of Models in Population Risk Assessment | |
| |
| |
| |
Technological Advances and New Biomarker Assays | |
| |
| |
| |
A Better Integrated Approach to Environmental Risk Assessment? | |
| |
| |
| |
Ethical Issues | |
| |
| |
| |
Summary | |
| |
| |
Further Reading | |
| |
| |
Glossary | |
| |
| |
Bibliography | |
| |
| |
Index | |