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Phase Transformations in Metals and Alloys

ISBN-10: 1420062107
ISBN-13: 9781420062106
Edition: 3rd 2011 (Revised)
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Description: Phase Transformations in Metals and Alloys, Third Edition provides a comprehensive overview of specific types of phase transformations, supplemented by practical case studies of engineering alloys. This new edition now addresses computer-aided  More...

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Book details

List price: $87.95
Edition: 3rd
Copyright year: 2011
Publisher: CRC Press LLC
Publication date: 2/10/2009
Binding: Paperback
Pages: 520
Size: 6.00" wide x 9.00" long x 1.00" tall
Weight: 1.848
Language: English

Phase Transformations in Metals and Alloys, Third Edition provides a comprehensive overview of specific types of phase transformations, supplemented by practical case studies of engineering alloys. This new edition now addresses computer-aided calculation of phase diagrams, which has undergone major changes in recent years. It also expands treatment of bainite transformation, nucleation, metallic glasses, steel, and Scheil's additivity rule for appreciating transformations during continuous cooling. Adding new case studies, detailed examples, and exercises drawn from current applications, this text features an easy-to-follow style that integrates basic and advanced material, making it ideal for newcomers to the field.

Preface to the Third Edition
Preface to the Second Edition
Preface to the First Edition
Authors
Thermodynamics and Phase Diagrams
Equilibrium
Single-Component Systems
Gibbs Free Energy as a Function of Temperature
Pressure Effects
Driving Force for Solidification
Binary Solutions
Gibbs Free Energy of Binary Solutions
Ideal Solutions
Chemical Potential
Regular Solutions
Activity
Real Solutions
Ordered Phases
Intermediate Phases
Equilibrium in Heterogeneous Systems
Binary Phase Diagrams
Simple Phase Diagram
Systems with a Miscibility Gap
Ordered Alloys
Simple Eutectic Systems
Phase Diagrams Containing Intermediate Phases
Gibbs Phase Rule
Effect of Temperature on Solid Solubility
Equilibrium Vacancy Concentration
Influence of Interfaces on Equilibrium
Ternary Equilibrium
Additional Thermodynamic Relationships for Binary Solutions
Computation of Phase Diagrams
Pure Stoichiometric Substances
Solution Phases
Substitutional Solutions
Kinetics of Phase Transformations
Exercises
References
Further Reading
Diffusion
Atomic Mechanisms of Diffusion
Interstitial Diffusion
Interstitial Diffusion as a Random Jump Process
Effect of Temperature-Thermal Activation
Steady-State Diffusion
Nonsteady-State Diffusion
Solutions to the Diffusion Equation
Homogenization
Carburization of Steel
Substitutional Diffusion
Self-Diffusion
Vacancy Diffusion
Diffusion in Substitutional Alloys
Diffusion in Dilute Substitutional Alloys
Atomic Mobility
Tracer Diffusion in Binary Alloys
Diffusion in Ternary Alloys
High-Diffusivity Paths
Diffusion along Grain Boundaries and Free Surfaces
Diffusion along Dislocations
Diffusion in Multiphase Binary Systems
Exercises
References
Further Reading
Crystal Interfaces and Microstructure
Interfacial Free Energy
Solid/Vapor Interfaces
Boundaries in Single-Phase Solids
Low-Angle and High-Angle Boundaries
Special High-Angle Grain Boundaries
Equilibrium in Polycrystalline Materials
Thermally Activated Migration of Grain Boundaries
Kinetics of Grain Growth
Interphase Interfaces in Solids
Interface Coherence
Fully Coherent Interfaces
Semicoherent Interfaces
Incoherent Interfaces
Complex Semicoherent Interfaces
Second-Phase Shape: Interfacial Energy Effects
Fully Coherent Precipitates
Partially Coherent Precipitates
Incoherent Precipitates
Precipitates on Grain Boundaries
Second-Phase Shape: Misfit Strain Effects
Fully Coherent Precipitates
Incoherent Inclusions
Platelike Precipitates
Coherency Loss
Glissile Interfaces
Solid/Liquid Interfaces
Interface Migration
Diffusion-Controlled and Interface-Controlled Growth
Exercises
References
Further Reading
Solidification
Nucleation in Pure Metals
Homogeneous Nucleation
Homogeneous Nucleation Rate
Heterogeneous Nucleation
Nucleation of Melting
Growth of a Pure Solid
Continuous Growth
Lateral Growth
Heat Flow and Interface Stability
Alloy Solidification
Solidification of Single-Phase Alloys
Eutectic Solidification
Off-Eutectic Alloys
Peritectic Solidification
Solidification of Ingots and Castings
Ingot Structure
Segregation in Ingots and Castings
Continuous Casting
Solidification of Fusion Welds
Solidification during Quenching from the Melt
Metallic Glasses
Thermodynamics and Kinetics
Case Studies of some Practical Castings and Welds
Casting of Carbon and Low-Alloy Steels
Casting of High-Speed Steels
Exercises
References
Further Reading
Diffusional Transformations in Solids
Homogeneous Nucleation in Solids
Heterogeneous Nucleation
Rate of Heterogeneous Nucleation
Precipitate Growth
Growth behind Planar Incoherent Interfaces
Diffusion-Controlled Lengthening of Plates or Needles
Thickening of Platelike Precipitates
Overall Transformation Kinetics: TTT Diagrams
Precipitation in Age-Hardening Alloys
Precipitation in Aluminum-Copper Alloys
Precipitation in Aluminum-Silver Alloys
Quenched-In Vacancies
Age Hardening
Spinodal Decomposition
Particle Coarsening
Precipitation of Ferrite from Austenite
Case Study: Ferrite Nucleation and Growth
Cellular Precipitation
Eutectoid Transformations
Pearlite Reaction in Fe-C Alloys
Bainite Transformation
Effect of Alloying Elements on Hardenability
Continuous Cooling Diagrams
Fibrous and Interphase Precipitation in Alloy Steels
Rule of Scheil
Massive Transformations
Ordering Transformations
Case Studies
Titanium Forging Alloys
Weldability of Low-Carbon and Microalloyed Rolled Steels
Very Low-Carbon Bainitic Steel with High Strength and Toughness
Very Fine Bainite
Exercises
References
Further Reading
Diffusionless Transformations
Characteristics of Diffusionless Transformations
Solid Solution of Carbon in Iron
Martensite Crystallography
Bain Model of the fcc (???) bct Transformation
Comparison of Crystallographic Theory with Experimental Results
Theories of Martensite Nucleation
Formation of Coherent Nuclei of Martensite
Role of Dislocations in Martensite Nucleation
Dislocation Strain Energy Assisted Transformation
Martensite Growth
Growth of Lath Martensite
Plate Martensite
Stabilization
Effect of External Stresses
Role of Grain Size
Premartensite Phenomena
Tempering of Ferrous Martensites
Case Studies
Carbon and Low-Alloy Quenched and Tempered Steels
Controlled Transformation Steels
TRIP-Assisted Steels
"Shape-Memory" Metal: Nitinol
Exercises
References
Further Reading
Solutions to Exercises
Index

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