Organic Chemistry Second Semester Topics

ISBN-10: 1118144341
ISBN-13: 9781118144343
Edition: 3rd 2012
Authors: David R. Klein
List price: $64.95
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Book details

List price: $64.95
Edition: 3rd
Copyright year: 2012
Publisher: John Wiley & Sons, Incorporated
Publication date: 10/19/2011
Binding: Paperback
Pages: 368
Size: 6.25" wide x 9.50" long x 0.75" tall
Weight: 1.232
Language: English

IR Spectroscopy
Vibrational Excitation
IR Spectra
Wavenumber
Signal Intensity
Signal Shape
Analyzing an IR Spectrum
NMR Spectroscopy
Chemical Equivalence
Chemical Shift (Benchmark Values)
Integration
Multiplicity
Pattern Recognition
Complex Splitting
No Splitting
Hydrogen Deficiency Index (Degrees of Unsaturation)
Analyzing a Proton NMR Spectrum
13C NMR Spectroscopy
Electrophilic Aromatic Substitution
Halogenation and the Role of Lewis Acids
Nitration
Friedel-Crafts Alkylation and Acylation
Sulfonation
Activation and Deactivation
Directing Effects
Identifying Activators and Deactivators
Predicting and Exploiting Steric Effects
Synthesis Strategies
Nucleophilic Aromatic Substitution
Criteria for Nucleophilic Aromatic Substitution
SNAr Mechanism
Elimination-Addition
Mechanism Strategies
Ketones And Aldehydes
Preparation of Ketones and Aldehydes
Stability and Reactivity of C�O Bonds
H-Nucleophiles
O-Nucleophiles
S-Nucleophiles
N-Nucleophiles
C-Nucleophiles
Some Important Exceptions to the Rule
How to Approach Synthesis Problems
Carboxylic Acid Derivatives
Reactivity of Carboxylic Acid Derivatives
General Rules
Acid Halides
Acid Anhydrides
Esters
Amides and Nitriles
Synthesis Problems
Enols And Enolates
Alpha Protons
Keto-Enol Tautomerism
Reactions Involving Enols
Making Enolates
Haloform Reaction
Alkylation of Enolates
Aldol Reactions
Claisen Condensation
Decarboxylation
Michael Reactions
Amines
Nucleophilicity and Basicity of Amines
Preparation of Amines through SN2 Reactions
Preparation of Amines through Reductive Amination
Acylation of Amines
Reactions of Amines with Nitrous Acid
Aromatic Diazonium Salts
Answer Key
Index

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