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| Note: Each chapter concludes with a Summary, Key Terms, and Questions and Exercises | |
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| Chemical Foundations | |
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| Chemistry: An Overview | |
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| The Scientific Method | |
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| Units of Measurement | |
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| Uncertainty in Measurement | |
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| Significant Figures and Calculations | |
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| Dimensional Analysis | |
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| Temperature | |
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| Density | |
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| Classification of Matter | |
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| Atoms, Molecules, and Ions | |
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| The Early History of Chemistry | |
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| Fundamental Chemical Laws | |
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| Dalton's Atomic Theory | |
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| Early Experiments to Characterize the Atom | |
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| The Modern View of Atomic Structure: An Introduction | |
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| Molecules and Ions | |
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| An Introduction to the Periodic Table | |
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| Naming Simple Compounds | |
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| Stoichiometry | |
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| Atomic Masses | |
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| The Mole | |
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| Molar Mass | |
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| Percent Composition of Compounds | |
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| Determining the Formula of a Compound | |
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| Chemical Equations | |
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| Balancing Chemical Equations | |
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| Stoichiometric Calculations: Amounts of Reactants and Products | |
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| Calculations Involving a Limiting Reactant | |
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| Types of Chemical Reactions and Solution Stoichiometry | |
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| Water, the Common Solvent | |
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| The Nature of Aqueous Solutions: Strong and Weak Electrolytes | |
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| The Composition of Solutions | |
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| Types of Chemical Reactions | |
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| Precipitation Reactions | |
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| Describing Reactions in Solution | |
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| Stoichiometry of Precipitation Reactions | |
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| Acid-Base Reactions | |
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| Oxidation-Reduction Reactions | |
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| Balancing Oxidation-Reduction Equations | |
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| Gases | |
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| Pressure | |
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| The Gas Laws of Boyle, Charles, and Avogadro | |
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| The Ideal Gas Law | |
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| Gas Stoichiometry | |
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| Dalton's Law of Partial Pressures | |
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| The Kinetic Molecular Theory of Gases | |
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| Effusion and Diffusion | |
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| Real Gases | |
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| Chemistry in the Atmosphere | |
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| Thermochemistry | |
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| The Nature of Energy | |
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| Enthalpy and Calorimetry | |
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| Hess's Law | |
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| Standard Enthalpies of Formation | |
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| Present Sources of Energy | |
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| New Energy Sources | |
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| Atomic Structure and Periodicity | |
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| Electromagnetic Radiation | |
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| The Nature of Matter | |
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| The Atomic Spectrum of Hydrogen | |
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| The Bohr Model | |
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| The Quantum Mechanical Model of the Atom | |
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| Quantum Numbers | |
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| Orbital Shapes and Energies | |
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| Electron Spin and the Pauli Principle | |
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| Polyelectronic Atoms | |
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| The History of the Periodic Table | |
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| The Aufbau Principles and the Periodic Table | |
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| Periodic Trends in Atomic Properties | |
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| The Properties of a Group: The Alkali Metals | |
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| Bonding: General Concepts | |
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| Types of Chemical Bonds | |
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| Electronegativity | |
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| Bond Polarity and Dipole Moments | |
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| Ions: Electron Configurations and Sizes | |
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| Formation of Binary Ionic Compounds | |
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| Partial Ionic Character of Covalent Bonds | |
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| The Covalent Chemical Bond: A Model | |
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| Covalent Bond Energies and Chemical Reactions | |
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| The Localized Electron Bonding Model | |
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| Lewis Structures | |
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| Exceptions to the Octet Rule | |
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| Resonance | |
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| Molecular Structure: The VSEPR Model | |
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| Covalent Bonding: Orbitals | |
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| Hybridization and the Localized Electron Model | |
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| The Molecular Orbital Model | |
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| Bonding in Homonuclear Diatomic Molecules | |
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| Bonding in Heteronuclear Diatomic Molecules | |
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| Combining the Localized Electron and Molecular Orbital Models | |
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| Liquids and Solids | |
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| Intermolecular Forces | |
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| The Liquid State | |
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| An Introduction to Structures and Types of Solids | |
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| Structure and Bonding in Metals | |
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| Carbon and Silicon: Network Atomic Solids | |
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| Molecular Solids | |
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| Ionic Solids | |
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| Vapor Pressure and Changes of State | |
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| Phase Diagrams | |
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| Properties of Solutions | |
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| Solution Composition | |
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| The Energies of Solution Formation | |
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| Factors Affecting Solubility | |
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| The Vapor Pressures of Solutions | |
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| Boiling-Point Elevation and Freezing-Point Depression | |
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| Osmotic Pressure | |
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| Colligative Properties of Electrolyte Solutions | |
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| Colloids | |
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| Chemical Kinetics | |
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| Reaction Rates | |
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| Rate Laws: An Introduction | |
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| Determining the Form of the Rate Law | |
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| The Integrated Rate Law | |
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| Rate Laws: A Summary | |
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| Reaction Mechanisms | |
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| A Model for Chemical Kinetics | |
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| Catalysis | |
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| Chemical Equilibrium | |
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| The Equilibrium Condition | |
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| The Equilibrium Constant | |
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| Equilibrium Expressions Involving Pressures | |
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| Heterogeneous Equilibria | |
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| Applications of the Equilibrium Constant | |
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| Solving Equilibrium Problems | |
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| Le Chacirc;telier's Principle | |
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| Acids and Bases | |
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| The Nature of Acids and Bases | |
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| Acid Strength | |
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| The pH Scale | |
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| Calculating the pH of Strong Acid Solutions | |
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| Calculating the pH of Weak Acid Solutions | |
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| Bases | |
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| Polyprotic Acids | |
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| Acid-Base Properties of Salts | |
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| The Effect of Structure on Acid-Base Properties | |
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| Acid-Base Properties of Oxides | |
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| The Lewis Acid-Base Model | |
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| Strategy for Solving Acid-Base Problems: A Summary | |
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| Applications of Aqueous Equilibria Acid-Base Equilibria | |
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| Solutions of Acids or Bases Containing a Common Ion | |
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| Buffered Solutions | |
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| Buffer Capacity | |
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| Titrations and pH Curves | |
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| Acid-Base Indicators Solubility Equilibria | |
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| Solubility Equilibria and the Solubility Product | |
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| Precipitation and Qualitative Analysis Complex Ion Equilibria | |
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| Equilibria Involving Complex Ions | |
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| Spontaneity, Entropy, and Free Energy | |
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| Spontaneous Processes and Entropy | |
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| Entropy and the Second Law of Thermodynamics | |
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| The Effect of Temperature on Spontaneity | |
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| Free Energy | |
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| Entropy Changes in Chemical Reactions | |
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| Free Energy and Chemical Reactions | |
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| The Dependence of Free Energy on Pressure | |
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| Free Energy and Equilibrium | |
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| Free Energy and Work | |
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| Electrochemistry | |
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| Galvanic Cells | |
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| Standard Reduction Potential | |
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| Cell Potential, Electrical Work, and Free Energy | |
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| Dependence of Cell Potential on Concentration | |
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| Batteries | |
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| Corrosion | |
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| Electrolysis | |
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| Commercial Electrolytic Processes | |
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| The Nucleus: A Chemist's View | |
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| Nuclear Stability and Radioactive Decay | |
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| The Kinetics of Radioactive Decay | |
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| Nuclear Transformations | |
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| Detection and Uses of Radioactivity | |
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| Thermodynamic Stability of the Nucleus | |
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| Nuclear Fission and Nuclear Fusion | |
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| Effects of Radiation | |
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| The Representative Elements: Groups 1A Through 4A | |
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| A Survey of the Representative Elements | |
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| The Group 1A Elements | |
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| Hydrogen | |
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| The Group 2A Elements | |
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| The Group 3A Elements | |
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| The Group 4A Elements | |
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| The Representative Elements: Groups 5A Through 8A | |
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| The Group 5A Elements | |
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| The Chemistry of Nitrogen | |
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| The Chemistry of Phosphorus | |
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| The Group 6A Elements | |
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| The Chemistry of Oxygen | |
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| The Chemistry of Sulfur | |
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| The Group 7A Elements | |
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| The Group 8A Elements | |
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| Transition Metals and Coordination Chemistry | |
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| The Transition Metals: A Survey | |
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| The First-Row Transition Metals | |
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| Coordination Compounds | |
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| Isomerism | |
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| Bonding in Complex Ions: The Localized Electron Model | |
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| The Crystal Field Model | |
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| The Biologic Importance of Coordination Complexes | |
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| Metallurgy and Iron and Steel Production | |
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| Organic and Biological Molecules | |
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| Alkanes: Saturated Hydrocarbons | |
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| Alkenes and Alkynes | |
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| Aromatic Hydrocarbons | |
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| Hydrocarbon Derivatives | |
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| Polymers | |
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| Natural Polymers | |
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| Appendix 1 | |