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Preface to the Third Edition | |
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Preface to the Second Edition | |
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Preface to the First Edition | |
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Introduction | |
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Definitions | |
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Thermodynamics and Potential | |
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Kinetics and Rates of Reaction | |
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Transport | |
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Concentration Overpotential and the Diffusion Potential | |
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Overall Cell Potential | |
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Problems | |
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Notation | |
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THermodynamics of Electrochemical Cells | |
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Thermodynamics in Terms of Electrochemical Potentials | |
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Phase Equilibrium | |
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Chemical Potential and Electrochemical Potential | |
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Definition of Some Thermodynamic Functions | |
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Cell with Solution of Uniform Concentration | |
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Transport Processes in Junction Regions | |
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Cell with a Single Electrolyte of Varying Concentration | |
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Cell with Two Electrolytes, One of Nearly Uniform Concentration | |
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Cell with Two Electrolytes, Both of Varying Concentration | |
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Standard Cell Potential and Activity Coefficients | |
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Pressure Dependence of Activity Coefficients | |
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Temperature Dependence of Cell Potentials | |
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Problems | |
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Notation | |
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References | |
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The Electric Potential | |
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The Electrostatic Potential | |
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Intermolecular Forces | |
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Outer and Inner Potentials | |
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Potentials of Reference Electrodes | |
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The Electric Potential in Thermodynamics | |
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Notation | |
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References | |
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Activity Coefficients | |
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Ionic Distributions in Dilute Solutions | |
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Electrical Contribution to the Free Energy | |
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Shortcomings of the Debye-Hu�ckel Model | |
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Binary Solutions | |
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Multicomponent Solutions | |
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Measurement of Activity Coefficients | |
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Weak Electrolytes.Problems | |
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Notation | |
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References | |
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Reference Electrodes | |
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Criteria for Reference Electrodes | |
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Experimental Factors Affecting The Selection of Reference Electrodes | |
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The Hydrogen Electrode | |
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The Calomel Electrode and Other Mercury-Mercurous Salt Electrodes | |
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The Mercury-Mercuric Oxide Electrode | |
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Silver-Silver Halide Electrodes | |
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Potentials Relative to a Given Reference Electrode | |
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Notation | |
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References | |
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Potentials of Cells with Junctions | |
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Nernst Equation | |
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Types of Liquid Junctions | |
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Formulas for Liquid-Junction Potentials | |
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Determination of Concentration Profiles | |
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Numerical Results | |
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Cells with Liquid Junction | |
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Error in the Nernst Equation | |
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Potentials Across Membranes | |
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Problems | |
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Notation | |
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References | |
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Electrode Kinetics and Other Interfacial Phenomena | |
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Structure of the Electric Double Layer | |
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Qualitative Description of Double Layers | |
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Gibbs Adsorption Isotherm | |
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The Lippmann Equation | |
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The Diffuse Part of the Double Layer | |
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Capacity of the Double Layer in the Absence of Specific Adsorption | |
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Specific Adsorption at an Electrode-Solution Interface | |
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Problems | |
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Notation | |
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References | |
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Electrode Kinetics | |
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Heterogeneous Electrode Reactions | |
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Dependence of Current Density on Surface Overpotential | |
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Models for Electrode Kinetics | |
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Effect of Double-Layer Structure | |
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The Oxygen Electrode | |
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Methods of Measurement | |
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Simultaneous Reactions | |
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Problems | |
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Notation | |
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References | |
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Electrokinetic Phenomena | |
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Discontinuous Velocity at an Interface | |
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Electro-Osmosis and the Streaming Potential | |
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Electrophoresis | |
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Sedimentation Potential | |
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Problems | |
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Notation | |
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References | |
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Electrocapillary Phenomena | |
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Dynamics of Interfaces | |
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Electrocapillary Motion of Mercury Drops | |
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Sedimentation Potentials for Falling Mercury Drops | |
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Notation | |
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References | |
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Transport Processes in Electrolytic Solutions | |
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Infinitely Dilute Solutions | |
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Transport Laws | |
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Conductivity, Diffusion Potentials, and Transference Numbers | |
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Conservation of Charge | |
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The Binary Electrolyte | |
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Supporting Electrolyte | |
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Multicomponent Diffusion by Elimination of the Electric Field | |
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Mobilities and Diffusion Coefficients | |
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Electroneutrality and Laplace''s Equation | |
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Moderately Dilute Solutions | |
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Problems | |
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Notation | |
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References | |
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Concentrated Solutions | |
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Transport Laws | |
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The Binary Electrolyte | |
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Reference Velocities | |
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The Potential | |
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Connection with Dilute-Solution Theory | |
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Multicomponent Transport | |
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Liquid-Junction Potentials | |
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Problems | |
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No | |