Electrochemical Systems

ISBN-10: 0471477567
ISBN-13: 9780471477563
Edition: 3rd 2004 (Revised)
List price: $211.00 Buy it from $93.83
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Description: The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and  More...

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Book details

List price: $211.00
Edition: 3rd
Copyright year: 2004
Publisher: John Wiley & Sons, Incorporated
Publication date: 5/27/2004
Binding: Hardcover
Pages: 672
Size: 6.00" wide x 9.25" long x 1.50" tall
Weight: 2.332
Language: English

The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields. Rigorous and complete presentation of the fundamental concepts In-depth examples applying the concepts to real-life design problems Homework problems ranging from the reinforcing to the highly thought-provoking Extensive bibliography giving both the historical development of the field and references for the practicing electrochemist.

Preface to the Third Edition
Preface to the Second Edition
Preface to the First Edition
Introduction
Definitions
Thermodynamics and Potential
Kinetics and Rates of Reaction
Transport
Concentration Overpotential and the Diffusion Potential
Overall Cell Potential
Problems
Notation
THermodynamics of Electrochemical Cells
Thermodynamics in Terms of Electrochemical Potentials
Phase Equilibrium
Chemical Potential and Electrochemical Potential
Definition of Some Thermodynamic Functions
Cell with Solution of Uniform Concentration
Transport Processes in Junction Regions
Cell with a Single Electrolyte of Varying Concentration
Cell with Two Electrolytes, One of Nearly Uniform Concentration
Cell with Two Electrolytes, Both of Varying Concentration
Standard Cell Potential and Activity Coefficients
Pressure Dependence of Activity Coefficients
Temperature Dependence of Cell Potentials
Problems
Notation
References
The Electric Potential
The Electrostatic Potential
Intermolecular Forces
Outer and Inner Potentials
Potentials of Reference Electrodes
The Electric Potential in Thermodynamics
Notation
References
Activity Coefficients
Ionic Distributions in Dilute Solutions
Electrical Contribution to the Free Energy
Shortcomings of the Debye-Hu�ckel Model
Binary Solutions
Multicomponent Solutions
Measurement of Activity Coefficients
Weak Electrolytes.Problems
Notation
References
Reference Electrodes
Criteria for Reference Electrodes
Experimental Factors Affecting The Selection of Reference Electrodes
The Hydrogen Electrode
The Calomel Electrode and Other Mercury-Mercurous Salt Electrodes
The Mercury-Mercuric Oxide Electrode
Silver-Silver Halide Electrodes
Potentials Relative to a Given Reference Electrode
Notation
References
Potentials of Cells with Junctions
Nernst Equation
Types of Liquid Junctions
Formulas for Liquid-Junction Potentials
Determination of Concentration Profiles
Numerical Results
Cells with Liquid Junction
Error in the Nernst Equation
Potentials Across Membranes
Problems
Notation
References
Electrode Kinetics and Other Interfacial Phenomena
Structure of the Electric Double Layer
Qualitative Description of Double Layers
Gibbs Adsorption Isotherm
The Lippmann Equation
The Diffuse Part of the Double Layer
Capacity of the Double Layer in the Absence of Specific Adsorption
Specific Adsorption at an Electrode-Solution Interface
Problems
Notation
References
Electrode Kinetics
Heterogeneous Electrode Reactions
Dependence of Current Density on Surface Overpotential
Models for Electrode Kinetics
Effect of Double-Layer Structure
The Oxygen Electrode
Methods of Measurement
Simultaneous Reactions
Problems
Notation
References
Electrokinetic Phenomena
Discontinuous Velocity at an Interface
Electro-Osmosis and the Streaming Potential
Electrophoresis
Sedimentation Potential
Problems
Notation
References
Electrocapillary Phenomena
Dynamics of Interfaces
Electrocapillary Motion of Mercury Drops
Sedimentation Potentials for Falling Mercury Drops
Notation
References
Transport Processes in Electrolytic Solutions
Infinitely Dilute Solutions
Transport Laws
Conductivity, Diffusion Potentials, and Transference Numbers
Conservation of Charge
The Binary Electrolyte
Supporting Electrolyte
Multicomponent Diffusion by Elimination of the Electric Field
Mobilities and Diffusion Coefficients
Electroneutrality and Laplace''s Equation
Moderately Dilute Solutions
Problems
Notation
References
Concentrated Solutions
Transport Laws
The Binary Electrolyte
Reference Velocities
The Potential
Connection with Dilute-Solution Theory
Multicomponent Transport
Liquid-Junction Potentials
Problems
No

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