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| Preface | |
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| Nomenclature | |
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| The Basics of Reaction Kinetics for Chemical Reaction Engineering | |
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| The Scope of Chemical Reaction Engineering | |
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| The Extent of Reaction | |
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| The Rate of Reaction | |
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| General Properties of the Rate Function for a Single Reaction | |
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| Examples of Reaction Rates | |
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| Rate Constants of Elementary Reactions | |
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| Elementary Reactions | |
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| Arrhenius Temperature Dependence of the Rate Constant | |
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| Transition-State Theory | |
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| Reactors for Measuring Reaction Rates | |
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| Ideal Reactors | |
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| Batch and Semibatch Reactors | |
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| Stirred-Flow Reactors | |
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| Ideal Tubular Reactors | |
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| Measurement of Reaction Rates | |
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| Batch Reactors | |
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| Flow Reactors | |
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| The Steady-State Approximation: Catalysis | |
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| Single Reactions | |
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| The Steady-State Approximation | |
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| Relaxation Methods | |
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| Heterogeneous Catalysis | |
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| Introduction | |
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| Kinetics of Elementary Steps: Adsorption, Desorption, and Surface Reaction | |
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| Kinetics of Overall Reactions | |
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| Evaluation of Kinetic Parameters | |
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| Effects of Transport Limitations on Rates of Solid-Catalyzed Reactions | |
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| Introduction | |
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| External Transport Effects | |
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| Internal Transport Effects | |
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| Combined Internal and External Transport Effects | |
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| Analysis of Rate Data | |
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| Microkinetic Analysis of Catalytic Reactions | |
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| Introduction | |
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| Asymmetric Hydrogenation of Prochiral Olefins | |
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| Ammonia Synthesis on Transition Metal Catalysts | |
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| Ethylene Hydrogenation on Transition Metals | |
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| Concluding Remarks | |
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| Nonideal Flow in Reactors | |
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| Introduction | |
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| Residence Time Distribution (RTD) | |
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| Application of RTD Functions to the Prediction of Reactor Conversion | |
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| Dispersion Models for Nonideal Reactors | |
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| Prediction of Conversion with an Axially-Dispersed PFR | |
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| Radial Dispersion | |
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| Dispersion Models for Nonideal Flow in Reactors | |
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| Nonisothermal Reactors | |
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| The Nature of the Problem | |
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| Energy Balances | |
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| Nonisothermal Batch Reactor | |
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| Nonisothermal Plug Flow Reactor | |
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| Temperature Effects in a CSTR | |
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| Stability and Sensitivity of Reactors Accomplishing Exothermic Reactions | |
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| Reactors Accomplishing Heterogeneous Reactions | |
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| Homogeneous Versus Heterogeneous Reactions in Tubular Reactors | |
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| One-Dimensional Models for Fixed-Bed Reactors | |
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| Two-Dimensional Models for Fixed-Bed Reactors | |
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| Reactor Configurations | |
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| Fluidized Beds with Recirculating Solids | |
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| Review of Chemical Equilibria | |
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| Basic Criteria for Chemical Equilibrium of Reacting Systems | |
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| Determination of Equilibrium Compositions | |
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| Regression Analysis | |
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| Method of Least Squares | |
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| Linear Correlation Coefficient | |
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| Correlation Probability with a Zero Y-Intercept | |
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| Nonlinear Regression | |
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| Transport in Porous Media | |
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| Derivation of Flux Relationships in One-Dimension | |
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| Flux Relationships in Porous Media | |
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| Index | |