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Preface | |
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Criticality and Chemistry | |
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Critical phenomena | |
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Chemical reactions | |
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Analogy between critical phenomena and the instability of chemical reactions | |
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Effect of Criticality on Chemical Reaction | |
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The effect of pressure on the equilibrium constant and rate of reaction | |
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Effect of phase transformations on chemistry | |
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Critical slowing-down of chemical reactions | |
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Hydrodynamic equations of reactive binary mixture: piston effect | |
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Heterogeneous reactions in near-critical systems | |
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Dynamics of chemical reactions | |
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Relaxation time of reactions | |
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Hydrodynamic equations of a reactive binary mixtures | |
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Hydrodynamic equations with statistically independent variables | |
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Critical anomalies of chemical equilibria | |
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Experiment | |
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Effect of Chemistry on Critical Phenomena | |
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Change of critical parameters due to a chemical reaction | |
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Modification of the critical indices | |
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Singularity in the degree of dissociation near a critical point | |
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Isotope exchange reaction in near-critical systems | |
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Singularities of transport coefficients in reactive systems | |
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Mode-coupling analysis | |
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Renormalization group methods | |
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Phase Separation in Reactive Systems | |
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Multiple solutions of the law of mass action | |
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Phase equilibrium in reactive binary mixtures quenched into a metastable state | |
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Thermodynamic analysis of reactive binary mixtures | |
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Thermodynamic analysis of reactive ternary mixtures | |
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Kinetics of phase separation | |
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Phase equilibrium in reactive mixtures quenched into an unstable state | |
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Thermodynamics of a three-component plasma with a dissociative chemical reaction | |
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Comments on the Geometry of the Phase Diagram of a Reaction Mixture | |
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Solubility in supercritical fluids | |
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Azeotropic points in reactive many-component systems | |
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Melting point of reactive binary mixtures | |
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Double critical point | |
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Sound Propagation and Light Scattering in Chemically Reactive Systems | |
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Ultrasound attenuation in near-critical reactive mixtures | |
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Hydrodynamic analysis of the dispersion-relation for sound waves | |
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Light scattering from reactive systems | |
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Inhomogeneous structure of near-critical reactive systems | |
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Conclusions | |
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Bibliography | |
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Index | |