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| Preface | |
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| Introduction To Catalysis | |
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| What is Catalysis | |
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| Catalysts Can Be Atoms, Molecules, Enzymes and Solid Surfaces | |
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| Why is Catalysis Important? | |
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| Catalysis as a Multidisciplinary Science | |
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| The Scope of This Book | |
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| Catalysis in Journals | |
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| General References to Textbooks in Catalysis | |
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| Kinetics | |
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| Introduction | |
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| The Rate Equation and Power Rate Laws | |
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| Reactions and Thermodynamic Equilibrium | |
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| Temperature Dependence of the Rate | |
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| Integrated Rate Equations: Time Dependence of Concentrations in Reactions of Different Orders | |
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| Coupled Reactions in Flow Reactors: The Steady-state Approximation | |
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| Coupled Reactions in Batch Reactors | |
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| Catalytic Reactions | |
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| Langmuir Adsorption Isotherms | |
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| Reaction Mechanisms | |
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| Entropy, Entropy Production, Auto Catalysis and Oscillating Reactions | |
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| Kinetics of Enzyme-catalyzed Reactions | |
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| Reaction Rate Theory | |
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| Introduction | |
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| The Boltzmann Distribution and the Partition Function | |
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| Partition Functions of Atoms and Molecules | |
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| Molecules in Equilibrium | |
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| Collision Theory | |
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| Activation of Reacting Molecules by Collisions: The Lindermann Theory | |
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| Transition State Theory | |
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| Transition State Theory of Surface Reactions | |
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| Summary | |
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| Catalyst Characterization | |
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| Introduction | |
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| X-Ray Diffraction (XRD) | |
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| X-Ray Photoelectron Spectroscopy (XPS) | |
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| Extended X-Ray Absorption Fine Structure (EXAFS) | |
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| Electron Microscopy | |
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| Mossbauer Spectroscopy | |
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| Ion Spectroscopy: SIMS, LEIS, RBS | |
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| Temperature-programmed Reduction, Oxidation and Sulfidation | |
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| Infrared Spectroscopy | |
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| Surface Science Techniques | |
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| Concluding Remarks | |
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| Solid Catalysts | |
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| Requirements of a Successful Catalyst | |
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| Structure of Metals, Oxides and Sulfides and their Surfaces | |
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| Characteristics of Small Particles and Porous Material | |
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| Catalyst Supports | |
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| Preparation of Supported Catalysts | |
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| Unsupported Catalysts | |
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| Zeolites | |
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| Catalyst Testing | |
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| Surface Reactivity | |
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| Introduction | |
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| Physisorption | |
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| Chemical Bonding | |
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| Chemisorption | |
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| Important Trends in Surface Reactivity | |
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| Kinetics Of Reactions On Surfaces | |
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| Elementary Surface Reactions | |
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| Kinetic Parameters from Fitting Langmuir-Hinshelwood Models | |
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| Micro-kinetic Modeling | |
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| Heterogeneous Catalysis In Practice: Hydrogen | |
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| Introduction | |
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| Steam Reforming Process | |
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| Reactions of Synthesis Gas | |
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| Water Gas Shift Reaction | |
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| Synthesis of Ammonia | |
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| Promoters and Inhibitors | |
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| The Hydrogen Society | |
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| Oil Refining And Pretrochemistry | |
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| Crude Oil | |
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| Hydrotreating | |
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| Gasoline Production | |
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| Petrochemistry: Reactions of Small Olefins | |
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| Environmental Catalysis | |
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| Introduction | |
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| Automotive Exhaust Catalysis | |
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| Air Pollution by Large Stationary Sources | |
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| Questions And Exercises | |
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| Appendix A | |
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| Appendix B | |
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| Index | |