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| List of Tables | |
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| Preface | |
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| Inorganic Ions and Simple Molecules in Chemistry and in Our Environment | |
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| Periodic Trends in Fundamental Properties of Atoms and Simple Ions | |
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| Why Study Inorganic Chemistry? | |
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| The Periodic Table | |
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| Quantum Mechanics: Waves/Particles | |
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| Electrons in Atoms: Angular Part of the Electronic Wave Function | |
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| Radial Part of the Wave Function | |
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| Shielding and Slater's Rules | |
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| Characteristic Valence Electron Configurations | |
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| Valence Electron Configurations, Charges, and Oxidation Numbers of Ions | |
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| Types of Atomic Radii, Their Periodic Trends, and Reasons for the Trends | |
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| Periodic Trends in Electronegativities of Atoms and Their Explanation | |
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| Relativistic Effects on Orbitals | |
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| Predicting the Chemistry of Superheavy Elements | |
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| Monoatomic Ions and Their Acid-Base Reactivity | |
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| Hydration of Cations | |
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| Acidity of Cations | |
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| Classification of Cations by Acidity Category | |
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| Halides that Fail to Undergo Hydrolysis: Oxo Cations | |
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| Hydration and Hydrolysis of Monoatomic Nonmetal Anions | |
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| Predominance Diagrams for Anions: Partially Protonated Anions | |
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| Acidic Nonmetal Hydrides and Basic Metal Oxides | |
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| Nomenclature | |
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| Polyatomic Ions and Their Acid-Base Properties With Applications to Environmental Chemistry and Analytical Chemistry | |
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| Covalent Bond Types and Periodicity of Bond Energies | |
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| Covalent Bonding to Ions: The Lewis Acid-Base Concept and Complex Ions | |
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| Lewis Structures, Coordination Numbers, and Fluoro Anions | |
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| The Shapes of p-Block Molecules and Complex Ions | |
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| Formulas of Oxo Anions | |
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| Basicity of Oxo Anions | |
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| Protonation of Oxo Anions: Hydroxo Anions and Oxo Acids | |
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| Most Common Forms of the Elements in Natural Waters | |
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| Nomenclature of Fluoro and Oxo Anions and Acids | |
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| Lewis Structures and Oxidation Numbers | |
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| Ionic Solids and Precipitation Reactions of Hydrated Ions With Applications to Analytical Chemistry, Organic Chemistry, and Water Chemistry | |
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| Solubility Rules for Salts of Oxo and Fluoro Anions | |
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| Thermodynamics and Solubility Rules for Salts | |
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| Entropy and Precipitation: The Structure of Hydrated Ions | |
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| Nonacidic Cations, Nonbasic Anions, and the Structure of Liquid Water | |
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| Enthalpy and Precipitation: The Importance of Lattice Energies | |
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| Ionic Solids: Coulombic Attractions and Lattice Energies | |
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| Radius Ratios and Lattice Types | |
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| Stability of Lattices and the Solubility Rules | |
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| Writing and Interpreting Net Ionic Equations | |
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| Nonaqueous Solvents for ionic or Ionizable Compounds | |
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| Trends in Coordination Equilibria With Applications to Biochemistry, Environmental Chemistry, Geochemistry, and Medicinal Chemistry | |
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| Classification of Ligands | |
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| Chelate and Macrocyclic Effects | |
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| The Hard and Soft Acid-Base Principle | |
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| Relative and Borderline Hardness and Softness | |
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| The HSAB Principle and Polar Covalent Bonding | |
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| The Need for Two Parameters: Softness and Strength | |
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| Applications of HSAB: Solubility of Halides and Chalcogenides | |
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| Applications of HSAB: The Qualitative Analysis Scheme for Metal Ions | |
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| Applications of HSAB: The Geochemical Classification and Differentiation of the Elements | |
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| Metal ions in Biochemistry | |
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| Applications of HSAB: Biological Functions and Toxicology of the Elements | |
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| Applications of HSAB and Cholation: Medicinal Chemistry | |
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| Principles of Oxidation-Reduction Reactivity With Applications to Chemical Safety, Environmental Chemistry, and Industrial Chemistry | |
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| Standard Reduction Potentials and Their Diagrammatic Representation | |
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| Explosives, Flammable Compounds, and the Handling of Strong Reducing Agents | |
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| Redox Predominance Diagrams: Construction; Species that Disproportionate; Nonstanmdard Conditions | |
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| Charge-Transfer Spectra and Marginal Redox Stability | |
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| Periodicity in the Activity of Metals and the Reduction of Metal Ions | |
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| Hard and Soft Acids and Bases and Redox Chemistry | |
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| Redox Chemistry of the Nonmetals | |
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| Industrial Processes for Extracting Elements from Their Ores | |
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| Effects of Concentration and pH on Redox Chemistry: Pourbaix Diagrams | |
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| pH Effects on Redox Chemistry: The Synthesis of Oxo Anions and Acids and Corrosion of Metals | |
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| Thermochemical Analyses of Reactivity Trends | |
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| Thermochemical Analysis of Redox Reactions: Born-Haber Cycle | |
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| Thermochemical Analysis of the Activity Series of the Elements | |
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| Significance of Atomization Energies in Redox Chemistry | |
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| Periodicity and Significance of Ionization Energies and Electron Affinities | |
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| Polar Covalent Bond Energies and Pauling Electronegativities | |
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| Effects of Changing Substituents and Oxidation Numbers on Electronegativities | |
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| Definitions of Electronegativity and Hardness Related to Ionization Energies and Electron Affinities | |
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| Thermodynamics of the Lewis Acis-Lewis Base Interaction: Drago's E, C, and T Parameters | |
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| Introduction to Transition Metal complexes With Applications to Biochemistry | |
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| Introduction | |
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| The Crystal Field Theory | |
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| High- and Low-Spin Electron Configurations: Magnetic Properties | |
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| Electronic Absorption Spectra of Complex Ions | |
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| The Spectrochemical Series of Ligands and the Effects of Covalency | |
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| Thermodynamic and Structural Consequences of Crystal Field Effects | |
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| Crystal Field Splitting in Complexes of Other Geometries | |
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| Geometric Preferences: Rates and Mechanisms of Ligand Exchange | |
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| Syntheses of d-Block Complexes | |
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| Bioinorganic Chemistry and Crystal Field Theory: Heme and Hemoglobin | |
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| Nomenclature of Coordination and Organometallic Compounds | |
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| Inorganic Molecules and Materials: Theory and Applications | |
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| Symmetry With Applications to Art, Environmental Chemistry and Organic Chemistry | |
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| Symmetry Operations and Elements | |
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| Molecular Point Groups | |
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| Elementary Applications of Symmetry: Molecular Polarity, Chirality, and Fluxionality | |
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| Character Tables for Symmetry Point Groups | |
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| Applications of Symmetry: Infrared and Raman Spectra | |
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| Molecular Orbital Theory With Applications to Organic Chemistry and materials Science | |
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| Molecular Orbital Theory for Homonuclear Diatomic Molecules | |
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| Bond Energies and Lengths, Spectroscopy, and Orbital Mixing in Homonuclear Diatomic Molecules | |
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| Heteroatomic Diatomic Molecules and Ions | |
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| Molecular Ionization Energies, Electron Affinities, Electronegativities, and Hardness | |
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| Molecular Orbital Theory for Linear Molecules | |
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| Molecular Orbital Theory for Cyclic Molecules: Generator Orbitals | |
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| Orbital Symmetry Rules for Concerted Reactions | |
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| Molecular Orbitals for D[subscript nh] Molecules | |
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| Molecular Orbitals for Three-Dimensional Molecules in Higher Order Point Groups | |
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| Molecular Orbitals for Cluster Compounds | |
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| Molecular Orbitals for Metals | |
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| Organometallic Chemistry of the d-Block Elements With Applications to Industrial Chemistry, Organic Chemistry, Biochemistry and Environmental Chemistry | |
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| Organometallic Compounds of the d-Block Metals: The 18-Electron Rule | |
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| Mononuclear Metal Carbonyls and Related Organometallics | |
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| Metal Complexes of [pi]-Donor Ligands | |
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| Other Ligands Forming One [sigma] Bond in Organometallics: Dinuclear and Polynuclear Organometallics | |
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| Bridging Ligands: Alkynes and Carbonyls | |
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| Ligands Forming Two or More Bonds to a Metal or Metals: The Isolobal Analogy | |
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| Reaction Types of d-Block Organometallic Compounds | |
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| Catalytic Cycles | |
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| Organometallic Catalysis in Biochemistry and Environmental Chemistry | |
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| The Elements and Their Physical Properties With Applications to Materials Science | |
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| Interunit Forces and Physical Properties | |
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| Physical Properties, Allotropes, and Uses of the Nonmetallic Elements | |
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| Metals and Alloys | |
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| Magnetism, Electrical Conductivity, and Semiconduction | |
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| Homopolyatomic Anions and Cations of the Elements: Metal Complexes | |
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| Heterogeneous Catalysis by Metals | |
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| Metallic Chains, Sheets, and Clusters | |
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| Oxides of the Elements With Applications to Geochemistry, Environmental Chemistry, and Materials Science | |
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| Physical States and Structures of the Fluorides and Oxides of the Elements | |
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| Covalent Oxides: Periodic Trends in Structure and Physical State | |
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| Acidity, Solubility, Practical Uses, and Environmental Chemistry of Volatile Oxides and Oxo Acids | |
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| Close Packed Anions, Metal Oxides, and Electrical Conductivity of Solid Ionic Compounds | |
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| Spinels, Perovskites, High-Temperature Superconductors, and Cooperative Magnetic Properties in Mixed-Metal Oxides | |
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| Polysilicates: Basic Structural Types, Uses, and Chemistry | |
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| Aluminosilicates | |
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| Oligomeric Polyoxometallate Anions of Other p- and d-Block Elements: Selected Structures and Uses | |
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| The Halides, Nitrides, and Sulfides of the Elements With Applications to Materials Science and Biochemistry | |
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| Structural Features of Halides | |
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| Physical States and Physical Properties of Halides | |
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| Methods of Synthesis of Halides | |
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| Reactions and Uses of Halides | |
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| Catenated and Cluster Halides | |
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| More Complex Oxygen Derivatives: Oxo Halides, Silicones, Inorganic Esters, Alkoxides | |
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| Nitrides and Carbides of the Elements | |
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| Sulfides, Selenides, Tellurides, and Arsenides of the Elements | |
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| Relationships among Ionic, Covalent, and Metallic Bonding | |
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| Hydrides, Alkyls, and Aryls of the Elements With Applications to Materials Science and Organic Chemistry | |
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| Classification of Hydrides: Hydrides of Metals | |
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| Electron-Precise and Electron-Rich Molecular Hydrides | |
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| Electron-Deficient Molecular Hydrides | |
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| Syntheses of the Hydrides and Hydride Anions of the Elements | |
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| Reactions and Uses of the Hydrides | |
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| Alkyls and Aryls of the Elements: Classification and Structures | |
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| Methods of Synthesis of Alkyls and Aryls | |
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| Reactions and Uses of the Alkyls and Aryls | |
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| Catenated Alkyls and Aryls of the p-Block | |
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| Multiply Bonded and Divalent Alkyls and Aryls of the Heavier p-Block Elements | |
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| Inorganic Reaction Mechanisms With Applications to Materials Science, Organic Chemistry, Environmental Chemistry, and Biochemistry | |
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| Rate Laws and Stoichiometric Reaction Mechanisms for Ligand Substitution Reactions | |
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| Intimate Mechanisms for Ligand Substitution Reactions | |
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| Entering Group, Leaving Group, and Metal Effects on Ligand Substitution Rates | |
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| Spectator Ligand Effects on Ligand Substitution Rates | |
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| Classification of Redox Reaction Mechanisms | |
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| Outer-Sphere Electron-Transfer Processes | |
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| One-Electron Inner-Sphere and Long-Range Electron-Transfer Processes | |
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| Two-Electron Inner-Sphere Electron-Transfer Processes | |
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| Advanced Topics: Excited Electronic States, Photochemistry, and Activated Molecules With Applications to Materials Science, Atmospheric Chemistry, and Biochemistry | |
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| Electronic States and Term Symbols | |
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| Electronic States for Diatomic Molecules and Their Consequences | |
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| Electronic States for Octahedral Complexes | |
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| Tanabe-Sugano Diagrams and Spectra of d-Block Complexes | |
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| Luminescence, Lasers, and Spin-Orbit Coupling | |
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| Photochemically Assisted Substitution and Redox Processes | |
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| Chlorophyll and Photosynthesis | |
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| Biochemical Oxygen Transport and Activation | |
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| Biochemical Nitrogen Activation | |
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| Discovery Laboratory Experiments for Part I | |
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| Some Reactions of Cations | |
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| Nonaqueous Reactions of Metal Ions and Compounds | |
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| Some Reactions of Oxo Anions | |
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| Reaction of Anions with Cations | |
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| Competitive Precipitation and Complexation Reactions | |
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| Periodicity in the Activity (Electromotive) Series of Metals | |
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| The Widely Varying Colors of d-Block Metal Complexes | |
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| Character Tables | |
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| Answers to Selected Exercises | |
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| Index | |