Adhesion and Adhesive Technology

Name: Adhesion and Adhesive Technology
Price: 83.23 USD
Availability: InStock
ISBN: 9781569903193

ISBN-10: 1569903190

ISBN-13: 9781569903193

Edition: 2nd 2002

Authors: A. V. Pocius

List price: $89.95

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Description:

This book describes, in clear, understandable language, the three main disciplines of adhesion technology:

Book details

List price: $89.95
Edition: 2nd
Copyright year: 2002
Publisher: Hanser-Gardner Publications
Binding: Hardcover
Size: 6.25" wide x 8.75" long x 0.50" tall
Weight: 1.496
Language: English

Introduction	p. 1
Introduction and Chapter Objectives	p. 1
Basic Definitions	p. 1
Advantages and Disadvantages of Adhesive Bonding	p. 2
Uses of Adhesive Bonding in Modern Industry	p. 5
Economics of Adhesive Technology	p. 11
Literature and Other Sources of Information	p. 12
Summary	p. 14
References	p. 14
The Mechanical Properties of Materials as They Relate to Adhesion	p. 15
Introduction	p. 15
Definition of Mechanical Stresses for Materials Testing	p. 15
Stress-Strain Plots and the Definition of Materials Property Parameters	p. 17
Tensile Forces	p. 17
Shear Forces	p. 20
Strain Energy Density	p. 20
Introduction to Linear Elastic Fracture Mechanics	p. 21
Introduction to Rheology of Liquids	p. 24
Introduction to Linear Viscoelasticity	p. 26
An Application of Materials Properties and Mechanics: The Bending of Beams	p. 31
Summary	p. 39
Bibliography	p. 39
Problems and Review Questions	p. 39
Mechanical Tests of Adhesive Bond Performance	p. 43
Introduction	p. 43
Failure Modes and the Definition of Practical Adhesion	p. 43
Tensile Testing of Adhesive Bonds	p. 44
Shear Loading of Adhesive Bonds	p. 48
The Standard Lap Shear Specimen	p. 48
Variations on the Lap Shear Specimen	p. 53
Specimen for Determining the True Shear Properties of an Adhesive	p. 55
The Goland--Reissner Analysis of the Lap Shear Specimen	p. 56
Cleavage Loading of Adhesive Bonds	p. 63
Cleavage or Fracture Specimens	p. 63
Double Cantilever Beam Specimens	p. 65
Linear Elastic Fracture Mechanics Applied to the Double Cantilever Beam Specimen	p. 66
Blister Test	p. 68
Compact Tension Test	p. 68
Wedge Test	p. 69
Peel Tests	p. 70
Stress Analysis in a Peel Specimen	p. 73
Summary	p. 76
Bibliography	p. 76
References	p. 76
Problems and Review Questions	p. 77
The Basics of Intermolecular Forces and Surface Science	p. 78
Introduction	p. 78
Fundamental Forces	p. 78
Electrostatic Forces	p. 80
van der Waals Interactions	p. 81
Dipole--Dipole Interactions	p. 81
Dipole-Induced Dipole	p. 83
Dispersion Forces	p. 83
Interactions through Electron Pair Sharing	p. 85
Repulsive Forces	p. 86
Surface Forces and Surface Energy	p. 86
Work of Cohesion and Adhesion	p. 90
Methods of Measurement of Surface Energy and Related Parameters	p. 92
Surface Tension	p. 92
Drop Weight/Volume Method	p. 93
du Nuoy Tensiometer	p. 93
Surface Energy of Solids	p. 94
Contact Angle Methods	p. 94
Contact Mechanics and Direct Measurement of Solid Surface Energy	p. 96
Surface Thermodynamics and Predictions of Surface and Interfacial Tensions	p. 102
The Good--Girifalco Relationship	p. 104
The Fowkes Hypothesis and Fractional Polarity	p. 105
The Zisman Plot	p. 107
Modern Application of Contact Angle Measurements	p. 108
Modern Methods of Surface Analysis	p. 109
Modern Methods for the Analysis of the Chemistry of Surfaces	p. 112
Topological Methods of Surface Analysis	p. 112
Summary	p. 114
Bibliography	p. 114
References	p. 114
Problems and Review Questions	p. 116
Basic Physico/Chemical Properties of Polymers	p. 118
Introduction	p. 118
Basic Terminology	p. 118
Monomers versus Polymers	p. 118
Basic Types of Polymeric Materials	p. 119
Molecular Weight	p. 120
Thermal Transitions of Polymers	p. 122
Measurement of T[subscript g]	p. 123
Dynamic Mechanical Measurements and Viscoelasticity	p. 124
Methods of Measurement of Dynamic Mechanical Properties	p. 124
Examples of Dynamic Mechanical Data for Polymers	p. 126
Time-Temperature Superposition	p. 129
Summary	p. 131
Bibliography	p. 131
References	p. 131
The Relationship of Surface Science and Adhesion Science	p. 132
Introduction	p. 132
Rationalizations of Adhesion Phenomena	p. 132
Electrostatic Theory of Adhesion	p. 133
Diffusion Theory of Adhesion	p. 135
Diffusive Adhesive Bonding and Block Copolymers at Interfaces	p. 138
Mechanical Interlocking and Adhesion	p. 141
Kinetics of Pore Penetration	p. 144
Wettability and Adhesion	p. 145
Acid-Base Interactions at Interfaces	p. 144
Covalent Bonding at Interfaces	p. 151
Coupling Agents	p. 153
The Relationship of Fundamental Forces of Adhesion and Practical Adhesion	p. 155
The Weak Boundary Layer	p. 159
Summary	p. 160
Bibliography	p. 161
References	p. 161
Problems and Review Questions	p. 162
The Surface Preparation of Adherends for Adhesive Bonding	p. 164
Introduction	p. 164
Plastic Surface Preparation	p. 166
Corona Discharge Treatment	p. 166
Corona Discharge Treatment of Polyethylene	p. 168
Corona Discharge Treatment of Polypropylene	p. 171
Corona Discharge Treatment of Poly(ethylene terephthalate)	p. 171
Corona Discharge Treatment of Other Materials	p. 173
Flame Treatment	p. 174
Plasma Treatment	p. 176
Plasma Treatment of PE	p. 177
Plasma Treatment of Other Substrates	p. 180
Other Physical Treatment Methods of Polymer Surfaces	p. 180
Treatments Using Ultraviolet Radiation	p. 180
Other Vacuum Methods of Surface Preparation	p. 181
Wet Chemical Methods of Treatment of Polymer Surfaces	p. 181
Single Surface Chemical Functionalization and Chromic Acid Treatment of PE	p. 182
Wet Chemical Surface Treatment of Poly(tetrafluoroethylene)	p. 183
Priming of Polymer Surfaces	p. 184
Priming of Polyolefins for Cyanoacrylates	p. 184
Chlorinated Polyolefins	p. 184
Metal Surface Preparation	p. 185
Surface Preparation of Aluminum for Adhesive Bonding	p. 186
The Forest Products Laboratory (FPL) Etch	p. 186
Anodization Treatments for Adhesive Bonding of Aluminum	p. 190
Mechanism of Anodization	p. 191
Anodization Media	p. 191
Phosphoric Acid Anodization in the Aerospace Industry	p. 193
General Techniques for the Surface Preparation of Metals	p. 194
Conversion Coatings	p. 194
Abrasion	p. 195
Electrochemical Methods for Treating Metals other than Aluminum	p. 196
Summary	p. 197
Bibliography	p. 197
References	p. 197
Problems and Review Questions	p. 199
The Chemistry and Physical Properties of Structural Adhesives	p. 201
Introduction to Chapters 8-10	p. 201
Introduction to Structural Adhesives	p. 201
Physical Forms of Uncured Structural Adhesives	p. 202
Chemistry of Base Resins Used in Structural Adhesives	p. 204
Phenolics	p. 204
Proteins	p. 206
Epoxy Resins	p. 207
Time-Temperature-Transformation Diagrams and the Cure of Epoxy Resins	p. 211
Urethane Resins	p. 213
Acrylics	p. 215
High Temperature Performance Structural Adhesives	p. 217
Formulation of Structural Adhesives for Optimum Performance	p. 220
Formulation of Phenolic Resins	p. 221
Epoxy Resins	p. 223
Acrylics	p. 230
High Temperature Performance Structural Adhesives	p. 232
Summary	p. 234
Bibliography	p. 234
References	p. 234
Problems and Review Questions	p. 236
The Chemistry and Physical Properties of Elastomer-Based Adhesives	p. 238
Introduction	p. 238
Pressure-Sensitive Adhesives	p. 238
Chemistry of the Base Resins Used in PSAs	p. 239
Chemistry of Tackifiers	p. 242
Natural Product Based Tackifiers	p. 242
Petroleum-Based Tackifiers	p. 243
Other Tackifiers	p. 245
Testing of Pressure-Sensitive Adhesives	p. 246
Measurements of Tack	p. 246
Measurement of Peel	p. 248
Measurement of Shear	p. 249
Balance of Properties	p. 250
PSA Performance Viewed as a Time Scale in Viscoelastic Response	p. 251
PSA Viscoelasticity and Tack	p. 251
PSA Peel and Viscoelasticity	p. 255
Shear and Creep Behavior of PSAs	p. 257
Summary	p. 259
Rubber-Based, Contact Bond and Other Elastomeric Adhesives	p. 259
Formulation of RBAs	p. 260
Base Polymers	p. 260
Tackifiers	p. 262
Pigments and Fillers	p. 262
Crossliking/Vulcanization of RBAs	p. 263
Solvents	p. 264
Elastomeric Adhesives, Sealants, and Realease Coatings Based upon Silicone Chemistry	p. 265
Summary	p. 266
Bibliography	p. 268
References	p. 268
Problems and Review Questions	p. 268
Thermoplastic, Pseudothermoplastic, and Other Adhesives	p. 270
Introduction	p. 270
Hot Melt Adhesives	p. 270
Introduction	p. 270
Polymer Physical Properties and Hot Melt Adhesives	p. 271
Formulation of Hot Melt Adhesives	p. 273
Synthetically Designed Hot Melt Adhesives	p. 277
Curing Hot Melts	p. 280
Polyvinyl Acetate-Based Adhesives	p. 282
Polyvinyl Acetal Adhesives	p. 282
Thermoplastic or Pseudo-Thermoplastic Adhesives Based upon Natural Products	p. 283
Starches	p. 283
Cellulosics	p. 284
Summary	p. 285
Bibliography	p. 285
References	p. 285
The Basis for Adhesive Bond Design	p. 286
Introduction	p. 286
Chemistry and Mechanical Properties of Adhesives	p. 286
Application Criteria	p. 289
Interfaces and Surface Preparations	p. 292
Miscellaneous Concerns	p. 293
Basic Criteria for the Design of an Adhesive Bond	p. 294
Hart-Smith Design Criteria for Double Lap Joints	p. 296
Summary	p. 299
References	p. 299
Problems and Review Questions	p. 300
Answer Key	p. 301
Index	p. 313
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