Organic Chemistry Second Semester Topics

Name: Organic Chemistry Second Semester Topics
Price: 4.57 USD
Availability: InStock
ISBN: 9781118144343

ISBN-10: 1118144341

ISBN-13: 9781118144343

Edition: 3rd 2012

Authors: David R. Klein

List price: $64.95

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Book details

List price: $64.95
Edition: 3rd
Copyright year: 2012
Publisher: John Wiley & Sons, Incorporated
Publication date: 10/19/2011
Binding: Paperback
Pages: 368
Size: 6.18" wide x 9.13" long x 0.51" tall
Weight: 0.880
Language: English




IR Spectroscopy



Vibrational Excitation



IR Spectra



Wavenumber



Signal Intensity



Signal Shape



Analyzing an IR Spectrum



NMR Spectroscopy



Chemical Equivalence



Chemical Shift (Benchmark Values)



Integration



Multiplicity



Pattern Recognition



Complex Splitting



No Splitting



Hydrogen Deficiency Index (Degrees of Unsaturation)



Analyzing a Proton NMR Spectrum



13C NMR Spectroscopy



Electrophilic Aromatic Substitution



Halogenation and the Role of Lewis Acids



Nitration



Friedel-Crafts Alkylation and Acylation



Sulfonation



Activation and Deactivation



Directing Effects



Identifying Activators and Deactivators



Predicting and Exploiting Steric Effects



Synthesis Strategies



Nucleophilic Aromatic Substitution



Criteria for Nucleophilic Aromatic Substitution



SNAr Mechanism



Elimination-Addition



Mechanism Strategies



Ketones And Aldehydes



Preparation of Ketones and Aldehydes



Stability and Reactivity of Cï¿½O Bonds



H-Nucleophiles



O-Nucleophiles



S-Nucleophiles



N-Nucleophiles



C-Nucleophiles



Some Important Exceptions to the Rule



How to Approach Synthesis Problems



Carboxylic Acid Derivatives



Reactivity of Carboxylic Acid Derivatives



General Rules



Acid Halides



Acid Anhydrides



Esters



Amides and Nitriles



Synthesis Problems



Enols And Enolates



Alpha Protons



Keto-Enol Tautomerism



Reactions Involving Enols



Making Enolates



Haloform Reaction



Alkylation of Enolates



Aldol Reactions



Claisen Condensation



Decarboxylation



Michael Reactions



Amines



Nucleophilicity and Basicity of Amines



Preparation of Amines through SN2 Reactions



Preparation of Amines through Reductive Amination



Acylation of Amines



Reactions of Amines with Nitrous Acid



Aromatic Diazonium Salts


Answer Key


Index