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Preface | |
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Introduction and Fundamental Concepts | |
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Electrokinetic Mechanisms for Microfluidic and Nanofluidic Transport | |
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Introduction to Microfluidic and Nanofluidic Systems | |
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Microscale and Nanoscale Electrokinetic Transport | |
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Organization | |
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Electrostatics | |
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Coulomb's Law | |
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Electric Field and Potential | |
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Charge Density | |
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Electric-Field Vector Relationships | |
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Gauss' Law: The Flux of the Electric Field | |
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Fundamental Concepts of Electrokinetic Theories | |
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Constitutive Relations Governing Continuum Hydrodynamics | |
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Induced Dipoles, Interfacial Conditions, and the Maxwell Stress Tensor | |
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Electrokinetic Actuation of Dielectric Liquids - Gradients in the Maxwell Pressure | |
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Constitutive Equation for Ion Transport | |
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Classical Equilibrium Theory Due to Surface Charges | |
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The Debye Double Layer | |
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Surface Charging | |
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Concentration Polarization of Ions - The Screening Effect | |
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Poisson-Boltzmann Distribution | |
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The Poisson-Boltzmann Distribution and Surface Electric Field | |
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Osmotic Pressure, Conservative Force, and Stability of the Poisson-Boltzmann Distribution | |
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Repulsive Forces Between Charged or Constant-Potential Particles in Electrolytes Under Poisson-Boltzmann Equilibrium | |
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The Debye-H�ckel Theory | |
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Nonlinear Analysis of the Poisson-Boltzmann Equilibrium in the Debye Layer | |
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Extensions to the Diffuse Double Layer Theory | |
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Attraction Between Identical Particles Due to Symmetry Breaking | |
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Overlapping Double Layers in Nanopores: Pore Conductance and Threshold Field for Electro-Osmotic Flow | |
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Double Layer Formation and Relaxation Dynamics | |
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Equilibrium Double Layer Electrokinetic Phenomena | |
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Electro-Osmotic Transport | |
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Electro-Osmosis | |
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Smoluchowski Slip in Microchannels | |
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Electro-Osmotic Slip Velocity with Bulk Concentration Gradients: Formal Asymptotics | |
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Electro-Osmotic Flow in Nanochannels | |
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Mixed or Frustrated Flows | |
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DC Electrokinetic Pumps | |
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Electric Field and Hydrodynamic Streamline Similarity | |
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Frustrated Flow and Vortex Formation Due to pH Gradients | |
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Conductivity-Gradient-Driven Electrohydrodynamic Instabilities | |
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Conductivity Gradients in the Direction of the Applied Field | |
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Conductivity Gradients Transverse to the Direction of the Applied Field | |
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Hydrodynamic Dispersion and Channel Profiling | |
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Electroviscous Effects Due to the Streaming Potential in a Finite-Length Nanochannel: The Zero-Current Model | |
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Electrophoretic Transport and Separation | |
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Uniform Charge Electrophoresis: Classical Theory | |
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Combined Electrophoresis and Electro-Osmotic Convection | |
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Electroviscous Effects | |
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Cellular Electrophoresis Involving a Conducting Layer of Charges | |
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Electrophoresis with Surface Charge Migration and Counterion Condensation Effects | |
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Other Conductive Electrophoresis Theories - Conducting Stern Layer and Convective Current Effects | |
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A General Electrophoresis Theory in the Debye-H�ckel Limit | |
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Capillary Electrophoresis: Applications | |
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Capillary Zone Electrophoresis | |
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Capillary Gel Electrophoresis | |
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Micellar Electrokinetic Chromatography | |
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Capillary Isotachophoresis | |
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Capillary Isoelectric Focusing | |
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Capillary Electrochromatography | |
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End-Labeled Free-Solution Electrophoresis | |
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Field-Induced Dielectric Polarization | |
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Nonequilibrium Electrokinetics | |
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Dielectric Polarization | |
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Dielectric Materials and Dipole Formation | |
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Polarization Mechanisms | |
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Impedance Characterization of Relaxation Times | |
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Interfacial Polarization | |
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Interfacial Polarizability - The Clausius-Mossotti Factor | |
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Dielectric Dispersion | |
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Bacterial Growth Detection Through Reactance Measurements | |
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DC Nonlinear Electrokinetics Due to Field-Induced Double Layer Polarization | |
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DC Nonlinear Electrokinetics | |
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Electrokinetic Flow Manipulation Using Field (Capacitance) Effects | |
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Concentration Polarization at Nearly Insulated Wedges | |
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Electrokinetic Phenomenon of the Second Kind | |
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Extended Polarized Layer: Current-Voltage Relationship | |
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Dukhin's Model and Tangential Convection Effects | |
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Low P�clet Numbers - The Dukhin Theory | |
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High P�clet Numbers - Tangential Convection Enhancement of the Normal Flux | |
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Electrokinetic Vortex Generation for Micromixing | |
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Dynamic Superconcentration at Critical-Point Double Layer Gates | |
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Vortex Instability of Extended Polarized Layers and Selection of Overlimiting Currents | |
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Nonlinear Current-Voltage Characteristics of Nanopores | |
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AC Nonlinear Electro-Osmosis Due to Field-Induced Double Layer Polarization | |
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AC Nonlinear Electrokinetics | |
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Derivation of the AC Electro-Osmotic Slip Velocity | |
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Double Layer Electrostatic Model | |
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Hydrodynamic Model | |
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Bulk Potential | |
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Flow Reversal | |
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Planar Converging Stagnation Flow on Symmetric Coplanar Electrodes | |
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Normal Double Layer Charging of Passive Metal Surfaces | |
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Electrothermal AC Electro-Osmosis | |
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Dielectrophoresis and Electrorotation - Double Layer Effects | |
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Ponderomotive Forces | |
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Dielectrophoresis | |
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Classical Maxwell-Wagner Theory | |
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Low-Conductivity Limit (a “�D) - Conducting Stern and Diffuse Layer Correction | |
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Normal Capacitive Charging | |
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Intermediate Conductivity Limit (a | |