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Introduction | |
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What is a Mineral? | |
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Defining a Mineral More Broadly | |
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Where Do We Find Minerals and What Can We Learn? | |
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Minerals as Integral to Earth Science | |
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Mineralogy as Important to Other Fields | |
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Disciplines of Mineral Science | |
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History of Mineralogy | |
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Minerals in Our Lives | |
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Naming of Minerals | |
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References and Literature of Mineralogy | |
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What's to Come | |
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Standard Mineralogical Reference Works and Further Reading | |
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Physical Properties of Minerals | |
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Crystal Shape | |
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Properties Based on Interaction with Light | |
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Luster | |
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Color | |
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Streak | |
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Play of Colors | |
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Chatoyancy and Asterism | |
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Luminescence | |
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Fluorescence and Phosphorescence | |
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Mechanical Properties | |
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Cleavage | |
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Parting | |
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Fracture | |
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Hardness | |
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Tenacity | |
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Properties Related to Mass | |
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Density and Specific Gravity | |
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Factors That Affect Density and Specific Gravity | |
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Average Specific Gravity | |
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Measurement of Specific Gravity | |
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Other Diagnostic Properties | |
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Magnetism | |
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Radioactivity | |
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Solubility in Acids | |
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Other Sensory Tests | |
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Electrical Properties (of Industrial Use) | |
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Piezoelectricity | |
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Pyroelectricity | |
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References and Further Reading | |
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Elements of Crystal Chemistry | |
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The Atom | |
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Electron Configuration | |
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Chemical Elements, Electronic Configuration, and the Periodic Table | |
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Atomic and Ionic Radii | |
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The Ion | |
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Bonding Forces in Crystals | |
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Bonds with Valence Electrons | |
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Ionic Bond | |
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Metallic Bond | |
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Covalent Bond | |
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Estimation of the Character of the Bonding Mechanism | |
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Electronegativity | |
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Bonds That Do Not Involve Valence Electrons | |
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Van der Waals Bond | |
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Hydrogen Bond | |
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Crystals with More Than One Bond Type | |
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References and Further Reading | |
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Aspects of Crystal Structures | |
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Coordination of Ions | |
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Pauling's Rules | |
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The Coordination Principle | |
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Other Coordination Geometries | |
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Coordination of Common Cations | |
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The Electrostatic Valency Principle | |
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Uniform Bond Strength | |
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Nonuniform Bond Strength | |
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Sharing of Polyhedral Elements, 1 | |
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Sharing of Polyhedral Elements, 2 | |
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The Principle of Parsimony | |
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Additional Controls on Mineral Structures | |
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Isostructuralism | |
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Polymorphism | |
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Illustration of Crystal Structures | |
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Examples of Selected Common Structure Types | |
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NaCl Structure | |
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CsCl Structure | |
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Sphalerite (ZnS) Structure | |
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CaF[subscript 2] Structure | |
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Rutile (TiO[subscript 2]) Structure | |
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Perovskite(ABO[subscript 3]) Structure | |
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Spinel (AB[subscript 2]O[subscript 4]) Structure | |
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Silicate Structures | |
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References and Further Reading | |
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Chemical Composition of Minerals | |
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Composition of the Earth | |
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Composition of the Earth's Crust | |
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Composition of the Mantle | |
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Composition of the Core | |
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Composition of the Earth | |
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Variability of Mineral Compositions | |
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Substitutional Solid Solution | |
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Coupled Substitution | |
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Interstitial Solid Solution | |
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Omission Solid Solution | |
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Determination of a Mineral Formula | |
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Calculation of Mineral Formulae from Metal Percentages | |
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Mineral Formulae from Oxide Weight Percentages | |
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Mineral Formulae for Hydrous Silicates | |
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Graphical Representation of Mineral Composition | |
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Linear or Bar Diagrams | |
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Triangular Diagrams | |
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Triangular Representation of More Than Three Components | |
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References and Further Reading | |
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Crystallography: External Symmetry of Minerals | |
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Symmetry | |
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Symmetry Elements (Without Translation) | |
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Rotation | |
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Reflection (Mirror) | |
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Center of Symmetry | |
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Rotation with Inversion | |
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Symmetry Notation | |
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Combinations of Rotations | |
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Combinations of Rotation Axes and Mirrors | |
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Combinations of Symmetry Operations Without Translation | |
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Crystal Systems | |
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Crystallographic Axes | |
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Crystallographic Notation for Planes | |
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Face Intercepts | |
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Miller Indices | |
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Zones | |
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Crystal Form | |
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Names of Forms | |
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Illustration and Description of Forms | |
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References and Further Reading | |
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Bilateral Symmetry in Humans and Architecture | |
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Internal Order and Symmetry In Minerals | |
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Translation Directions and Distances | |
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One-Dimensional Order-Rows | |
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Two-Dimensional Order-Plane Lattices | |
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Rotation Angle Restrictions | |
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Symmetry Content of Planar Motifs | |
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Symmetry Content of Plane Lattices | |
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Two-Dimensional Plane Groups | |
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Three-Dimensional Order | |
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Three-Dimensional Lattices | |
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Symmetry Elements in 3D that Involve Translation: Screw Axes and Glide Planes | |
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Space Groups | |
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References and Further Reading | |
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Patterns in Our Environment | |
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Periodic Drawings | |
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Crystal Projections | |
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Spherical Projection | |
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Stereographic Projection | |
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Stereographic Net and the Mechanics of Plotting | |
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Measuring Crystal Angles | |
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Projection of an Orthorhombic Crystal | |
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Projection of a Monoclinic Crystal | |
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References and Further Reading | |
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Selected Point Groups and Further Aspects of Space Groups | |
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Nineteen of the Thirty-Two Point Groups | |
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Triclinic System | |
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Monoclinic System | |
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Orthorhombic System | |
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Tetragonal System | |
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Hexagonal System | |
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Isometric System | |
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Characteristics of Isometric Crystals | |
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Representations of Some Space Groups | |
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Space Group Derivation | |
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Illustrations of Space Groups | |
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References and Further Reading | |
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Crystal Growth and Defects; Twinning, Color, and Magnetism | |
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Crystal Growth | |
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Vectorial Properties | |
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Structural Complexities and Defects | |
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Point Defects | |
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Line Defects | |
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Planar Defects | |
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Other Defects | |
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Mineralogic Examples of Defect Structures | |
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Intergrowths of Crystals | |
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Twinning | |
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Twin Classification | |
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Common Twin Laws | |
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Triclinic System | |
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Monoclinic System | |
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Orthorhombic System | |
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Tetragonal System | |
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Hexagonal System | |
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Isometric System | |
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Origin of Color | |
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Crystal Field Transitions | |
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Molecular Orbital Transitions | |
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Color Centers | |
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Physical Processes as a Cause of Color | |
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Origin of Magnetic Properties | |
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Mineraloids (Noncrystalline Minerals) | |
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References and Further Reading | |
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Mineral Stability and Phase Diagrams | |
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Stability, Activation Energy, and Equilibrium | |
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Introductory Thermodynamics | |
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Phase Diagrams | |
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Components | |
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Examples of Mineral Stability (Phase) Diagrams | |
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One-Component Diagrams | |
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Two-Component Diagrams | |
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Three- or More-Component Diagrams | |
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Diagrams for Mineral Reactions Involving H[subscript 2]O or CO[superscript 2] | |
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Eh-pH Diagrams | |
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References and Further Reading | |
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Post-Crystallization Processes in Minerals | |
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Polymorphic Reactions | |
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Reconstructive Polymorphism | |
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Displacive Polymorphism | |
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Order-Disorder Polymorphism | |
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Polytypism | |
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Secondary Twinning | |
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Exsolution | |
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Radioactivity and Metamictization | |
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Metamict Minerals | |
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Pseudomorphism | |
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References and Further Reading | |
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Optical Microscopy | |
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Nature of Light | |
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Reflection and Refraction | |
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Refractive Index and Snell's Law | |
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Total Reflection and the Critical Angle | |
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Isotropic and Anisotropic Crystals | |
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Polarized Light | |
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Polarized Light by Absorption | |
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Polarized Light by Reflection | |
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The Polarizing Microscope | |
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Microscopic Examination of Minerals and Rocks | |
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Isotropic Crystals and the Becke Line | |
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Uniaxial Crystals | |
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Uniaxial Crystals Between Crossed Polars | |
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Extinction | |
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Interference | |
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Accessory Plates | |
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Uniaxial Crystals in Convergent Polarized Light | |
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Determination of Optic Sign | |
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Sign of Elongation | |
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Absorption and Dichroism | |
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Biaxial Crystals | |
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The Biaxial Indicatrix | |
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Optical Orientation in Biaxial Crystals | |
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Biaxial Crystals in Convergent Polarized Light | |
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The Apparent Optic Angle | |
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Determination of Optic Sign of Biaxial Crystals | |
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Absorption and Pleochroism | |
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Other Properties | |
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Optical Properties of Opaque Minerals | |
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References and Further Reading | |
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Analytical and Imaging Methods in Mineral Science | |
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Technique Overview | |
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Techniques That Use X-rays | |
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X-ray Diffraction Techniques (XRD) | |
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X-ray Spectra | |
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Diffraction Effects and the Bragg Equation | |
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Single-Crystal X-ray Diffraction and Structure Analysis | |
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The Determination of Crystal Structures | |
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X-ray Powder Diffraction and Mineral Identification | |
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X-ray Fluorescence Analysis (XRF) | |
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Electron Beam Techniques | |
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Scanning Electron Microscopy (SEM) | |
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Transmission Electron Microscopy (TEM) | |
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Electron Microprobe Analysis (EMPA) | |
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Additional Techniques | |
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Secondary Ion Mass Spectrometry (SIMS) | |
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Atomic Force Microscopy (AFM) | |
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References and Further Reading | |
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Crystal Chemistry and Systematic Descriptions of Native Elements, Sulfides, and Sulfosalts | |
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Mineral Classification | |
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Crystal Chemistry of Native Elements, Sulfides, and Sulfosalts | |
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Native Elements | |
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Native Metals | |
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Native Semimetals | |
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Native Nonmetals | |
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Sulfides | |
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Sulfosalts | |
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Systematic Descriptions | |
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Native Metals | |
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Native Nonmetals | |
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Sulfides, Sulfarsenides, and Arsenides | |
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Sulfosalts | |
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References and Further Reading | |
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Economic Geology | |
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Diamond Synthesis | |
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Veins and Vein Mineralization | |
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Sulfide Minerals as Ores and as Mining-Related Contaminants | |
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Crystal Chemistry and Systematic Descriptions of Oxides, Hydroxides, and Halides | |
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Crystal Chemistry of Oxides | |
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Crystal Chemistry of Hydroxides | |
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Crystal Chemistry of Halides | |
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Systematic Descriptions | |
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Oxides | |
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Hydroxides | |
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Halides | |
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References and Further Reading | |
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Ore Minerals for the Steel Industry | |
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Evaporite Minerals | |
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Crystal Chemistry and Systematic Descriptions of Carbonates, Nitrates, Borates, Sulfates, Chromates, Tungstates, Molybdates, Phosphates, Arsenates, and Vanadates | |
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Crystal Chemistry of Carbonates | |
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Calcite Group | |
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Aragonite Group | |
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Dolomite Group | |
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Crystal Chemistry of Nitrates | |
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Crystal Chemistry of Borates | |
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Crystal Chemistry of Sulfates | |
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Crystal Chemistry of Tungstates and Molybdates | |
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Crystal Chemistry of Phosphates, Arsenaes, and Vanadates | |
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Systematic Descriptions | |
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Carbonates | |
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Nitrates | |
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Borates | |
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Sulfates and Chromates | |
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Tungstates and Molybdates | |
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Phosphates, Arsenates, and Vanadates | |
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References and Further Reading | |
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The Source of Chemicals in Fertilizers | |
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Crystal Chemistry of Rock-Forming Silicates | |
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Nesosilicates | |
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Sorosilicates | |
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Cyclosilicates | |
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Inosilicates | |
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Pyroxene Group | |
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Pyroxenoid Group | |
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Amphibole Group | |
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Phyllosilicates | |
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Tectosilicates | |
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SiO[subscript 2] Group | |
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Feldspar Group | |
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Structure | |
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Composition | |
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Feldspathoid Group | |
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Zeolite Group | |
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References and Further Reading | |
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Systematic Descriptions of Rock-Forming Silicates | |
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Nesosilicates | |
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Phenacite Group | |
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Olivine Group | |
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Garnet Group | |
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Al[subscript 2]SiO[subscript 2] Group | |
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Humite Group | |
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Sorosilicates | |
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Epidote Group | |
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Cyclosilicates | |
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Inosilicates | |
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Pyroxene Group | |
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Pyroxenoid Group | |
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Amphibole Group | |
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Phyllosilicates | |
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Serpentine Group | |
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Clay Mineral Group | |
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Mica Group | |
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Chlorite Group | |
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Related Species | |
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Tectosilicates | |
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SiO[subscript 2] Group | |
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Feldspar Group | |
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K-Feldspars | |
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Feldspathoid Group | |
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Scapolite Series | |
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Zeolite Group | |
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References and Further Reading | |
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The Two Most Common Crustal Rock Types: Basalt and Granite | |
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Asbestos: A Mixture and Mix-Up of Minerals | |
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Clay Minerals and Some of Their Applications | |
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Mineral Dust in the Environment | |
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Minerals in Pegmatites | |
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Zeolites and Their Many Unique Properties | |
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Gem Minerals | |
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Gem Minerals | |
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Gem Qualifications | |
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Types of Gem Cuts | |
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The Early Uses of Gems | |
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Important Gems-Past and Present | |
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Diamond | |
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Beryl | |
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Ruby and Sapphire | |
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Opal | |
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Jade | |
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Chrysoberyl | |
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Topaz | |
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Tourmaline | |
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Quartz | |
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Turquoise | |
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Garnet | |
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Zircon | |
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Olivine | |
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Gem Properties and Instruments for Their Determination | |
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Physical Properties | |
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Cleavage and Fracture | |
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Hardness | |
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Specific Gravity | |
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Fluorescence | |
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Instruments for Studying Gems | |
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Observation | |
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Hand Lens | |
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The Microscope | |
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The Polariscope | |
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Refractive Index and the Refractometer | |
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Dispersion | |
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The Dichroscope | |
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Color Filters | |
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The Spectroscope | |
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X-ray Diffraction | |
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Synthesis of Gem Materials | |
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Verneuil Process | |
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Czochralski Process | |
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Flux Growth | |
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Hydrothermal Growth | |
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Treatment of Gemstones | |
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Dyeing | |
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Heat Treatment | |
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Irradiation | |
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Synthetic and Treated Gems | |
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Beryl | |
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Chrysoberyl | |
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Corundum (Ruby and Sapphire) | |
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Diamond | |
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Jade | |
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Opal | |
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Quartz | |
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Rutile | |
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Spinel | |
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Turquoise | |
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Manufactured Gem Materials Without Natural Counterparts | |
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Garnet | |
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Strontium Titanate | |
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Cubic Zirconia | |
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References and Further Reading | |
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Mineral Assemblages: Introduction to Rock Types | |
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Igneous Rocks | |
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General Occurrence and Texture | |
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Chemical Composition | |
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Classification | |
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Mineralogical Composition | |
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Plutonic Rocks | |
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Volcanic Rocks | |
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Fragmental Igneous Rocks | |
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Pegmatites | |
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Sedimentary Rocks | |
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Chemical Composition | |
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Mineralogical Composition | |
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Classification | |
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Terrigenous Sedimentary Rocks | |
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Allochemical Carbonate Rocks | |
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Orthochemical Sedimentary Rocks | |
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Further Description of Rock Types | |
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Metamorphic Rocks | |
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Chemical Composition | |
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Mineralogical Composition | |
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Rock Types | |
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References and Further Reading | |
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Determinative Tables | |
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General Classification of the Tables | |
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Luster-Metallic or Submetallic | |
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Luster-Nonmetallic | |
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Minerals Arranged by Several Physical Properties | |
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Minerals Arranged According to Increasing Specific Gravity | |
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Nonopaque Minerals and Some Synthetic Compounds Arranged According to Increasing Refractive index | |
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Outstanding Contributions to the Mineral Sciences | |
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Development of Models for the Atom | |
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Distribution of Forms in 32 Point Groups, Arranged by Crystal System | |
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Space Groups as an Expression of Morphology and Structure | |
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Mineral Index | |
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Subject Index | |