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Preface | |
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Introduction | |
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Types of Polymers and Polymerizations | |
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Nomenclature of Polymers | |
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Linear, Branched, and Crosslinked Polymers | |
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Molecular Weight | |
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Physical State | |
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Applications of Polymers | |
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References | |
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Step Polymerization | |
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Reactivity of Functional Groups | |
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Kinetics of Step Polymerization | |
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Accessibility of Functional Groups | |
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Equilibrium Considerations | |
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Cyclization versus Linear Polymerization | |
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Molecular Weight Control in Linear Polymerization | |
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Molecular Weight Distribution in Linear Polymerization | |
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Process Conditions | |
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Multichain Polymerization | |
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Crosslinking | |
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Molecular Weight Distributions in Nonlinear Polymerizations | |
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Crosslinking Technology | |
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Step Copolymerization | |
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High-Performance Polymers | |
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Inorganic and Organometallic Polymers | |
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Dendritic (Highly Branched) Polymers | |
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Miscellaneous Topics | |
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References | |
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Radical Chain Polymerization | |
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Nature of Radical Chain Polymerization | |
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Structural Arrangement of Monomer Units | |
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Rate of Radical Chain Polymerization | |
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Initiation | |
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Molecular Weight | |
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Chain Transfer | |
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Inhibition and Retardation | |
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Determination of Absolute Rate Constants | |
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Energetic Characteristics | |
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Autoacceleration | |
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Molecular Weight Distribution | |
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Effect of Pressure | |
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Process Conditions | |
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Specific Commercial Polymers | |
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Living Radical Polymerization | |
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Other Polymerizations | |
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References | |
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Emulsion Polymerization | |
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Description of Process | |
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Quantitative Aspects | |
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Other Characteristics of Emulsion Polymerization | |
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References | |
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Ionic Chain Polymerization | |
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Comparison of Radical and Ionic Polymerizations | |
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Cationic Polymerization of the Carbon-Carbon Double Bond | |
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Anionic Polymerization of the Carbon-Carbon Double Bond | |
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Block and Other Polymer Architectures | |
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Distinguishing Between Radical, Cationic, and Anionic Polymerizations | |
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Carbonyl Polymerization | |
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Miscellaneous Polymerizations | |
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References | |
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Chain Copolymerization | |
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General Considerations | |
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Copolymer Composition | |
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Radical Copolymerization | |
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Ionic Copolymerization | |
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Deviations from Terminal Copolymerization Model | |
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Copolymerizations Involving Dienes | |
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Other Copolymerizations | |
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Applications of Copolymerization | |
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References | |
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Ring-Opening Polymerization | |
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General Characteristics | |
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Cyclic Ethers | |
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Lactams | |
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N-Carboxy-[alpha]-Amino Acid Anhydrides | |
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Lactones | |
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Nitrogen Heterocyclics | |
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Sulfur Heterocyclics | |
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Cycloalkenes | |
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Miscellaneous Oxygen Heterocyclics | |
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Other Ring-Opening Polymerizations | |
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Inorganic and Partially Inorganic Polymers | |
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Copolymerization | |
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References | |
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Stereochemistry of Polymerization | |
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Types of Stereoisomerism in Polymers | |
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Properties of Stereoregular Polymers | |
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Forces of Stereoregulation in Alkene Polymerizations | |
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Traditional Ziegler-Natta Polymerization of Nonpolar Alkene Monomers | |
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Metallocene Polymerization of Nonpolar Alkene Monomers | |
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Other Hydrocarbon Monomers | |
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Copolymerization | |
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Postmetallocene: Chelate Initiators | |
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Living Polymerization | |
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Polymerization of 1,3-Dienes | |
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Commercial Applications | |
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Polymerization of Polar Vinyl Monomers | |
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Aldehydes | |
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Optical Activity in Polymers | |
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Ring-Opening Polymerization | |
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Statistical Models of Propagation | |
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References | |
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Reactions of Polymers | |
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Principles of Polymer Reactivity | |
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Crosslinking | |
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Reactions of Cellulose | |
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Reactions of Poly(vinyl acetate) | |
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Halogenation | |
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Aromatic Substitution | |
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Cyclization | |
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Other Reactions | |
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Graft Copolymers | |
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Block Copolymers | |
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Polymers as Carriers or Supports | |
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Polymer Reagents | |
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Polymer Catalysts | |
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Polymer Substrates | |
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References | |
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Index | |