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Thermodynamics, Fundamentals | |
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First Law of Thermodynamics | |
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Second Law | |
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Variational Statement of Second Law | |
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Application: Thermal Equilibrium and Temperature | |
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Auxiliary Functions and Legendre Transforms | |
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Maxwell Relations | |
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Extensive Functions and the Gibbs-Duhem Equation | |
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Intensive Functions | |
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Conditions for Equilibrium and Stability | |
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Multiphase Equilibrium | |
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Stability | |
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Application to Phase Equilibria | |
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Plane Interfaces | |
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Statistical Mechanics | |
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The Statistical Method and Ensembles | |
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Microcanonical Ensemble and the Rational Foundation of Thermodynamics | |
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Canonical Ensemble | |
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A Simple Example | |
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Generalized Ensembles and the Gibbs Entropy Formula | |
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Fluctuations Involving Uncorrelated Particles | |
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Alternative Development of Equilibrium Distribution Functions | |
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Non-Interacting (Ideal) Systems | |
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Occupation Numbers | |
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Photon Gas | |
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Phonon Gas | |
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Ideal Gases of Real Particles | |
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Electrons in Metals | |
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Classical Ideal Gases, the Classical Limit | |
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Thermodynamics of an Ideal Gas of Structureless Classical Particles | |
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A Dilute Gas of Atoms | |
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A Dilute Gas of Diatomic Molecules | |
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Chemical Equilibria in Gases | |
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Statistical Mechanical Theory of Phase Transitions | |
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Ising Model | |
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Lattice Gas | |
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Broken Symmetry and Range of Correlations | |
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Mean Field Theory | |
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Variational Treatment of Mean Field Theory | |
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Renormalization Group (RG) Theory | |
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RG Theory for the Two Dimensional Ising Model | |
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Isomorphism Between Two-Level Quantum Mechanical System and the Ising Model | |
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Monte Carlo Method in Statistical Mechanics | |
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Trajectories | |
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A Monte Carlo Trajectory | |
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Non-Boltzmann Sampling | |
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Quantum Monte Carlo | |
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Classical Fluids | |
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Averages in Phase Space | |
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Reduced Configurational Distribution Functions | |
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Reversible Work Theorem | |
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Thermodynamic Properties from g(r) | |
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Measurement of g(r) by Diffraction | |
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Solvation and Chemical Equilibrium in Liquids | |
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Molecular Liquids | |
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Monte Carlo for Hard Disks | |
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Statistical Mechanics of Non-Equilibrium Systems | |
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Systems Close to Equilibrium | |
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Onsager's Regression Hypothesis and Time Correlation Functions | |
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Application: Chemical Kinetics | |
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Another Application: Self Diffusion | |
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Fluctuation Dissipation Theorem | |
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Response Functions | |
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Absorption | |
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Friction and the Langevin Equation | |