Introduction to the Thermodynamics of Materials

ISBN-10: 1560329920

ISBN-13: 9781560329923

Edition: 4th 2003 (Revised)

List price: $129.95
30 day, 100% satisfaction guarantee

If an item you ordered from TextbookRush does not meet your expectations due to an error on our part, simply fill out a return request and then return it by mail within 30 days of ordering it for a full refund of item cost.

Learn more about our returns policy

Description:

This edition features a CD-ROM containing the thermodynamic properties of 50 commonly used compounds, a new chapter on 'Phase Diagrams for Binary Systems in Pressure Temperature Composition Space' & new appendices on 'Exact Differential Equations' & 'Generation of Auxiliary Functions as Legendre'.
what's this?
Rush Rewards U
Members Receive:
coins
coins
You have reached 400 XP and carrot coins. That is the daily max!
Study Briefs

Limited time offer: Get the first one free! (?)

All the information you need in one place! Each Study Brief is a summary of one specific subject; facts, figures, and explanations to help you learn faster.

Add to cart
Study Briefs
Periodic Table Online content $4.95 $1.99
Add to cart
Study Briefs
Periodic Table Online content $4.95 $1.99
Add to cart
Study Briefs
Business Ethics Online content $4.95 $1.99
Add to cart
Study Briefs
Business Law Online content $4.95 $1.99
Customers also bought
Loading
Loading
Loading
Loading
Loading
Loading
Loading
Loading
Loading
Loading

Book details

List price: $129.95
Edition: 4th
Copyright year: 2003
Publisher: Routledge
Publication date: 2/7/2003
Binding: Hardcover
Pages: 634
Size: 6.00" wide x 9.00" long x 1.75" tall
Weight: 2.486
Language: English

Preface
Introduction and Definition of Terms
Introduction
The Concept of State
Simple Equilibrium
The Equation of State of an Ideal Gas
The Units of Energy and Work
Extensive and Intensive Properties
Phase Diagrams and Thermodynamic Components
The First Law of Thermodynamics
Introduction
The Relationship between Heat and Work
Internal Energy and the First Law of Thermodynamics
Constant-Volume Processes
Constant-Pressure Processes and the Enthalpy H
Heat Capacity
Reversible Adiabatic Processes
Reversible Isothermal Pressure or Volume Changes of an Ideal Gas
Summary
Numerical Examples
Problems
The Second Law of Thermodynamics
Introduction
Spontaneous or Natural Processes
Entropy and the Quantification of Irreversibility
Reversible Processes
An Illustration of Irreversible and Reversible Processes
Entropy and Reversible Heat
The Reversible Isothermal Compression of an Ideal Gas
The Reversible Adiabatic Expansion of an Ideal Gas
Summary Statements
The Properties of Heat Engines
The Thermodynamic Temperature Scale
The Second Law of Thermodynamics
Maximum Work
Entropy and the Criterion for Equilibrium
The Combined Statement of the First and Second Laws of Thermodynamics
Summary
Numerical Examples
Problems
The Statistical Interpretation of Entropy
Introduction
Entropy and Disorder on an Atomic Scale
The Concept of Microstate
Determination of the Most Probable Microstate
The Influence of Temperature
Thermal Equilibrium and the Boltzmann Equation
Heat Flow and the Production of Entropy
Configurational Entropy and Thermal Entropy
Summary
Numerical Examples
Problems
Auxiliary Functions
Introduction
The Enthalpy H
The Helmholtz Free Energy A
The Gibbs Free Energy G
Summary of the Equations for a Closed System
The Variation of the Composition and Size of the System
The Chemical Potential
Thermodynamic Relations
Maxwell's Equations
The Upstairs-Downstairs-Inside-Out Formula
The Gibbs-Helmholtz Equation
Summary
Example of the Use of the Thermodynamic Relations
Problems
Heat Capacity, Enthalpy, Entropy, and the Third Law of Thermodynamics
Introduction
Theoretical Calculation of the Heat Capacity
The Empirical Representation of Heat Capacities
Enthalpy as a Function of Temperature and Composition
The Dependence of Entropy on Temperature and the Third Law of Thermodynamics
Experimental Verification of the Third Law
The Influence of Pressure on Enthalpy and Entropy
Summary
Numerical Examples
Problems
Phase Equilibrium in a One-Component System
Introduction
The Variation of Gibbs Free Energy with Temperature at Constant Pressure
The Variation of Gibbs Free Energy with Pressure at Constant Temperature
Gibbs Free Energy as a Function of Temperature and Pressure
Equilibrium between the Vapor Phase and a Condensed Phase
Graphical Representation of Phase Equilibria in a One-Component System
Solid-Solid Equilibria
Summary
Numerical Examples
Problems
The Behavior of Gases
Introduction
The P-V-T Relationships of Gases
Deviations from Ideality and Equations of State for Real Gases
The van der Waals Gas
Other Equations of State for Nonideal Gases
The Thermodynamic Properties of Ideal Gases and Mixtures of Ideal Gases
The Thermodynamic Treatment of Nonideal Gases
Summary
Numerical Examples
Problems
The Behavior of Solutions
Introduction
Raoult's Law and Henry's Law
The Thermodynamic Activity of a Component in Solution
The Gibbs-Duhem Equation
The Gibbs Free Energy of Formation of a Solution
The Properties of Raoultian Ideal Solutions
Nonideal Solutions
Application of the Gibbs-Duhem Relation to the Determination of Activity
Regular Solutions
A Statistical Model of Solutions
Subregular Solutions
Summary
Numerical Examples
Problems
Gibbs Free Energy Composition and Phase Diagrams of Binary Systems
Introduction
Gibbs Free Energy and Thermodynamic Activity
The Gibbs Free Energy of Formation of Regular Solutions
Criteria for Phase Stability in Regular Solutions
Liquid and Solid Standard States
Phase Diagrams, Gibbs Free Energy, and Thermodynamic Activity
The Phase Diagrams of Binary Systems That Exhibit Regular Solution Behavior in the Liquid and Solid States
Summary
Numerical Example
Problems
Reactions Involving Gases
Introduction
Reaction Equilibrium in a Gas Mixture and the Equilibrium Constant
The Effect of Temperature on the Equilibrium Constant
The Effect of Pressure on the Equilibrium Constant
Reaction Equilibrium as a Compromise between Enthalpy and Entropy
Reaction Equilibrium in the System SO[subscript 2(g)]-SO[subscript 3(g)]-O[subscript 2(g)]
Equilibrium in H[subscript 2]O-H[subscript 2] and CO[subscript 2]-CO Mixtures
Summary
Numerical Examples
Problems
Reactions Involving Pure Condensed Phases and a Gaseous Phase
Introduction
Reaction Equilibrium in a System Containing Pure Condensed Phases and a Gas Phase
The Variation of the Standard Gibbs Free Energy Change with Temperature
Ellingham Diagrams
The Effect of Phase Transformations
The Oxides of Carbon
Graphical Representation of Equilibria in the System Metal-Carbon-Oxygen
Summary
Numerical Examples
Problems
Reaction Equilibria in Systems Containing Components in Condensed Solution
Introduction
The Criteria for Reaction Equilibrium in Systems Containing Components in Condensed Solution
Alternative Standard States
The Gibbs Phase Rule
Binary Systems Containing Compounds
Graphical Representation of Phase Equilibria
The Formation of Oxide Phases of Variable Composition
The Solubility of Gases in Metals
Solutions Containing Several Dilute Solutes
Summary
Numerical Examples
Problems
Phase Diagrams for Binary Systems in Pressure-Temperature-Composition Space
Introduction
A Binary System Exhibiting Complete Mutual Solubility of the Components in the Solid and Liquid States
A Binary System Exhibiting Complete Mutual Solubility in the Solid and Liquid States and Showing Minima on the Melting, Boiling, and Sublimation Curves
A Binary System Containing a Eutectic Equilibrium and Having Complete Mutual Solubility in the Liquid
A Binary System Containing a Peritectic Equilibrium and Having Complete Mutual Solubility in the Liquid State
Phase Equilibrium in a Binary System Containing an Intermediate [gamma] Phase That Melts, Sublimes, and Boils Congruently
Phase Equilibrium in a Binary System Containing an Intermediate [gamma] Phase That Melts and Sublimes Congruently and Boils Incongruently
Phase Equilibrium in a Binary System with a Eutectic and One Component That Exhibits Allotropy
A Binary Eutectic System in Which Both Components Exhibit Allotropy
Phase Equilibrium at Low Pressure: The Cadmium-Zinc System
Phase Equilibrium at High Pressure: The Na[subscript 2]O[middle dot]Al[subscript 2]O[subscript 3 middle dot]2SiO[subscript 2]-SiO[subscript 2] System
Summary
Electrochemistry
Introduction
The Relationship between Chemical and Electrical Driving Forces
The Effect of Concentration on EMF
Formation Cells
Concentration Cells
The Temperature Coefficient of the EMF
Heat Effects
The Thermodynamics of Aqueous Solutions
The Gibbs Free Energy of Formation of Ions and Standard Reduction Potentials
Pourbaix Diagrams
Summary
Numerical Examples
Problems
Appendices
Selected Thermodynamic and Thermochemical Data
Exact Differential Equations
The Generation of Auxiliary Functions as Legendre Transformations
Nomenclature
Answers
Index
×
Free shipping on orders over $35*

*A minimum purchase of $35 is required. Shipping is provided via FedEx SmartPost® and FedEx Express Saver®. Average delivery time is 1 – 5 business days, but is not guaranteed in that timeframe. Also allow 1 - 2 days for processing. Free shipping is eligible only in the continental United States and excludes Hawaii, Alaska and Puerto Rico. FedEx service marks used by permission."Marketplace" orders are not eligible for free or discounted shipping.

Learn more about the TextbookRush Marketplace.

×