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| Note: Each chaper concludes with Key Equations, Problems, and Suggested Reading | |
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| The Nature of Physical Chemistry and the Kinetic Theory of Gases | |
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| The Nature of Physical Chemistry | |
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| Some Concepts from Classical Mechanics | |
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| Systems, States, and Equilibrium | |
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| Thermal Equilibrium | |
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| Pressure and Boyle's Law Biography: Robert Boyle | |
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| Gay-Lussac's (Charles's) Law | |
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| The Ideal Gas Thermometer | |
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| The Equation of State for an Ideal Gas | |
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| The Kinetic-Molecular Theory of Ideal Gases | |
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| The Barometric Distribution Law | |
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| The Maxwell Distribution of Molecular Speeds and Translational Energies | |
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| Real Gases | |
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| Equations of State | |
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| The Virial Equation Appendix: Some Definite and Indefinite Integrals Often Used in Physical Chemistry | |
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| The First Law of Thermodynamics | |
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| Origins of the First Law | |
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| States and State Functions | |
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| Equilibrium States and Reversibility | |
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| Energy, Heat, and Work | |
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| Thermochemistry | |
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| Ideal Gas Relationships | |
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| Real Gases | |
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| The Second and Third Laws of Thermodynamics Biography: Rudolph Julius Emmanuel Clausius | |
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| The Carnot Cycle | |
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| Irreversible Processes | |
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| Molecular Interpretation of Entropy | |
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| The Calculation of Entropy Changes | |
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| The Third Law of Thermodynamics | |
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| Conditions for Equilibrium | |
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| The Gibbs Energy | |
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| Some Thermodynamic Relationships | |
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| The Gibbs-Helmholtz Equation | |
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| Thermodynamic Limitations to Energy Conversion | |
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| Chemical Equilibrium Biography: Jacobus Henricus van't Hoff | |
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| Chemical Equilibrium Involving Ideal Gases | |
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| Equilibrium in Nonideal Gaseous Systems | |
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| Chemical Equilibrium in Solution | |
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| Heterogeneous Equilibrium | |
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| Tests for Chemical Equilibrium | |
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| Shifts of Equilibrium at Constant Temperature | |
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| Coupling of Reactions | |
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| Temperature Dependence of Equilibrium Constants | |
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| Pressure Dependence of Equilibrium Constants | |
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| Phases and Solutions | |
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| Phase Recognition | |
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| Vaporization and Vapor Pressure | |
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| Classification of Transitions in Single-Component Systems | |
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| Ideal Solutions: Raoult's and Henry's Laws | |
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| Partial Molar Quantities | |
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| The Chemical Potential | |
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| Thermodynamics of Solutions | |
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| The Colligative Properties | |
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| Phase Equilibria | |
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| Equilibrium Between Phases | |
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| One-Component Systems | |
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| Binary Systems Involving Vapor | |
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| Condensed Binary Systems | |
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| Thermal Analysis | |
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| More Complicated Binary Systems | |
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| Crystal Solubility: The Krafft Boundary and Krafft Eutectic | |
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| Ternary Systems | |
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| Solutions of Electrolytes | |
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| Faraday's Laws of Electrolysis Biography: Michael Faraday | |
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| Molar Conductivity | |
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| Weak Electrolytes: The Arrhenius Theory Biography: Svante August Arrhenius | |
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| Strong Electrolytes | |
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| Independent Migration of Ions | |
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| Transport Numbers | |
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| Ion Conductivities | |
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| Thermodynamics of Ions | |
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| Theories of Ions in Solution | |
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| Activity Coefficients | |
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| Ionic Equilibria | |
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| Ionization of Water | |
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| The Donnan Equilibrium | |
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| Electrochemical Cells | |
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| The Daniell Cell | |
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| Standard Electrode Potentials | |
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| Thermodynamics of Electrochemical Cells | |
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| Types of Electrochemical Cells | |
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| Applications of emf Measurements | |
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| Fuel Cells | |
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| Photogalvanic Cells | |
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| Batteries, Old and New | |
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| Chemical Kinetics I. The Basic Ideas | |
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| Rates of Consumption and Formation | |
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| Rate of Reaction | |
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| Empirical Rate Equations | |
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| Analysis of Kinetic Results | |
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| Techniques for Very Fast Reactions | |
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| Molecular Kinetics | |
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| The Arrhenius Equation | |
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| Potential-Energy Surfaces | |
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| The Preexponential Factor Biography: Henry Eyring | |
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| Reactions in Solution | |
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| Reaction Dynamics | |
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| Chemical Kinetics II. Composite Mechanisms | |
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| Evidence for a Composite Mechanism | |
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| Types of Composite Reactions | |
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| Rate Equations for Composite Mechanisms | |
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| Rate Constants, Rate Coefficients, and Equilibrium Constants | |
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| Free-Radical Reactions | |
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| Photochemical Reactions | |
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| Radiation-Chemical Reactions | |
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| Explosions | |
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| Catalysis | |
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| Reactions in Solution: Some Special Features | |
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| Mechanisms of Polymerization in Macromolecules | |
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| Kinetics of Polymerization | |
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| Induction Periods, Oscillations, and Chaos | |
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| Electrochemical Dynamics | |
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| Quantum Mechanics and Atomic Structure | |
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| Electromagnetic Radiation and the Old Quantum Theory | |
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| Bohr's Atomic Theory | |
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| The Foundations of Quantum Mechanics | |
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| Schr?dinger's Wave Mechanics | |
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| Quantum-Mechanical Postulates | |
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| Quantum Mechanics of Some Simple Systems | |
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| Quantum Mechanics of Hydrogenlike Atoms | |
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| Physical Significance of the Orbital Quantum Numbers | |
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| Angular Momentum and Magnetic Moment | |
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| The Rigid Linear Rotor | |
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| Spin Quantum Numbers | |
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| Many-Electron Atoms | |
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| Approximate Methods in Quantum Mechanics | |
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| The Chemical Bond Biography: Gilbert Newton Lewis | |
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| The Hydrogen Molecular-Ion, H2+ | |
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| The Hydrogen Molecule | |
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| H?ckel Theory for More Complex Molecules | |
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| Valence-Bond Theory for More Complex Molecules | |
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| Symmetry in Chemistry | |
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| Symmetry of Molecular Orbitals Appendix: Character Tables | |
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| Foundations of Chemical Spectroscopy | |
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| Emission and Absorption Spectra | |
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| Atomic Spectra Biography: Gerhard Herzberg | |
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| Pure Rotational Spectra of Molecules | |
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| Vibrational-Rotational Spectra of Molecules | |
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| Raman Spectra | |
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| Electronic Spectra of Molecules Appendix: Symmetry Species Corresponding to Infrared and Raman Spectra | |
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| Some Modern Applications of Spectroscopy | |
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| Laser Spectroscopy | |
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| Spectral Line Widths | |
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| Types of Lasers | |
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| Laser Techniques for Chemistry | |
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| Magnetic Spectroscopy | |
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| Nuclear Magnetic Spectroscopy | |
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| Electron Magnetic Resonance (EMR) | |
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| M?ssbauer Spectroscopy | |
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| Photoelectron Spectroscopy | |
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| Photoacoustic Spectroscopy | |
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| Chiroptical Methods | |
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| Mass Spectrometry | |
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| Statistical Mechanics | |
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| Forms of Molecular Energy Biography: Ludwig Boltzmann | |
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| Principles of Statistical Mechanics | |
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| The Partition Function | |
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| Thermodynamic Quantities from Partition Functions | |
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| The Partition Function for Some Special Cases | |
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| The Internal Energy, Enthalpy, and Gibbs Energy Functions | |
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| The Calculation of Equilibrium Constants | |
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| Transition-State Theory | |
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| The Approach to Equilibrium | |
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| The Canonical Ensemble | |
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| The Solid State | |
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| Crystal Forms and Crystal Lattices | |
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| X-Ray Crystallography | |
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| Experimental Methods Biography: Dorothy Crowfoot Hodgkin | |
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| Theories of Solids | |
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| Statistical Thermodynamics of Crystals: Theories of Heat Capacities | |
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| Electrical Conductivity in Solids | |
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| Optical Properties of Solids | |
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| The Liquid State | |
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| Liquids Compared with Dense Gases | |
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| Liquids Compared with Solids | |
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| Intermolecular Forces | |
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| Theories and Models of Liquids | |
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| Water, the Incomparable Liquid | |
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| The Hydrophobic Effect | |
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| Surface Chemistry and Colloids | |
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| Adsorption | |
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| Adsorption Isotherms | |
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| Thermodynamics and Statistical Mechanics of Adsorption | |
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| Chemical Reactions on Surfaces | |
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| Surface Heterogeneity | |
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| The Structure of Solid Surfaces and of Adsorbed Layers | |
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| Surface Tension and Capillarity | |
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| Liquid Films on Surfaces Biography: Agnes Pockels | |
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| Colloidal Systems | |
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| Transport Properties | |
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| Viscosity | |
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| Diffusion | |
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| Sedimentation | |
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| Units, Quantities, and Symbols: The SI/IUPAC Recommendations | |
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| Physical Constants | |
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| Some Mathematical Relationships | |
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| Standard Enthalpies, Entropies, and Gibbs Energies of Formation | |
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| Character Tables for Some Important Symmetry Groups in Chemistry Answers to Problems | |
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| Index | |