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General Chemistry | |
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Basic Concepts About Matter | |
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Chemistry: The Study of Matter | |
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Physical States of Matter | |
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Properties of Matter | |
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Changes in Matter | |
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Chemistry At A Glance: Use of the Terms Physical and Chemical | |
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Pure Substances and Mixtures | |
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Elements and Compounds | |
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Chemistry At A Glance: Classes of Matter | |
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Discovery and Abundance of the Elements | |
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Names and Chemical Symbols of the Elements | |
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Atoms and Molecules | |
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Chemical Formulas | |
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Chemical Connections: "Good" Versus "Bad" Properties for a Chemical Substance Elemental Composition of the Human Body | |
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Measurements in Chemistry | |
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Measurement Systems | |
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Metric System Units | |
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Exact and Inexact Numbers | |
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Uncertainty in Measurement and Significant Figures | |
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Chemistry At A Glance: Significant Figures | |
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Significant Figures and Mathematical Operations | |
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Scientific Notation | |
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Conversion Factors | |
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Dimensional Analysis | |
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Chemistry At A Glance: Conversion Factors | |
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Density | |
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Temperature Scales | |
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Heat Energy and Specific Heat | |
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Chemical Connections | |
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Body Density and Percent Body Fat | |
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Normal Human Body Temperature | |
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Atomic Structure and the Periodic Table | |
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Internal Structure of an Atom | |
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Atomic Number and Mass Number | |
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Isotopes and Atomic Masses | |
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Chemistry At A Glance: Atomic Structure | |
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The Periodic Law and the Periodic Table | |
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Metals and Nonmetals | |
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Electron Arrangements Within Atoms | |
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Chemistry At A Glance: Shell-Subshell-Orbital Interrelationships | |
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Electron Configurations and Orbital Diagrams | |
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The Electronic Basis for the Periodic Law and the Periodic Table | |
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Classification of the Elements | |
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Chemistry At A Glance: Element Classification Schemes and the Periodic Table | |
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Chemical Connections: Protium, Deuterium, and Tritium | |
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The Three Isotopes of Hydrogen | |
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Metallic Elements and the Human Body | |
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Iron: The Most Abundant Transition Element in the Human Body | |
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Chemical Bonding: The Ionic Bond Model | |
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Chemical Bonds | |
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Valence Electrons and Lewis Symbols | |
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The Octet Rule | |
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The Ionic Bond Model | |
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The Sign and Magnitude of Ionic Charge | |
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Lewis Structures for Ionic Compounds | |
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Chemical Formulas for Ionic Compounds | |
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The Structure of Ionic Compounds | |
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Recognizing and Naming Binary Ionic Compounds | |
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Chemistry At A Glance: Ionic Bonds and Ionic Compounds | |
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Polyatomic Ions Chemical Formulas and Names for Ionic Compounds Containing Polyatomic Ions | |
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Chemistry At A Glance: Nomenclature of Ionic Compounds | |
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Chemical Connections | |
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Fresh Water, Seawater, Hard Water, and Soft Water: A Matter of Ions | |
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Tooth Enamel: A Combination of Monatomic and Polyatomic Ions | |
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Chemical Bonding: The Covalent Bond Model | |
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The Covalent Bond Model | |
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Lewis Structures for Molecular Compounds | |
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Single, Double, and Triple Covalent Bonds | |
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Valence Electrons and Number of Covalent Bonds Formed | |
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Coordinate Covalent Bonds | |
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Systematic Procedures for Drawing Lewis Structures | |
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Bonding in Compounds with Polyatomic Ions Present | |
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Molecular Geometry | |
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Chemistry At A Glance: The Geometry of Molecules | |
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Electronegativity | |
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Bond Polarity | |
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Molecular Polarity | |
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Chemistry At A Glance: Covalent Bonds and Molecular Compounds | |
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Naming Binary Molecular Compounds | |
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Chemical Connections: Nitric Oxide | |
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A Molecule Whose Bonding Does Not Follow "The Rules" | |
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The Chemical Senses of Smell and Taste | |
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Chemical Calculations: Formula Masses, Moles, and Chemical Equations | |
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Formula Masses | |
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The Mole: A Counting Unit for Chemists | |
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The Mass of a Mole | |
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Chemical Formulas and the Mole Concept | |
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The Mole and Chemical Calculations | |
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Writing and Balancing Chemical Equations | |
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Chemical Equations and the Mole Concept | |
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Chemistry At A Glance: Relationships Involving the Mole Concept | |
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Chemical Calculations Using Chemical Equations | |
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Chemical Connections: Carbon Monoxide Air Pollution: A Case of Combining Ratios Chemical Reactions on an Industrial Scale: Sulfuric Acid | |
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Gases, Liquids, and Solids | |
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The Kinetic Molecular Theory of Matter | |
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Kinetic Molecular Theory and Physical States | |
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Gas Law Variables | |
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Boyle's Law: A Pressure-Volume Relationship | |
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Charles's Law: A Temperature-Volume Relationship | |
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The Combined Gas Law | |
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The Ideal Gas Law | |
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Dalton's Law of Partial Pressures | |
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Chemistry At A Glance: The Gas Laws | |
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Changes of State | |
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Evaporation of Liquids | |
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Vapor Pressure of Liquids | |
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Boiling and Boiling Point | |
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Intermolecular Forces in Liquids | |
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Chemistry At A Glance: Intermolecular Forces | |
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Chemical Connections | |
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The Importance of Gas Densities | |
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Blood Pressure and the Sodium Ion/Potassium Ion Ratio | |
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Hydrogen Bonding and the Density of Water | |
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Solutions | |
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Characteristics of Solutions | |
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Solubility | |
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Solution Formation | |
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Solubility Rules | |
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Solution Concentration Units | |
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Dilution | |
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Chemistry At A Glance: Solutions | |
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Colloidal Dispersions and Suspensions | |
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Colligative Properties of Solutions | |
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Osmosis and Osmotic Pressure | |
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Chemistry At A Glance: Summary of Colligative Property Terminology | |
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Dialysis | |
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Chemical Connections | |
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Factors Affecting Gas Solubility | |
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Solubility of Vitamins | |
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Controlled-Release Drugs: Regulating Concentration, Rate, and Location of Release | |
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The Artificial Kidney: A Hemodialysis Machine | |
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Chemical Reactions | |
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Types of Chemical Reactions | |
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Redox and Nonredox Chemical Reactions | |
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Chemistry At A Glance: Types of Chemical Reactions | |
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Terminology Associated with Redox Processes | |
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Collision Theory and Chemical Reactions | |
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Exothermic and Endothermic Chemical Reactions | |
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Factors That Influence Chemical Reaction Rates | |
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Chemical Equilibrium | |
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Chemistry At A Glance: Factors That Increase Reaction Rates | |
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Equilibrium Constants | |
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Altering Equilibrium Conditions: Le Ch?telier's Principle | |
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Chemical Connections: Combustion Reactions, Carbon Dioxide, and Global Warming | |
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"Undesirable" Oxidation-Reduction Processes | |
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Metallic Corrosion | |
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Stratospheric Ozone: An Equilibrium Situation | |
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Acids, Bases, and Salts | |
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Arrhenius Acid-Base Theory | |
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Br?nsted-Lowry Acid-Base Theory | |
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Mono-, Di-, and Triprotic Acids | |
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Chemistry At A Glance: Acid-Base Definitions | |
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Strengths of Acids and Bases | |
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Ionization Constants for Acids and Bases | |
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Salts | |
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Acid-Base Neutralization Chemical Reactions | |
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Self-Ionization of Water | |
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The pH Concept | |
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The pKa Method for Expressing Acid Strength | |
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The pH of Aqueous Salt Solutions | |
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Chemistry At A Glance: Acids and Acidic Solutions | |
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Buffers | |
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The Henderson-Hasselbalch Equation | |
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Chemistry At A Glance: Buffer Systems | |
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Electrolytes | |
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Equivalents and Milliequivalents of Electrolytes | |
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Acid-Base Titrations | |
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Chemical Connections: Excessive Acidity Within the Stomach | |
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Antacids and Acid Inhibitors | |
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Acid Rain: Excess Acidity | |
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Blood Plasma pH and Hydrolysis | |
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Buffering Action in Human Blood | |
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Electrolytes and Body Fluids | |
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Nuclear Chemistry | |
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Stable and Unstable Nuclides | |
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The Nature of Radioactive Emissions | |
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Equations for Radioactive Decay | |
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Rate of Radioactive Decay | |
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Chemistry At A Glance: Radioactive Decay | |
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Transmutation and Bombardment Reactions | |
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Radioactive Decay Series | |
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Chemical Effects of Radiation | |
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Biochemical Effects of Radiation | |
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Detection of Radiation | |
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Sources of Radiation Exposure | |
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Nuclear Medicine | |
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Nuclear Fission and Nuclear Fusion | |
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Chemistry At A Glance: Characteristics of Nuclear Reactions | |
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Nuclear and Chemical Reactions Compared | |
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Chemical Connections | |
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Tobacco Radioactivity and the Uranium-238 Decay Series | |
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Preserving Food Through Food Irradiation | |
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The Indoor Radon-222 Problem | |
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Organic Chemistry | |
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Saturated Hydrocarbons | |
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Organic and Inorganic Compounds | |
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Bonding Characteristics of the Carbon Atom | |
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Hydrocarbons and Hydrocarbon Derivatives | |
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Alkanes: Acyclic Saturated Hydrocarbons | |
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Structural Formulas | |
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Alkane Isomerism | |
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Conformations of Alkanes | |
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IUPAC Nomenclature for Alkanes | |
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Line-Angle Structural Formulas for Alkanes | |
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Chemistry At A Glance: Structural Representations for Alkane Molecules | |
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Classification of Carbon Atoms | |
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Branched-Chain Alkyl Groups | |
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Cycloalkanes | |
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IUPAC Nomenclature for Cycloalkanes | |
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Isomerism in Cycloalkanes | |
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Sources of Alkanes and Cycloalkanes | |
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Physical Properties of Alkanes and Cycloalkanes | |
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Chemical Properties of Alkanes and Cycloalkanes | |
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Chemistry At A Glance: Properties of Alkanes and Cycloalkanes | |
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Nomenclature and Properties of Halogenated Alkanes | |
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Chemical Connections | |
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The Occurrence of Methane | |
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The Physiological Effects of Alkanes | |
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Chlorofluorocarbons and the Ozone Layer | |
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Unsaturated Hydrocarbons | |
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Unsaturated Hydrocarbons | |
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Characteristics of Alkenes and Cycloalkenes | |
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IUPAC Nomenclature for Alkenes and Cycloalkenes | |
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Line-Angle Structural Formulas for Alkenes | |
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Constitutional Isomerism in Alkenes | |
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Cis-Trans Isomerism in Alkenes | |
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Naturally Occurring Alkenes | |
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Physical Properties of Alkenes and Cycloalkenes | |
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Chemical Reactions of Alkenes | |
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Polymerization of Alkenes: Addition Polymers | |
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Alkynes | |
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Chemistry At A Glance: Chemical Reactions of Alkenes 383 | |
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Chemistry At A Glance: IUPAC Nomenclature for Alkanes, Alkenes, and Alkynes | |
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Aromatic Hydrocarbons | |
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Names for Aromatic Hydrocarbons | |
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Aromatic Hydrocarbons: Physical Properties and Sources | |
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Chemical Reactions of Aromatic Hydrocarbons | |
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Fused-Ring Aromatic Hydrocarbons | |
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Chemical Connections: Ethene | |
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A Plant Hormone and High-Volume Industrial Chemical | |
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Cis-Trans Isomerism and Vision | |
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Carotenoids: A Source of Color | |
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Fused-Ring Aromatic Hydrocarbons and Cancer | |
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Alcohols, Phenols, and Ethers | |
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Bonding Characteristics of Oxygen Atoms in Organic Compounds | |
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Structural Characteristics of Alcohols | |
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Nomenclature for Alcohols | |
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Isomerism for Alcohols | |
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Important Commonly Encountered Alcohols | |
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Physical Properties of Alcohols | |
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Preparation of Alcohols | |
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Classification of Alcohols | |
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Chemical Reactions of Alcohols | |
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Chemistry At A Glance: Summary of Chemical Reactions Involving Alcohols | |
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Polymeric Alcohols | |
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Structural Characteristics of Phenols | |
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Nomenclature for Phenols | |
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Physical and Chemical Properties of Phenols | |
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Occurrence of and Uses for Phenols | |
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Structural Characteristics of Ethers | |
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Nomenclature for Ethers | |
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Isomerism for Ethers | |
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Physical and Chemical Properties of Ethers | |
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Cyclic Ethers | |
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Sulfur Analogs of Alcohols | |
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Sulfur Analogs of Ethers | |
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Chemical Connections: Menthol | |
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A Useful Naturally Occurring Terpene Alcohol | |
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Ethers as General Anesthetics | |
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Marijuana: The Most Commonly Used Illicit Drug | |
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Garlic and Onions: Odiferous Medicinal Plants | |
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Chemistry At A Glance: Alcohols, Thiols, Ethers, and Thioethers | |
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Aldehydes and Ketones | |
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The Carbonyl Group | |
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Compounds Containing a Carbonyl Group | |
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The Aldehyde and Ketone Functional Groups | |
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Nomenclature for Aldehydes | |
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Nomenclature for Ketones | |
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Isomerism for Aldehydes and Ketones | |
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Selected Common Aldehydes and Ketones | |
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Physical Properties of Aldehydes and Ketones | |
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Preparation of Aldehydes and Ketones | |
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Oxidation and Reduction of Aldehydes and Ketones | |
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Reaction of Aldehydes and Ketones with Alcohols | |
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Chemistry At A Glance: Summary of Chemical Reactions Involving Aldehydes and Ketones | |
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Formaldehyde-Based Polymers | |
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Sulfur-Containing Carbonyl Groups | |
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Chemical Connections | |
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Lachrymatory Aldehydes and Ketones | |
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Melanin: A Hair and Skin Pigment | |
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Diabetes, Aldehyde Oxidation, and Glucose Testing | |
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Carboxylic Acids, Esters, and Other Acid Derivatives | |
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Structure of Carboxylic Acids and Their Derivatives | |
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IUPAC Nomenclature for Carboxylic Acids | |
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Common Names for Carboxylic Acids | |
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Polyfunctional Carboxylic Acids | |
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Metabolic Acids | |
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Physical Properties of Carboxylic Acids | |
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Preparation of Carboxylic Acids | |
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Acidity of Carboxylic Acids | |
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Carboxylic Acid Salts | |
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Structure of Esters | |
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Preparation of Esters | |
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Chemistry At A Glance: Summary of the "H Versus R" Relationship for Pairs of Hydrocarbon Derivatives | |
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Nomenclature for Esters | |
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Selected Common Esters | |
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Isomerism for Carboxylic Acids and Esters | |
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Physical Properties of Esters | |
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Chemical Reactions of Esters | |
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Sulfur Analogs of Esters | |
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Chemistry At A Glance: Summary of Chemical Reactions Involving Carboxylic Acids and Esters | |
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Polyesters | |
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Acid Chlorides and Acid Anhydrides | |
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Esters and Anhydrides of Inorganic Acids | |
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Chemical Connections | |
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Nonprescription Pain Relievers Derived from Propanoic Acid Carboxylic Acids and Skin Care | |
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Aspirin | |
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Nitroglycerin: An Inorganic Triester | |
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Amines and Amides | |
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Bonding Characteristics of Nitrogen Atoms in Organic Compounds | |
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Structure and Classifi cation of Amines | |
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Nomenclature for Amines | |
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Isomerism for Amines | |
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Physical Properties of Amines | |
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Basicity of Amines | |
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Amine Salts | |
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Preparation of Amines and Quaternary Ammonium Salts | |
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Heterocyclic Amines | |
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Selected Biochemically Important Amines | |
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Alkaloids | |
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Structure and Classification of Amides | |
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Nomenclature for Amides | |
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Selected Amides and Their Uses | |
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Physical Properties of Amides | |
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Preparation of Amides | |
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Hydrolysis of Amides | |
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Polyamides and Polyurethanes | |
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Chemistry At A Glance: Summary of Chemical Reactions Involving Amines and Amides | |
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Chemical Connections | |
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Caffeine: The Most Widely Used Central Nervous System Stimulant | |
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Nicotine Addiction: A Widespread Example of Drug Dependence | |
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Alkaloids Present in Chocolate | |
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Acetaminophen: A Substituted Amide | |
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Biological Chemistry | |
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Carbohydrates | |
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Biochemistry--An Overview | |
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Occurrence and Functions of Carbohydrates | |
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Classifi cation of Carbohydrates | |
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Chirality: Handedness in Molecules | |
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Stereoisomerism: Enantiomers and Diastereomers | |
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Designating Handedness Using Fischer Projection Formulas | |
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Chemistry At A Glance: Constitutional Isomers and Stereoisomers | |
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Properties of Enantiomers | |
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Classifi cation of Monosaccharides | |
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Biochemically Important Monosaccharides | |
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Cyclic Forms of Monosaccharides | |
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Haworth Projection Formulas | |
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Reactions of Monosaccharides | |
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Disaccharides | |
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Chemistry At A Glance: "Sugar Terminology" Associated with Monosaccharides and Their Derivatives | |
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General Characteristics of Polysaccharides | |
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Storage Polysaccharides | |
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Structural Polysaccharides | |
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Chemistry At A Glance: Types of Glycosidic Linkages for Common Glucose-Containing Diand Polysaccharides | |
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Acidic Polysaccharides | |
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Glycolipids and Glycoproteins: Cell Recognition | |
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Dietary Considerations and Carbohydrates | |
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Chemical Connections | |
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Blood Types and Monosaccharides | |
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Lactose Intolerance and Galactosemia | |
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Changing Sugar Patterns: Decreased Sucrose, Increased Fructose | |
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Artificial Sweeteners; "Good and Bad Carbs": The Glycemic Index | |
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Lipids | |
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Structure and Classification of Lipids | |
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Types of Fatty Acids | |
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Physical Properties of Fatty Acids | |
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Energy-Storage Lipids: Triacylglycerols | |
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Dietary Considerations and Triacylglycerols | |
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Chemical Reactions of Triacylglycerols | |
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Chemistry At A Glance: Classification Schemes for Fatty Acid Residues Present in Triacylglycerols | |
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Membrane Lipids: Phospholipids | |
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Membrane Lipids: Sphingoglycolipids | |
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Chemistry At A Glance: Terminology for and Structural Relationships Among Various Types of Fatty-Acid-Containing Lipids | |
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Membrane Lipids: Cholesterol | |
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Cell Membranes | |
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Emulsification Lipids: Bile Acids | |
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Messenger Lipids: Steroid Hormones | |
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Messenger Lipids: Eicosanoids | |
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Protective-Coating Lipids: Biological Waxes | |
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Chemistry At A Glance: Types of Lipids in Terms of How They Function | |
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Chemical Connections | |
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The Fat Content of Tree Nuts and Peanuts | |
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Artificial Fat Substitutes | |
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The Cleansing Action of Soap | |
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Trans Fatty Acids and Blood Cholesterol Levels | |
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Steroid Drugs in Sports | |
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The Mode of Action for Anti-Inflammatory Drugs | |
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Proteins | |
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Characteristics of Proteins | |
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Amino Acids: The Building Blocks for Proteins | |
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Chirality and Amino Acids | |
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Acid-Base Properties of Amino Acids | |
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Cysteine: A Chemically Unique Amino Acid | |
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Peptides | |
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Biochemically Important Small Peptides | |
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General Structural Characteristics of Proteins | |
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Primary Structure of Proteins | |
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Secondary Structure of Proteins | |
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Tertiary Structure of Proteins | |
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Quaternary Structure of Proteins | |
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Protein Classification Based on Shape | |
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Protein Classification Based on Function | |
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Chemistry At A Glance: Protein Structure | |
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Protein Hydrolysis | |
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Protein Denaturation | |
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Glycoproteins | |
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Lipoproteins | |
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Chemical Connections | |
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The Essential Amino Acids | |
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Substitutes for Human Insulin Protein Structure and the Color of Meat | |
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Denaturation and Human Hair | |
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Cyclosporine: An Antirejection Drug | |
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Lipoproteins and Heart Disease Risk | |
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Enzymes and Vitamins | |
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General Characteristics of Enzymes | |
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Enzyme Structure | |
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Nomenclature and Classifi cation of Enzymes | |
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Models of Enzyme Action | |
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Enzyme Specificity | |
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Factors That Affect Enzyme Activity | |
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Chemistry At A Glance: Enzyme Activity | |
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Enzyme Inhibition | |
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Chemistry At A Glance: Enzyme Inhibition | |
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Regulation of Enzyme Activity | |
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Antibiotics That Inhibit Enzyme Activity | |
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Medical Uses of Enzymes | |
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General Characteristics of Vitamins | |
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Water-Soluble Vitamins | |
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Fat-Soluble Vitamins | |
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Chemical Connections | |
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H. pylori and Stomach Ulcers | |
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Enzymatic Browning: Discoloration of Fruits and Vegetables | |
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Heart Attacks and Enzyme Analysis | |
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Nucleic Acids | |
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Types of Nucleic Acids | |
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Nucleotides: Building Blocks of Nucleic Acids | |
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Primary Nucleic Acid Structure | |
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Chemistry At A Glance: Nucleic Acid Structure | |
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The DNA Double Helix | |
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Replication of DNA Molecules | |
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Overview of Protein Synthesis | |
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Ribonucleic Acids | |
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Chemistry At A Glance: DNA Replication | |
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Transcription: RNA Synthesis | |
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The Genetic Code | |
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Anticodons and tRNA Molecules | |
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Translation: Protein Synthesis | |
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Mutations | |
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Nucleic Acids and Viruses | |
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Chemistry At A Glance: Protein Synthesis: Transcription and Translation | |
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Recombinant DNA and Genetic Engineering | |
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The Polymerase Chain Reaction | |
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DNA Sequencing | |
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Chemical Connections | |
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Use of Synthetic Nucleic Acid Bases in Medicine | |
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Antibiotics That Inhibit Bacterial Protein Synthesis | |
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Biochemical Energy Production | |
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Metabolism | |
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Metabolism and Cell Structure | |
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Important Intermediate Compounds in Metabolic Pathways | |
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High-Energy Phosphate Compounds | |
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An Overview of Biochemical Energy Production | |
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The Citric Acid Cycle | |
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Chemistry At A Glance: Simplified Summary of the Four Stages of Biochemical Energy Production | |
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Chemistry At A Glance: Summary of the Reactions of the Citric Acid Cycle | |
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The Electron Transport Chain | |
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Chemistry At A Glance: Summary of the Flow of Electrons Through the Four Complexes of the Electron Transport Chain | |
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Oxidative Phosphorylation | |
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Chemistry At A Glance: Summary of the Common Metabolic Pathway | |
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ATP Production for the Common Metabolic Pathway | |
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The Importance of ATP | |
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Non-ETC Oxygen-Consuming Reactions | |
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Chemical Connections | |
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Cyanide Poisoning | |
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Brown Fat, Newborn Babies, and Hibernating Animals | |
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Flavonoids: An Important Class of Dietary Antioxidants | |
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Carbohydrate Metabolism | |
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Digestion and Absorption of Carbohydrates | |
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Glycolysis | |
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Fates of Pyruvate | |
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ATP Production for the Complete Oxidation of Glucose | |
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Glycogen Synthesis and Degradation | |
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Gluconeogenesis | |
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Terminology for Glucose Metabolic Pathways | |
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The Pentose Phosphate Pathway | |
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Chemistry At A Glance: Glucose Metabolism | |
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Hormonal Control of Carbohydrate Metabolism | |
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Chemical Connections | |
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Lactate Accumulation | |
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Diabetes Mellitus | |
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Lipid Metabolism | |
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Digestion and Absorption of Lipids | |
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| |
Triacylglycerol Storage and Mobilization | |
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| |
Glycerol Metabolism | |
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| |
Oxidation of Fatty Acids | |
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| |
ATP Production from Fatty Acid Oxidation | |
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Ketone Bodies | |
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Biosynthesis of Fatty Acids: Lipogenesis | |
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Relationships Between Lipogenesis and Citric Acid Cycle Intermediates | |
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Biosynthesis of Cholesterol | |
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Chemistry At A Glance: Interrelationships Between Carbohydrate and Lipid Metabolism | |
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Relationships Between Lipid and Carbohydrate Metabolism | |
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| |
Chemical Connections | |
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| |
High-Intensity Versus Low-Intensity Workouts | |
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| |
Statins: Drugs That Lower Plasma Levels of Cholesterol | |
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| |
| |
Protein Metabolism | |
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| |
Protein Digestion and Absorption | |
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| |
Amino Acid Utilization | |
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| |
Transamination and Oxidative Deamination | |
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| |
The Urea Cycle | |
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| |
Amino Acid Carbon Skeletons | |
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| |
Amino Acid Biosynthesis | |
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| |
Hemoglobin Catabolism | |
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| |
Chemistry At A Glance: Interrelationships Among Carbohydrate, Lipid, and Protein Metabolism | |
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| |
Interrelationships Among Metabolic Pathways | |
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| |
Chemical Connections: The Chemical Composition of Urine Arginine, Citrulline, and the Chemical Messenger Nitric Oxide | |
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Answers to Selected Exercises A-1 | |