Green Organic Chemistry Strategies, Tools, and Laboratory Experiments

ISBN-10: 0534388515

ISBN-13: 9780534388515

Edition: 2004

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Description: Developing the green organic program at the University of Oregon, Kenneth Doxsee and James Hutchison saw the urgent need and rapidly growing demand for green chemistry laboratory materials. This lab text describes the tools and strategies of green chemistry, and the lab experiments that allow investigation of organic chemistry concepts and techniques in a greener laboratory setting. GREEN ORGANIC CHEMISTRY: STRATEGIES, TOOLS AND LABORATORY EXPERIMENTS was developed and successfully tested as a direct replacement of the traditional organic chemistry laboratory curriculum. Thus, the conceptual themes and experimental techniques important to the modern practice of organic chemistry can be taught in the context of more environmentally-benign laboratory experiments. Students acquire the tools to assess the health and environmental impacts of chemical processes and the strategies to improve develop new processes that are less harmful to human health and the environment. The curriculum introduces a number of state-of-the-art experiments and reduces reliance on expensive environmental controls, such as fume hoods.

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Book details

List price: $119.95
Copyright year: 2004
Publisher: Brooks/Cole
Publication date: 5/7/2003
Binding: Hardcover
Pages: 256
Size: 8.25" wide x 10.50" long x 0.75" tall
Weight: 1.540
Language: English

Graphical Abstracts for the Experiments
Strategies and Tools
Introduction
Identification and Evaluation of Chemical Hazards
Chemical Exposure and Environmental Contamination
Sources of Information about Chemical Hazards
Introduction to Green Chemistry
Alternative Solvents
Alternative Reagents
Reaction Design and Efficiency
Alternative Feedstocks and Products
The Big Picture and Green Chemistry Metrics
Laboratory Experiments
Preface to the Experimental Section
Solventless Reactions: The Aldol Reaction
Bromination of An Alkene: Preparation of Stilbene Dibromide
A Greener Bromination of Stilbene
Preparation and Distillation of Cyclohexene
Synthesis and Recrystallization of Adipic Acid
Oxidative Coupling of Alkynes: The Glaser-Eglinton-Hay Coupling
Gas-Phase Synthesis, Column Chromatography and Visible Spectroscopy of 5,10,15,20-Tetraphenylporphyrin
Microwave Synthesis of 5,10,15,20-Tetraphenylporphyrin
Metallation of 5,10,15,20-Tetraphenylporphyrin
Measuring Solvent Effects: Kinetics of Hydrolysis of tert-Butyl Chloride
Molecular Mechanics Modeling
Electrophilic Aromatic Iodination
Palladium-Catalyzed Alkyne Coupling/Intramolecular Alkyne Addition: Natural Product Synthesis
Resin-Based Oxidation Chemistry
Carbonyl Chemistry: Thiamine-Mediated Benzoin Condensation of Furfural
Solid-Phase Photochemistry
Applications of Organic Chemistry: Patterning Surfaces With Molecular Films
The Friedel-Crafts Reaction: Acetylation of Ferrocene
Combinatorial Chemistry: Antibiotic Drug Discovery
The Twelve Principles of Green Chemistry
Index
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