Organic Chemistry II Second Semester Topics

Name: Organic Chemistry II Second Semester Topics
Price: 3.87 USD
Availability: InStock
ISBN: 9780471738084

ISBN-10: 0471738085

ISBN-13: 9780471738084

Edition: 2nd 2006

Authors: David R. Klein

List price: $50.95

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Description:

Building on the resounding success of the first volume (0-471-27235-3), "Organic Chemistry as a Second Language, Volume 2 provides readers with clear, easy-to-understand explanations of fundamental principles. It explores the critical concepts while also examining why they are relevant. The core content is presented within the framework of predicting products, proposing mechanisms, and solving synthesis problems. Readers will fine-tune the key skills involved in solving those types of problems with the help of interactive, step-by-step instructions and problems.

Book details

List price: $50.95
Edition: 2nd
Copyright year: 2006
Publisher: John Wiley & Sons, Incorporated
Publication date: 10/7/2005
Binding: Paperback
Pages: 320
Size: 6.00" wide x 9.00" long x 0.50" tall
Weight: 0.880
Language: English




The Skills You Need



The Goal of This book



Mechanisms Are Your Keys to Success



Intro to Ionic Mechanisms



Curved Arrows



The Basic Moves



Combining the Basic Moves



Electrophilic Aromatic Substitution



Halogenation and the role of Lewis Acids



Nitration



Friedel-Crafts Alkylation and Acylation



Sulfonation



Modifying the Nucleophilicity of the Nucleophile



Predicting Directing Effects



Identifying Activators and Deactivators



Predicting and Exploiting Steric Effects



Synthesis Strategies



Nucleophilic Aromatic Substitution



Criteria for Nucleophilic Aromatic Substitution



S[subscript N]Ar Mechanism



Elimination-Addition



Mechanism Strategies



Ketones and Aldehydes



Preparation of Ketones and Aldehydes



Stability and Reactivity of the Carbonyl



H-Nucleophiles



O-Nucleophiles



S-Nucleophiles



N-Nucleophiles



C-Nucleophiles



Some Important Exceptions to the Rule



How to Approach Synthesis Problems



Carboxylic Acid Derivatives



General Rules



Acyl Halides



Anhydrides



Esters



Amides and Nitriles



Synthesis Problems



Enols and Enolates



Keto-Enol Tautomerism



Reactions Involving Enols



Making Enolates



Haloform Reactions



Alkylation of Enolates



Aldol Reaction and Aldol Condensation



Claisen Condensation



Decarboxylation Provides Some Useful Synthetic Techniques



Michael Reactions



Amines



Nucleophilicity and Basicity of Amines and Amides



Preparation of Amines through S[subscript N]2 Reactions



Preparation of Amines through Reductive Amination



Preparation of Amines from Amides



Acylation of Amines



Reactions of Amines with Nitrous Acid



Aromatic Diazonium Salts


Answer Key


Index