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| Preface | |
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| Acknowledgement | |
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| Note from the chairman of the NEA TDB Project Phase II | |
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| Editor's note | |
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| Introductory material | |
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| Introduction | |
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| Background | |
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| Focus of the review | |
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| Review procedure and results | |
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| Standards, Conventions, and Contents of the Tables | |
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| Symbols, terminology and nomenclature | |
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| Abbreviations | |
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| Symbols and terminology | |
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| Chemical formulae and nomenclature | |
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| Phase designators | |
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| Processes | |
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| Equilibrium constants | |
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| Protonation of a ligand | |
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| Formation of metal ion complexes | |
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| Solubility constants | |
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| Equilibria involving the addition of a gaseous ligand | |
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| Redox equilibria | |
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| pH | |
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| Order of formulae | |
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| Reference codes | |
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| Units and conversion factors | |
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| Standard and reference conditions | |
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| Standard state | |
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| Standard state pressure | |
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| Reference temperature | |
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| Fundamental physical constants | |
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| Uncertainty estimates | |
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| The NEA-TDB system | |
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| Presentation of the selected data | |
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| Tables of selected data | |
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| Selected Nickel Data | |
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| Selected Auxiliary Data | |
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| Discussion of data selection | |
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| Discussion of Data Selection for Nickel | |
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| Elemental nickel | |
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| Nickel gas | |
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| Nickel crystal | |
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| Nickel liquid | |
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| Simple nickel aqua ions | |
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| Ni[superscript 2+] | |
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| Gibbs energy of formation of Ni[superscript 2+] | |
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| Temperature coefficient of the standard electrode potential Ni[superscript 2+ vertical bar]Ni | |
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| Enthalpy of formation of Ni[superscript 2+] | |
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| Partial molar entropy of Ni[superscript 2+] | |
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| NiSO[subscript 4 middle dot 7H subscript 2]O(cr) cycle | |
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| NiCl[subscript 2 middle dot 6H subscript 2]O(cr) cycle | |
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| Entropy of Ni[superscript 2+] from its [Delta subscript f]G[superscript o subscript m] and [Delta subscript f]H[superscript o subscript m] | |
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| Heat capacity of Ni[superscript 2+] | |
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| Other oxidation states | |
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| Ni[superscript 3+] | |
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| Oxygen and hydrogen compounds and complexes | |
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| Aqueous nickel(II) hydroxo complexes | |
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| Hydroxo complexes in acidic or neutral solutions | |
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| Hydroxo complexes in alkaline solutions | |
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| Solid nickel oxides and hydroxides | |
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| Ni(II) oxide | |
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| Solubility measurements | |
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| Ni(II) hydroxides, Ni(OH)[subscript 2](cr) | |
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| Crystallography and mineralogy of nickel hydroxide | |
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| [beta]-Ni(OH)[subscript 2] | |
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| [alpha]-Ni(OH)[subscript 2] | |
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| Heat capacity and entropy of Ni(OH)[subscript 2](cr) | |
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| Thermodynamic analysis of solubility data of Ni(OH)[subscript 2](s) | |
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| Ni(III, IV) hydroxides | |
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| [beta]-NiOOH | |
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| [gamma]-NiOOH | |
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| Group 17 (halogen) compounds and complexes | |
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| Nickel halide compounds | |
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| Solid nickel fluoride, NiF[subscript 2](cr) | |
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| Enthalpy of formation of NiF[subscript 2](cr) | |
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| Solid nickel chloride, NiCl[subscript 2](cr) | |
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| Low-temperature heat capacity and entropy of NiCl[subscript 2](cr) | |
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| The high-temperature heat capacity of NiCl[subscript 2](cr) | |
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| Enthalpy of formation of NiCl[subscript 2](cr) | |
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| Gibbs energy of formation of NiCl[subscript 2](cr) | |
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| Hydrated NiCl[subscript 2] solids | |
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| Gibbs energy of formation of NiCl[subscript 2 middle dot 6H subscript 2]O | |
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| Enthalpy of formation of NiCl[subscript 2 middle dot 6H subscript 2]O | |
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| The entropy and heat capacity of NiCl[subscript 2 middle dot 6H subscript 2]O(cr) | |
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| Gibbs energy and enthalpy of formation of nickel chloride tetrahydrate | |
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| The entropy and heat capacity of nickel chloride dihydrate | |
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| Gibbs energy and enthalpy of formation of nickel chloride dihydrate | |
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| Solid nickel bromide, NiBr[subscript 2](cr) | |
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| Low-temperature heat capacity and entropy of NiBr[subscript 2](cr) | |
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| The high-temperature heat capacity of NiBr[subscript 2](cr) | |
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| Enthalpy of formation of NiBr[subscript 2](cr) | |
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| Hydrated solid, NiBr[subscript 2 middle dot xH subscript 2]O | |
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| Solid nickel iodide, NiI[subscript 2](cr) | |
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| Entropy of NiI[subscript 2](cr) | |
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| Heat capacity of NiI[subscript 2](cr) | |
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| Enthalpy of formation of NiI[subscript 2](cr) | |
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| Solid nickel iodate compounds | |
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| Aqueous nickel halide complexes | |
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| Introduction | |
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| Solution structural studies | |
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| Aqueous Ni(II) - fluoro complexes | |
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| Aqueous Ni(II) - chloro complexes | |
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| Aqueous Ni(II) - bromo complexes | |
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| Determination of the Ni[superscript 2+] - Br[superscript -] ion interaction coefficient | |
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| Aqueous Ni(II) - iodine complexes | |
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| Aqueous Ni(II) - iodo complexes | |
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| Determination of the Ni[superscript 2+] - ClO[superscript - subscript 4] ion interaction coefficient | |
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| Group 16 (chalcogen) compounds and complexes | |
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| Sulphur compounds and complexes | |
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| Nickel sulphides | |
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| Solid nickel sulphides | |
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| Crystallography and mineralogy of nickel sulphides | |
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| Heazlewoodite, Ni[subscript 3]S[subscript 2](cr) | |
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| [alpha]-Ni[subscript 7]S[subscript 6] | |
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| Pentlandite, (Fe, Ni)[subscript 9]S[subscript 8](cr) | |
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| Godlevskite, Ni[subscript 9]S[subscript 8](cr) | |
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| Millerite, [beta]-NiS | |
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| Polydymite, Ni[subscript 3]S[subscript 4](cr) | |
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| Vaesite, NiS[subscript 2](cr) | |
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| Ni - S phase diagram | |
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| Ni - S melt | |
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| [beta subscript 1]-Ni[subscript 3]S[subscript 2] and [beta subscript 2]-Ni[subscript 4]S[subscript 3] | |
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| Ni[subscript 3]S[subscript 2](cr) (heazlewoodite) | |
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| Ni[subscript 7]S[subscript 6](cr) and Ni[subscript 9]S[subscript 8](cr) | |
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| NiS([alpha]) and NiS([beta]) | |
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| NiS[subscript 2](cr), vaesite | |
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| Ni[subscript 3]S[subscript 4](cr), polydymite | |
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| Ni[subscript 4.5]Fe[subscript 4.5]S[subscript 8](cr), pentlandite | |
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| Discussion of selected thermodynamic properties of nickel sulphides | |
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| Solubility of NiS(s) and aqueous nickel hydrogen sulphido species | |
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| Nickel sulphates | |
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| Aqueous nickel (II) sulphato complexes | |
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| Enthalpy of formation of NiSO[subscript 4](aq) | |
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| Heat capacity values | |
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| Solid nickel sulphates | |
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| NiSO[subscript 4 middle dot 7H subscript 2]O(cr) | |
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| [alpha]-NiSO[subscript 4 middle dot 6H subscript 2]O | |
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| Other hydrated nickel sulphate solids | |
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| NiSO[subscript 4](cr) | |
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| Selenium compounds and complexes | |
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| Tellurium compounds and complexes | |
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| Nickel tellurides | |
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| NiTe[subscript 0.775]([gamma subscript 1]) | |
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| NiTe[subscript 0.85]([gamma subscript 2]) | |
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| Group 15 compounds and complexes | |
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| Nitrogen compounds and complexes | |
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| Solid nickel nitrates | |
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| Ni(NO[subscript 3])[subscript 2] [middle dot] 9H[subscript 2]O(cr) | |
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| Ni(NO[subscript 3])[subscript 2] [middle dot] 6H[subscript 2]O(cr) | |
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| Ni(NO[subscript 3])[subscript 2] [middle dot] 4H[subscript 2]O(cr), Ni(NO[subscript 3])[subscript 2] [middle dot] 3H[subscript 2]O(cr), Ni(NO[subscript 3])[subscript 2] [middle dot] 2H[subscript 2]O(cr) | |
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| Ni(NO[subscript 3])[subscript 2](anhydrous) | |
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| Aqueous Ni(II)-nitrato complexes | |
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| Determination of the Ni[superscript 2+] - NO[superscript - subscript 3] ion interaction coefficient | |
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| Phosphorus compounds and complexes | |
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| Solid nickel phosphorus compounds | |
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| Nickel phosphides | |
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| Nickel phosphates | |
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| Aqueous nickel phosphorus species | |
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| Simple nickel phosphato complexes | |
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| Aqueous nickel diphosphato complexes | |
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| Arsenic compounds | |
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| Nickel arsenides | |
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| NiAs(cr) | |
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| Ni[subscript 11]As[subscript 8](cr) | |
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| Ni[subscript 5]As[subscript 2](cr) | |
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| NiAs[subscript 2](cr) | |
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| Nickel arsenates | |
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| Solid nickel arsenates | |
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| Aqueous nickel arsenato complexes | |
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| Nickel arsenites | |
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| Solid nickel arsenites | |
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| Group 14 compounds and complexes | |
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| Carbon compounds and complexes | |
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| Nickel carbonates | |
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| Solid nickel carbonates | |
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| NiCO[subscript 3](cr) | |
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| Crystallography and mineralogy of nickel carbonate | |
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| Heat capacity and entropy of NiCO[subscript 3](cr) | |
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| Thermodynamic analysis of solubility data on gaspeite | |
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| NiCO[subscript 3 middle dot 5.5H subscript 2]O(cr) | |
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| Crystallography and mineralogy of nickel carbonate hydrate | |
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| Heat capacity and entropy of NiCO[subscript 3 middle dot 5.5H subscript 2]O(cr) | |
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| Thermodynamic analysis of solubility data on hellyerite | |
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| Aqueous nickel carbonato complexes | |
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| Nickel cyanides | |
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| Aqueous Ni(II) cyano complexes | |
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| Complexes in neutral and alkaline solution | |
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| Protonated complexes | |
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| Nickel thiocyanates | |
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| Aqueous nickel thiocyanato complexes | |
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| Silicon compounds and complexes | |
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| Solid nickel silicates | |
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| Nickel orthosilicate Ni[subscript 2]SiO[subscript 4](cr) | |
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| Crystal structure and phase transitions | |
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| Crystallography and mineralogy of nickel orthosilicate | |
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| Heat capacity and standard entropy | |
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| Enthalpy of formation | |
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| Gibbs energy of formation | |
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| Germanium compounds and complexes | |
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| Solid nickel germanates | |
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| Nickel orthogermanate Ni[subscript 2]GeO[subscript 4](cr) | |
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| Crystal structure of nickel orthogermanate | |
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| Enthalpy of formation from NiO(cr) and GeO[subscript 2](cr) | |
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| Group 13 compounds and complexes | |
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| Boron compounds and complexes | |
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| Solid nickel borates | |
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| Crystal structure | |
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| Thermodynamic data for NiO[middle dot]2B[subscript 2]O[subscript 3](s) | |
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| Solubility of Ni(BO[subscript 2])[subscript 2] [middle dot] 4H[subscript 2]O(s) | |
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| Aqueous nickel borato complexes | |
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| Discussion of Auxiliary Data Selection | |
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| Group 15 auxiliary species | |
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| Additional consistent auxiliary data for As compounds | |
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| Other auxiliary species | |
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| Auxiliary data for KCl(cr), KBr(cr) and KI(cr) | |
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| Appendices | |
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| Discussion of selected references | |
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| Ionic strength corrections | |
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| The specific ion interaction equations | |
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| Background | |
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| Ionic strength corrections at temperatures other than 298.15 K | |
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| Estimation of ion interaction coefficients | |
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| Estimation from mean activity coefficient data | |
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| Estimations based on experimental values of equilibrium constants at different ionic strengths | |
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| On the magnitude of ion interaction coefficients | |
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| Ion interaction coefficients versus equilibrium constants for ion pairs | |
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| Tables of ion interaction coefficients | |
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| Assigned uncertainties | |
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| The general problem | |
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| Uncertainty estimates in the selected thermodynamic data | |
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| One source datum | |
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| Two or more independent source data | |
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| Discrepancies | |
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| Several data at different ionic strengths | |
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| Discrepancies or insufficient number of data points | |
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| Procedures for data handling | |
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| Correction to zero ionic strength | |
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| Propagation of errors | |
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| Rounding | |
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| Significant digits | |
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| Bibliography | |
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| List of authors | |