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| Tools of the Trade | |
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| Basic Terminology | |
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| Analysis of Rate Data | |
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| Concentration Variables and First-Order Rates | |
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| Complex Rate Laws | |
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| Complex Kinetic Systems | |
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| Temperature Dependence of Rate Constants | |
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| Pressure Dependence of Rate Constants | |
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| Ionic Strength Dependence of Rate Constants | |
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| Diffusion-Controlled Rate Constants | |
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| Rate Law and Mechanism | |
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| Qualitative Guidelines | |
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| Steady-State Approximation | |
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| Rapid Equilibrium Assumption | |
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| Rapid Equilibrium or Steady State? | |
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| Numerical Integration Methods | |
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| Principle of Detailed Balancing | |
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| Principle of Microscopic Reversibility | |
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| Ligand Substitution Reactions | |
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| Operational Approach to Classification of Substitution Mechanisms | |
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| Operational Tests for the Stoichiometric Mechanism | |
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| Examples of Tests for a Dissociative Mechanism | |
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| Operational Test for an Associative Mechanism | |
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| Operational Tests for the Intimate Mechanism | |
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| Some Special Effects | |
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| Variation of Substitution Rates with Metal Ion | |
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| Ligand Substitution on Labile Transition-Metal Ions | |
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| Kinetics of Chelate Formation | |
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| Stereochemical Change | |
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| Types of Ligand Rearrangements | |
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| Geometrical and Optical Isomerism in Octahedral Systems | |
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| Stereochemical Change in Five-Coordinate Systems | |
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| Isomerism in Square Planar Systems | |
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| Fluxional Organometallic Compounds | |
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| Reaction Mechanisms of Organometallic Systems | |
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| Ligand Substitution Reactions | |
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| Insertion Reactions | |
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| Oxidative Addition Reactions | |
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| Reactions of Alkenes | |
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| Catalytic Hydrogenation of Alkenes | |
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| Homogeneous Catalysis by Organometallic Compounds | |
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| Oxidation-Reduction Reactions | |
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| Classification of Reactions | |
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| Outer-Sphere Electron-Transfer Theory | |
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| Differentiation of Inner-Sphere and Outer-Sphere Mechanisms | |
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| Bridging Ligand Effects in Inner-Sphere Reactions | |
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| Intervalence Electron Transfer | |
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| Electron Transfer in Metalloproteins | |
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| Inorganic Photochemistry | |
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| Basic Terminology | |
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| Kinetic Factors Affecting Quantum Yields | |
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| Photochemistry of Cobalt (III) Complexes | |
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| Photochemistry of Rhodium (III) Complexes | |
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| Photochemistry of Chromium (III) Complexes | |
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| Ru(II)polypyridine Complexes | |
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| Organometallic Photochemistry | |
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| Photochemical Generation of Reaction Intermediates | |
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| Bioinorganic Systems | |
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| Vitamin B12 | |
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| A Zinc(II) Enzyme: Carbonic Anhydrase | |
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| Enzymic Reactions of Dioxygen | |
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| Enzymic Reactions of Nitric Oxide | |
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| Experimental Methods | |
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| Flow Methods | |
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| Relaxation Methods | |
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| Electrochemical Methods | |
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| Nuclear Magnetic Resonance Methods | |
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| Electron Paramagnetic Resonance Methods | |
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| Pulse Radiolysis Methods | |
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| Flash Photolysis Methods | |
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| Problems | |
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| Chemical Abbreviations | |
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| Index | |