Reaction Mechanisms of Inorganic and Organometallic Systems

ISBN-10: 0195301005
ISBN-13: 9780195301007
Edition: 3rd 2006 (Revised)
Authors: Robert B. Jordan
List price: $90.00
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Description: This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to  More...

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Book details

List price: $90.00
Edition: 3rd
Copyright year: 2006
Publisher: Oxford University Press, Incorporated
Publication date: 6/18/2007
Binding: Hardcover
Pages: 528
Size: 6.25" wide x 9.25" long x 1.10" tall
Weight: 1.848
Language: English

This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Tools of the Trade
Basic Terminology
Analysis of Rate Data
Concentration Variables and First-Order Rates
Complex Rate Laws
Complex Kinetic Systems
Temperature Dependence of Rate Constants
Pressure Dependence of Rate Constants
Ionic Strength Dependence of Rate Constants
Diffusion-Controlled Rate Constants
Rate Law and Mechanism
Qualitative Guidelines
Steady-State Approximation
Rapid Equilibrium Assumption
Rapid Equilibrium or Steady State?
Numerical Integration Methods
Principle of Detailed Balancing
Principle of Microscopic Reversibility
Ligand Substitution Reactions
Operational Approach to Classification of Substitution Mechanisms
Operational Tests for the Stoichiometric Mechanism
Examples of Tests for a Dissociative Mechanism
Operational Test for an Associative Mechanism
Operational Tests for the Intimate Mechanism
Some Special Effects
Variation of Substitution Rates with Metal Ion
Ligand Substitution on Labile Transition-Metal Ions
Kinetics of Chelate Formation
Stereochemical Change
Types of Ligand Rearrangements
Geometrical and Optical Isomerism in Octahedral Systems
Stereochemical Change in Five-Coordinate Systems
Isomerism in Square Planar Systems
Fluxional Organometallic Compounds
Reaction Mechanisms of Organometallic Systems
Ligand Substitution Reactions
Insertion Reactions
Oxidative Addition Reactions
Reactions of Alkenes
Catalytic Hydrogenation of Alkenes
Homogeneous Catalysis by Organometallic Compounds
Oxidation-Reduction Reactions
Classification of Reactions
Outer-Sphere Electron-Transfer Theory
Differentiation of Inner-Sphere and Outer-Sphere Mechanisms
Bridging Ligand Effects in Inner-Sphere Reactions
Intervalence Electron Transfer
Electron Transfer in Metalloproteins
Inorganic Photochemistry
Basic Terminology
Kinetic Factors Affecting Quantum Yields
Photochemistry of Cobalt (III) Complexes
Photochemistry of Rhodium (III) Complexes
Photochemistry of Chromium (III) Complexes
Ru(II)polypyridine Complexes
Organometallic Photochemistry
Photochemical Generation of Reaction Intermediates
Bioinorganic Systems
Vitamin B12
A Zinc(II) Enzyme: Carbonic Anhydrase
Enzymic Reactions of Dioxygen
Enzymic Reactions of Nitric Oxide
Experimental Methods
Flow Methods
Relaxation Methods
Electrochemical Methods
Nuclear Magnetic Resonance Methods
Electron Paramagnetic Resonance Methods
Pulse Radiolysis Methods
Flash Photolysis Methods
Problems
Chemical Abbreviations
Index

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