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Preface | |
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The Evolving Realm of Inorganic Chemistry | |
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Coordination Chemistry | |
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An Introduction to Coordination Chemistry | |
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The Historical Perspective | |
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The History of Coordination Compounds | |
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The Modern View of Coordination Compounds | |
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An Introduction to the Nomenclature of Coordination Compounds | |
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Structures of Coordination Compounds | |
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Stereoisomers | |
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Octahedral Coordination Spheres | |
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Square Planar Coordination Spheres | |
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Tetrahedral Coordination Spheres | |
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Other Coordination Spheres | |
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Structural Isomers | |
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Bonding Theories for Coordination Compounds | |
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Early Bonding Theories | |
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The Crystal Field Theory | |
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Consequences and Applications of Crystal Field Splitting | |
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Rates and Mechanisms of Reactions of Coordination Compounds | |
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A Brief Survey of Reaction Types | |
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Labile and Inert Coordination Compounds | |
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Substitution Reactions of Octahedral Complexes | |
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Redox or Electron Transfer Reactions | |
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Substitution Reactions in Square Planar Complexes: The Kinetic Trans Effect | |
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Applications of Coordination Compounds | |
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Applications of Monodentate Complexes | |
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Two Keys to the Stability of Transition Metal Complexes | |
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Application of Multidentate Complexes | |
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Chelating Agents as Coordination Chemistry | |
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Solid State Chemistry | |
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Solid State Structures | |
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Types of Crystals | |
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A-type Crystal Lattices | |
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ABn-type Crystal Lattices | |
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Structures Involving Polyatomic Molecules and Ions | |
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Defect Structures | |
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Spinel Structures: Connecting Crystal Field Effects with Solid State Structures | |
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Solid State Energetics | |
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Lattice Energy: A Theoretical Evaluation | |
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Lattice Energy: Thermodynamic Cycles | |
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Lattices Energies and Ionic Radii: Connecting Crystal Field Effects with Solid State Energetics | |
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Descriptive Chemistry of the Representative Elements | |
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Descriptive Chemistry of the Representative Elements | |
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Building a Network of Ideas to Make Sense of the Periodic Table | |
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The Periodic Law | |
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The Uniqueness Principle | |
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The Diagonal Effect | |
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The Inert Pair Effect | |
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Metal, Non-Metal, and Metalloid Regions | |
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Hydrogen and Hydrides | |
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The Origin of the Elements (and of Us!) | |
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The Discovery, Preparation, and Uses of Hydrogen | |
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Isotopes of Hydrogen | |
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Radioactive Processes Involving Hydrogen | |
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Hydrides and the Network | |
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The Role of Hydrogen in Various Alternative Energy Sources | |
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Oxygen, Aqueous Solutions, and the Acid Base Character of Oxides and Hydroxides | |
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Oxygen | |
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Water and Aqueous Solutions | |
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The Acid-Base Character of Oxides and Hydroxides in Aqueous Solution | |
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The Relative Strengths of Oxo- and Hydroacids in Aqueous Solution | |
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Ozone | |
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The Greenhouse Effect and Global Warming | |
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Group 1A: The Alkali Metals | |
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Discovery and Isolation of the Elements | |
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Fundamental Properties and the Network | |
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Reduction Potentials and the Network | |
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Peroxides and Superoxides | |
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Reactions and Compounds of Practical Importance | |
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Selected Topic in Depth: Metal-Ammonia Solutions | |
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Group 2A: The Alkaline Earth Metals | |
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Discover and Isolation of the Elements | |
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Fundamental Properties and the Network | |
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Reactions and Compounds of Practical Importance | |
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Selected Topic in Depth: The Commercial Uses of Calcium Compounds | |
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The Group 3A: Elements | |
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Discovery and Isolation of the Elements | |
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Fundamental Properties and the Network | |
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Structural Aspects of Boron Chemistry | |
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Aluminum, Gallium, Indium, and Thallium? | |
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Reaction and Compounds of Practical Importance | |
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Selected Topic in Depth: Electron-Deficient Compounds | |
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The Group 4A Elements | |
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Discovery and Isolation of the Elements | |
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Fundamental Properties and the Network | |
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An Eighth Component of the Interconnected Network: pi-dpi Bonding Involving Elements of the Second and Third Periods | |
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Reactions and Compounds of Practical Importance | |
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Silicates, Silica, and Aluminosilicates | |
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Selected Topics in Depth: Semiconductors and Glass | |
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Group 5A: The Pnicogens | |
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Discovery and Isolation of the Elements | |
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Fundamental Properties and the Network | |
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A Survey of Nitrogen Oxidation States | |
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Reactions and Compounds of Practical Importance | |
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Selected Topic in Depth | |