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Preface to the Second Edition | |
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Preface to the First Edition | |
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Structure of Atoms and Molecules | |
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Light, Electrons, and Nuclei | |
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Some Early Experiments in Atomic Physics | |
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The Nature of Light | |
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The Bohr Model | |
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Particle-Wave Duality | |
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Electronic Properties of Atoms | |
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Nuclear Binding Energy | |
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Nuclear Stability | |
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Types of Nuclear Decay | |
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Predicting Decay Modes | |
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Basic Quantum Mechanics and Atomic Structure | |
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The Postulates | |
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The Hydrogen Atom | |
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The Helium Atom | |
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Slater Wave Functions | |
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Electron Configurations | |
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Spectroscopic States | |
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Covalent Bonding in Diatomic Molecules | |
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The Basic Ideas of Molecular Orbital Methods | |
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The H<sub>2</sub><sup>+</sup> and H<sub>2</sub> Molecules | |
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Diatomic Molecules of Second-Row Elements | |
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Photoelectron Spectroscopy | |
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Heteronuclear Diatomic Molecules | |
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Electronegativity | |
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Spectroscopic States for Molecules | |
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A Survey of Inorganic Structures and Bonding | |
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Structures of Molecules Having Single Bonds | |
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Resonance and Formal Charge | |
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Complex Structures: A Preview of Coming Attractions | |
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Electron-Deficient Molecules | |
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Structures Having Unsaturated Rings | |
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Bond Energies | |
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Symmetry and Molecular Orbitals | |
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Symmetry Elements | |
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Orbital Symmetry | |
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A Brief Look at Group Theory | |
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Construction of Molecular Orbitals | |
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Orbitals and Angles | |
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Simple Calculations Using the H�ckel Method | |
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Condensed Phases | |
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Dipole Moments and Intermolecular Interactions | |
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Dipole Moments | |
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Dipole-Dipole Forces | |
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Dipole-Induced Dipole Forces | |
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London (Dispersion) Forces | |
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The van der Waals Equation | |
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Hydrogen Bonding | |
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Cohesion Energy and Solubility Parameters | |
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Solvatochromism | |
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Ionic Bonding and Structures of Solids | |
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Energetics of Crystal Formation | |
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Madelung Constants | |
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The Kapustinskii Equation | |
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Ionic Sizes and Crystal Environments | |
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Crystal Structures | |
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Solubility of Ionic Compounds | |
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Proton and Electron Affinities | |
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Structures of Metals | |
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Defects in Crystals | |
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Phase Transitions in Solids | |
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Heat Capacity | |
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Hardness of Solids | |
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Dynamic Processes in Inorganic Solids | |
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Characteristics of Solid-State Reactions | |
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Kinetic Models for Reactions in Solids | |
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Thermal Methods of Analysis | |
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Effects of Pressure | |
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Reactions in Some Solid Inorganic Compounds | |
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Phase Transitions | |
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Reactions at Interfaces | |
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Diffusion in Solids | |
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Sintering | |
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Drift and Conductivity | |
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Acids, Bases, and Solvents | |
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Acid-Base Chemistry | |
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Arrhenius Theory | |
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Br�nsted-Lowry Theory | |
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Factors Affecting the Strength of Acids and Bases | |
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Acid-Base Character of Oxides | |
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Proton Affinities | |
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Lewis Theory | |
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Catalytic Behavior of Acids and Bases | |
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The Hard-Soft Interaction Principle (HSIP) | |
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Electronic Polarizabilities | |
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The Drago Four-Parameter Equation | |
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Chemistry in Nonaqueous Solvents | |
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Some Common Nonaqueous Solvents | |
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The Solvent Concept | |
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Amphoteric Behavior | |
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The Coordination Model | |
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Chemistry in Liquid Ammonia | |
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Liquid Hydrogen Fluoride | |
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Liquid Sulfur Dioxide | |
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Superacids | |
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Chemistry of the Elements | |
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Chemistry of Metallic Elements | |
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The Metallic Elements | |
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Band Theory | |
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Groups IA and IIA Metals | |
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Zintl Phases | |
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Aluminum and Beryllium | |
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The First-Row Transition Metals | |
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Second- and Third-Row Transition Metals | |
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Alloys | |
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Chemistry of Transition Metals | |
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The Lanthanides | |
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Organometallic Compounds of the Main Group Elements | |
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Preparation of Organometallic Compounds | |
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Organometallic Compounds of Group IA Metals | |
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Organometallic Compounds of Group IIA Metals | |
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Organometallic Compounds of Group IIIA Metals | |
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Organometallic Compounds of Group IVA Metals | |
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Organometallic Compounds of Group VA Elements | |
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Organometallic Compounds of Zn, Cd, and Hg | |
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Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen, and Carbon | |
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Hydrogen | |
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Boron | |
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Oxygen | |
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Carbon | |
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Chemistry of Nonmetallic Elements II Groups IVA and VA | |
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The Group IVA Elements | |
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Nitrogen | |
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Phosphorus, Arsenic, Antimony, and Bismuth | |
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Chemistry of Nonmetallic Elements EL Groups VIA-VTIIA | |
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Sulfur, Selenium, and Tellurium | |
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The Halogens | |
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The Noble Gases | |
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Chemistry of Coordination Compounds | |
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Introduction to Coordination Chemistry | |
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Structures of Coordination Compounds | |
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Metal-Ligand Bonds | |
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Naming Coordination Compounds | |
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Isomerism | |
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A Simple Valence Bond Description of Coordinate Bonds | |
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Magnetism | |
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A Survey of Complexes of First-Row Metals | |
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Complexes of Second- and Third-Row Metals | |
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The 18-Electron Rule | |
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Back Donation | |
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Complexes of Dinitrogen, Dioxygen, and Dihydrogen | |
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Ligand Fields and Molecular Orbitals | |
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Splitting of d Orbital Energies in Octahedral Fields | |
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Splitting of d Orbital Energies in Fields of Other Symmetry | |
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Factors Affecting � | |
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Consequences of Crystal Field Splitting | |
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Jahn-Teller Distortion | |
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Spectral Bands | |
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Molecular Orbitals in Complexes | |
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Interpretation of Spectra | |
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Splitting of Spectroscopic States | |
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Orgel Diagrams | |
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Racah Parameters and Quantitative Methods | |
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The Nephelauxetic Effect | |
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Tanabe-Sugano Diagrams | |
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The Lever Method | |
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J�rgensen's Method | |
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Charge Transfer Absorption | |
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Solvatochromism | |
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Composition and Stability of Complexes | |
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Composition of Complexes in Solution | |
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Job's Method of Continuous Variations | |
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Equilibria Involving Complexes | |
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Distribution Diagrams | |
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Factors Affecting the Stability of Complexes | |
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Synthesis and Reactions of Coordination Compounds | |
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Synthesis of Coordination Compounds | |
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Substitution Reactions in Octahedral Complexes | |
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Ligand Field Effects | |
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Acid-Catalyzed Reactions of Complexes | |
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Base-Catalyzed Reactions of Complexes | |
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The Compensation Effect | |
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Linkage Isomerization | |
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Substitution in Square Planar Complexes | |
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The Trans Effect | |
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Electron Transfer Reactions | |
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Reactions in Solid Coordination Compounds | |
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Complexes Containing Metal-Carbon and Metal-Metal Bonds | |
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Binary Metal Carbonyls | |
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Structures of Metal Carbonyls | |
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Bonding of Carbon Monoxide to Metals | |
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Preparation of Metal Carbonyls | |
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Reactions of Metal Carbonyls | |
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Structure and Bonding in Metal-Alkene Complexes | |
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Preparation of Metal-Alkene Complexes | |
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Chemistry of Cyclopentadienyl and Related Complexes | |
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Bonding in Ferrocene | |
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Reactions of Ferrocene and other Metallocenes | |
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Complexes of Benzene and Related Aromatics | |
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Compounds Containing Metal-Metal Bonds | |
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Coordination Compounds in Catalysis | |
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Elementary Steps in Catalytic Processes | |
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Homogeneous Catalysis | |
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Bioinorganic Chemistry | |
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What Metals Do in Some Living Systems | |
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Cytotoxicity of Some Metal Compounds | |
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Antimalarial Metallodrugs | |
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Ionization Energies | |
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Character Tables for Selected Point Groups | |
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Index | |