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| Contributors | |
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| Introduction | |
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| Electronics at the Atomic-Scale | |
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| Stm Manipulation of Single Atoms and Molecules on Insulating Films | |
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| Introduction | |
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| Ultrathin Insulating Films | |
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| Interface State in NaCl/Cu(111) | |
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| Manipulation of Metal Atoms | |
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| Controlling the Charge State | |
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| Vertical Transfer and Build-up of Nanostructures | |
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| Imaging Molecular Orbitals | |
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| Manipulation of Molecules: Molecular/Orbital Engineering | |
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| Manipulation of a Small Molecule: Water Dissociation on MgO Films | |
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| Organometallic Synthesis: Au-Pentacene | |
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| Metai-Ligand Complex Formation | |
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| Molecular Switching Based on a Tautomerization Reaction | |
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| Conclusion | |
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| References | |
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| Electron Transfer Phenomena at the Molecular Scale: Organic Charge Transfer Complexes on Metal Surfaces | |
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| Introduction | |
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| Tcnq on Au(111): The Neutral Adsorption of an Electron Acceptor Molecule | |
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| TTF on Au(111): Formation of a Wigner Molecular Lattice | |
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| TTF Nucleation: Long-Range Repulsive Versus Short-Range Attractive Interactions | |
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| TTF-Tcnq on Au(111): Molecular Magnetism Induced by CT | |
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| Conclusions and Remarks | |
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| References | |
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| Chemistry at the Atomic-Scale | |
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| Imprinting Atomic and Molecular Patterns | |
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| Single-Molecule Imprinting on Semiconductors | |
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| Localized Atomic Reaction | |
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| Single Dissociative Attachment 1: Diatomic Molecules at Si(100)-2 x 1 | |
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| Single Dissociative Attachment 2: Dissociative Attachment of Polyatomics | |
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| Discussion of Single Dissociative Attachment | |
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| Multiple Dissociative Attachment | |
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| Single-Molecule Imprinting on Metals | |
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| Lar on Metals | |
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| Self-Assembly Followed by Pattern Imprinting | |
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| Imprinting Circles | |
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| Forming Lines | |
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| Imprinting Lines | |
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| Modes of Reaction | |
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| Direct and Indirect Reaction | |
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| Cooperative Reaction | |
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| Chain Reaction | |
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| Recoil Reaction | |
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| Conclusion | |
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| Acknowledgements | |
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| References | |
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| Tunnel-Current Induced STM Atomic Manipulation | |
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| Introduction | |
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| Experirnental Methods | |
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| Frame-by-Frame Scanning | |
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| Single-Point Current Injection | |
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| Desorption | |
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| Diet and Dimet | |
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| Si(100)-2x1:H | |
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| Chlorobenzene/Si(11.l)-7x7 | |
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| Intramolecular Bond Dissociation | |
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| Cypt(ll) | |
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| Chlorobenzene/Si(111)-7x7 | |
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| Fluoropentane/Si(100) | |
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| Nonlocal Manipulation | |
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| CH3SSCH3/Au(111) | |
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| Chlorobenzene/Si(111)-7x7 | |
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| References | |
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| Index | |