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    Solid-State Supramolecular Chemistry Crystal Engineering

    ISBN-10: 0080427189
    ISBN-13: 9780080427188
    Author(s): J. M. Lehn, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, Fritz V�gtle
    Description: This volume, containing 27 chapters, provides a state-of-the-art account of the chemistry of solid-state supramolecular systems. Following a valuable introductory chapter reviewing important general principles, the coherent coverage is structured in  More...
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    Publisher: Elsevier Science & Technology Books
    Binding: Hardcover
    Size: 7.50" wide x 10.75" long x 2.50" tall
    Weight: 5.346
    Language: English

    This volume, containing 27 chapters, provides a state-of-the-art account of the chemistry of solid-state supramolecular systems. Following a valuable introductory chapter reviewing important general principles, the coherent coverage is structured in the form of a series of contributions all written by experts in the respective areas comprehensively described. Throughout the volume, emphasis is placed not only on the design and structure of new host systems but also on practical applications of these novel materials in real chemical situations. The crystal engineering methods described relate to the synthesis of both organic and inorganic tailor-made hosts. Also the reader is presented with highly relevant descriptions of thermodynamic and kinetic considerations germane to the formation crystalline inclusion compounds. The final chapter gives a fascinating account of the self-organisation of molecules in two and three dimensions, crucially important to any process of crystal nucleation.

    Review of general principles
    Hydroquinone clathrates and diamondoid host lattices
    1,3,5-benzenetricarboxylic acid (trimesic acid)
    Helical host lattices formed by alicyclic diols
    Gossypol: a versatile host molecule
    Deoxycholic acid and related hosts
    Urea, thiourea, and selenourea
    Tri-o-thymotide and related hosts
    Cyclotriveratrylene and related hosts
    A survey of hydrocarbon hosts: biaryls, polyaryls, allenes, spiranes and cyclophanes
    Tetraphenylene and related hosts
    Perhydrotriphenylene: a D 3 symmetric host
    Cyclophosphazenes: structures and molecular selectives
    Symmetry in the evolution of host design
    Design of dialkynic diols and other new bifunctional hosts
    Onium salt hosts
    Shape and symmetry in the design of new hosts
    Survey of other potentially important hosts
    Supramolecular chemistry in cyanometallate systems
    Werner clathrates
    Porphyrin-based lattice clathrates: a molecular masonary approach to crystal engineering
    Infinite frameworks
    Hydrate inclusion compounds
    Stoichiometry and thermodynamics of clathrate systems
    Phase transformations in inclusion compounds, kinetics and thermodynamics of enclathration
    Cystalline microporous silicas as host-guest systems
    Crystal engineering in two and three dimensions

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