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Heteroatom Manipulation

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ISBN-10: 0080405975

ISBN-13: 9780080405971

Edition: 3rd 1991

Authors: E. Winterfeldt

List price: $660.00
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Description:

In this volume, those functional groups containing heteroatoms that have gained importance in organic synthesis are dealt with in detail. The introduction of these various groups and their relevant transformations are described and the various aspects of chemoselectivity, regioselectivity and stereoselectivity are discussed. After a compilation of the synthetically most useful substitution processes, there is a series of chapters on the various types of acylation reactions and in this context the different methods of acyl group activation are discussed. As functional group protection is of very general importance for organic synthesis, a corresponding chapter is included. This is followed…    
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Book details

List price: $660.00
Edition: 3rd
Copyright year: 1991
Publisher: Elsevier Science & Technology
Publication date: 9/8/1992
Binding: Hardcover
Size: 7.25" wide x 10.75" long x 3.00" tall
Weight: 6.160
Language: English

Displacement by Substitution Processes
Synthesis of alcohols and ethers
Synthesis of glycosides
Synthesis of amines and ammonium salts
Synthesis of nitroso, nitro and related compounds
Synthesis of sulfides, sulfoxides and sulfones
Synthesis of phosphonium ylides
Synthesis of halides
Formation of pseudohalides, nitriles and related compounds
Ritter-type reactions
Acylation-Type Reactions
Synthesis of acid halides, anhydrides and related compounds
Synthesis of activated esters and related compounds
Synthesis of amides and related compounds
Synthesis of thioamides and thiolactams
Synthesis of thioesters and thiolactones
Selenoesters of all oxidation states
Synthesis of iminium salts, orthoesters and related compounds
Inorganic acid derivatives
Protecting Groups
Alcohols, amines and thiols, including multiple protecting groups
Functional Group Interconversion
Carbonyl group derivatization
Use of carbonyl derivatives for heterocyclic synthesis
Functional group transformations via carbonyl derivatives
Degradation reactions
Functional group transformation via allyl rearrangement
2,3-sigmatropic rearrangements
Polonovski- and Pummerer-type reactions and the Nef reaction
Elimination Reactions
Eliminations to form alkenes, allenes and alkynes and related reactions
Reductive elimination, vicinal deoxygenation and vicinal desilylation
The Cope elimination, sulfoxide elimination and related thermal reactions
Fragmentation reactions
Author index
Subject index