Combining C-C ?-Bonds Volume 5

Name: Combining C-C ?-Bonds Volume 5
Availability: OutOfStock
ISBN: 9780080405964

ISBN-10: 0080405967

ISBN-13: 9780080405964

Edition: 3rd 1991

Authors: L. A. Paquette

List price: $745.00

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Description:

The guiding principle underlying the subject matter specifically compiled in Volume 5 has been to make available to the organic chemical community a sourcebook comprehensively covering all the important pgr;-bond-dependent transformations. Thermal, photochemical, and metal-catalyzed cycloadditions of every major type are expertly detailed by the most knowledgeable researchers in these areas. The synthetically useful electrocyclic and sigmatropic processes where alkenic centers are intimately involved in the structural change are similarly canvassed in compact detail. With added attention given to ene reactions, small-ring rearrangements, and related transition metal-associated reactions,…

Book details

List price: $745.00
Edition: 3rd
Copyright year: 1991
Publisher: Elsevier Science & Technology
Publication date: 9/8/1992
Binding: Hardcover
Size: 7.50" wide x 10.75" long x 3.00" tall
Weight: 6.336
Language: English



Selected contents: Ene Reactions


Ene reactions with alkenes as enophiles


Metallo-ene reactions


[2 + 2] Cycloadditions


Thermal cyclobutane ring formation


Formation of four-membered heterocycles


Di-pgr;-methane photoisomerizations


Oxa-di-pgr;-methane photoisomerizations


[3 + 2] Cycloadditions


Thermal cycloadditions


Transition metal mediated cycloadditions


[4 + 2] Cycloadditions


Intermolecular Diels-Alder reactions


Retrograde Diels-Alder reactions


Higher-Order Cycloadditions


[4 + 3] cycloadditions


[4 + 4] and [6 + 4] cycloadditions


[3 + 2] and [5 + 2] arene-alkene photocyloadditions


Electrocyclic Processes


Cyclobutene ring opening reactions


1,3-cyclohexadiene formation reactions


Nazarov and related cationic cyclizations


Sigmatropic Processes


Cope, oxy-cope and anionic oxy-cope rearrangements


Claisen rearrangements


Consecutive rearrangements


Small-Ring Rearrangements


Rearrangements of vinylcyclopropanes and related systems


Charge-accelerated rearrangements


Other Transition Metal Associated Reactions


The Pauson-Khand reaction


Metal-carbene cycloadditions


Metal-catalyzed cycloaddition of small ring compounds


Author index


Subject index